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Melting and draining tests on glass waste form for the immobilization of Cs, Sr, and rare-earth nuclides using a cold-crucible induction melting system

  • Choi, Jung-Hoon (Radioactive Waste Treatment Research Team, Korea Atomic Energy Research Institute) ;
  • Lee, Byeonggwan (Radioactive Waste Treatment Research Team, Korea Atomic Energy Research Institute) ;
  • Lee, Ki-Rak (Radioactive Waste Treatment Research Team, Korea Atomic Energy Research Institute) ;
  • Kang, Hyun Woo (Radioactive Waste Treatment Research Team, Korea Atomic Energy Research Institute) ;
  • Eom, Hyeon Jin (Radioactive Waste Treatment Research Team, Korea Atomic Energy Research Institute) ;
  • Park, Hwan-Seo (Radioactive Waste Treatment Research Team, Korea Atomic Energy Research Institute)
  • Received : 2021.05.25
  • Accepted : 2021.09.30
  • Published : 2022.04.25

Abstract

Cold-crucible induction melting (CCIM) technology has been intensively studied as an advanced vitrification process for the immobilization of highly radioactive waste. This technology uses high-frequency induction to melt a glass matrix and waste, while the outer surface of the crucible is water-cooled, resulting in the formation of a frozen glass layer (skull). In this study, for the fabrication of borosilicate glass waste form, CCIM operation test with 60 kg of glass per batch was conducted using surrogate wastes composed of Cs, Sr, and Nd as a representative of highly radioactive nuclides generated during spent nuclear fuel management. A 60 kg-scale glass waste form was successfully fabricated through melting and draining processes using a CCIM system, and its physicochemical properties were analyzed. In particular, to enhance the controllability and reliability of the draining process, an air-cooling drain control method that can control draining through air-cooling near drain holes was developed, and its validity for draining control was verified. The method can offer controllability on various draining processes, such as molten salt or molten metal draining processes, and can be applied to a process requiring high throughput draining.

Keywords

Acknowledgement

This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korean government (MSIT) (NRF-2021M2E3A1040061).

References

  1. G.L. Smith, J.B. Lang, D. Kim, J.V. Crum, M.J. Schweiger, C.L. Crawford, J.C. Marra, J.D. Vienna, Silicate based glass formulations for immobilization of U.S. Defense wastes, Using Cold Crucible Induction Melters (2014). PNNL23288/emsp-RPT-021.
  2. A.B. Barnes, D.C. Iverson, B.J. Adkins, E. Tchemitcheff, Feasibility Evaluation and Retrofit Plan for Cold Crucible Induction Melter Deployment in the Defense Waste Processing Facility at Savannah River Site - 8118, WSRC-STI2007-00669, 2008.
  3. D. Gombert, J.R. Richardson, Cold-crucible induction melter Design and development, Nucl. Technol. 141 (2003) 301-308. https://doi.org/10.13182/nt03-a3368
  4. C.W. Kim, C.S. Ray, D. Zhu, D.E. Day, D. Gombert, A. Aloy, A. Mogus-Milankovic, M. Karabulut, Chemically durable iron phosphate glasses for vitrifying sodium bearing waste (SBW) using conventional and cold crucible induction melting (CCIM) techniques, J. Nucl. Mater. 322 (2003) 152-164. https://doi.org/10.1016/S0022-3115(03)00325-8
  5. S.V. Stefanovky, A.G. Ptashkin, O.A. Knyazev, O.I. Stefanovskaya, B.S. Nikonov, B.I. Omelianenko, J.C. Marra, Vitrification of simulator of high-level Na-, Fe-, and Al-containing waste in a cold crucible, and the product properties, inorganic materials, Applied Research 2 (2011) 268-277.
  6. G. Sugilal, Experimental analysis of the performance of cold crucible induction glass melter, Appl. Therm. Eng. 28 (2008) 1952-1961. https://doi.org/10.1016/j.applthermaleng.2007.12.011
  7. N. Soelberg, S. Rossberg, Melting Hanford LAW into Iron-Phosphate Glass in a CCIM, INL/EXT-11-23251, 2011.
  8. V. Maio, B. Benefiel, C. Scott, J. Crum, C. Rodriguez, J.W. Amoroso, J.C. Marra, Cold Crucible Induction Melter (CCIM) Testing on Glass Ceramic and Ceramic Waste Form, FCRD-MRWFD-2015-000758/srnl-STI-2015-00186, 2015.
  9. J.W. Amoroso, J.C. Marra, Characterization of Ceramic Material Produced from a Cold Crucible Induction Melter Test, FCRD-MRWFD-2015-000133/srnl-STI2015-00188, 2015.
  10. M.I. Ojovan, W.E. Lee, New Developments in Glassy Nuclear Wasteforms, Nova science publishers, 2007.
  11. D.B. Lopukh, A.P. Martynov, A.V. Vavilov, I.N. Skrigan, A new Russian way to vitrify radioactive waste by induction melting in cold crucibles, Russ. Electr. Eng. 90 (2019) 802-806. https://doi.org/10.3103/s1068371219120095
  12. G.I. Park, M.K. Jeon, J.H. Choi, K.R. Lee, S.Y. Han, I.T. Kim, Y.Z. Cho, H.S. Park, Recent progress in waste treatment technology for pyroprocessing at KAERI, Journal of Nuclear Fuel Cycle and Waste Technology 17 (2019) 279-298. https://doi.org/10.7733/jnfcwt.2019.17.3.279
  13. H.S. Lee, J.M. Hur, J.G. Kim, D.H. Ahn, Y.Z. Cho, S.W. Paek, Korean pyrochemical process R&D activities, Energy Procedia 7 (2011) 391-395. https://doi.org/10.1016/j.egypro.2011.06.051
  14. H.S. Lee, G.I. Park, K.H. Kang, J.M. Hur, J.G. Kim, D.H. Ahn, Y.Z. Cho, E.H. Kim, Pyroprocessing technology development at KAERI, Nuclear Engineering and Technology 43 (2011) 317-328. https://doi.org/10.5516/NET.2011.43.4.317
  15. H.S. Lee, G.I. Park, J.W. Lee, K.H. Kang, J.M. Hur, J.G. Kim, S.W. Paek, I.T. Kim, I.J. Cho, Current status of pyroprocessing development at KAERI, Science and Technology of Nuclear Installations (2013) 1-11, 2013.
  16. J.H. Choi, T.K. Lee, K.R. Lee, S.Y. Han, Y.Z. Cho, N.Y. Kim, S.A. Jang, H.S. Park, J.M. Hur, Melt-crystallization monitoring system for the purification of 10 kg-scale LiCl salt waste, Nucl. Eng. Des. 326 (2018) 1-6. https://doi.org/10.1016/j.nucengdes.2017.10.016
  17. S.I. Moon, W.M. Chong, G.S. You, J.H. Ku, H.D. Kim, Preliminary conceptual study of engineering-scale pyroprocess demonstration facility, Nucl. Eng. Des. 259 (2013) 71-78. https://doi.org/10.1016/j.nucengdes.2013.02.046
  18. J.H. Choi, H.C. Eun, K.R. Lee, I.H. Cho, T.K. Lee, H.S. Park, D.H. Ahn, Fabrication of rare earth calcium phosphate glass waste forms for the immobilization of rare earth phosphates generated from pyrochemical process, J. Non-Cryst. Solids 434 (2016) 79-84. https://doi.org/10.1016/j.jnoncrysol.2015.12.017
  19. S.L. Marra, C.M. Jantzen, Characterization of Projected DWPF Glasses Heat Treated to Simulate Canister Centerline Cooling, vols. 92-142, WSRC-TR, 1992.
  20. C.M. Jantzen, N.E. Bibler, D.C. Beam, C.L. Crawford, M.A. Pickett, Characterization of the Defense Waste Processing Facility (DWPF) Environmental Assessment (EA) Glass Standard Reference Material, WSRC-TR, 1993, pp. 92-346.