Nuclear Engineering and Technology

  • 제54권11호
  • /
  • Pages.4013-4021
  • /
  • 2022
  • /
  • 1738-5733(pISSN)
  • /
  • 2234-358X(eISSN)
한국원자력학회 (Korean Nuclear Society)
권호 표지
DOI QR코드

DOI QR Code

Synthesis and application of zirconium phosphate mesoporous coordination polymer for effective removal of Co(II) from aqueous solutions

  • Yang Zeng (Key Laboratory of Radiation Physics and Technology of the Ministry of Education, Institute of Nuclear Science and Technology, Sichuan University) ;
  • Guoyuan Yuan (College of Chemistry and Chemical Engineering, Chongqing University of Science and Technology) ;
  • Tu Lan (Key Laboratory of Radiation Physics and Technology of the Ministry of Education, Institute of Nuclear Science and Technology, Sichuan University) ;
  • Feize Li (Key Laboratory of Radiation Physics and Technology of the Ministry of Education, Institute of Nuclear Science and Technology, Sichuan University) ;
  • Jijun Yang (Key Laboratory of Radiation Physics and Technology of the Ministry of Education, Institute of Nuclear Science and Technology, Sichuan University) ;
  • Jiali Liao (Key Laboratory of Radiation Physics and Technology of the Ministry of Education, Institute of Nuclear Science and Technology, Sichuan University) ;
  • Yuanyou Yang (Key Laboratory of Radiation Physics and Technology of the Ministry of Education, Institute of Nuclear Science and Technology, Sichuan University) ;
  • Ning Liu (Key Laboratory of Radiation Physics and Technology of the Ministry of Education, Institute of Nuclear Science and Technology, Sichuan University)
  • 투고 : 2022.01.25
  • 심사 : 2022.06.13
  • 발행 : 2022.11.25
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

A kind of zirconium phosphate mesoporous coordination polymer Zr-EDTMPA was successfully synthesized and characterized using XRD, FTIR, TGA, EA, SEM-EDS, and N2 sorption-desorption measurements. The prepared Zr-EDTMPA was first employed for the removal of Co(II) from an aqueous solution, and the effects of pH, contact time, temperature, initial Co(II) concentration, reusability, and sorption mechanism were systematically investigated. The results showed that the Zr-EDTMPA is a zirconium phosphate complex formed by the coordination of EDTMPA to Zr in a molar ratio of 1:1. The sorption of Co(II) by Zr-EDTMPA was a pH-dependent, spontaneous and endothermic process, which was better fitted to the pseudo-second-order kinetic model and Langmuir isotherm model. The Zr-EDTMPA was demonstrated to have excellent reusability and presented a high sorption capacity of 73.0 mg·g-1 for Co(II) at pH 8.0. The sorption mechanism was mainly attributed to the strong coordination between cobalt and the untapped hydroxyl functional groups on Zr-EDTMPA, which was confirmed by XPS spectra. Therefore, as a candidate sorbent with high sorption capacity and excellent reusability, Zr-EDTMPA has a great potential for the removal of Co(II) from aqueous solutions.

키워드

과제정보

Financial support from the National Natural Science Foundation of China (Grant No. 21876122) and the Fundamental Research Funds for the Central Universities is gratefully acknowledged.

참고문헌

  1. Y.A. Mustafa, M.J. Zaiter, Treatment of radioactive liquid waste (Co-60) by sorption on Zeolite Na-A prepared from Iraqi kaolin, J. Hazard. Mater. 196 (2011) 228-233. https://doi.org/10.1016/j.jhazmat.2011.09.013
  2. M. Li, G. Yuan, Y. Zeng, H. Peng, Y. Yang, J. Liao, J. Yang, N. Liu, Efficient removal of Co(II) from aqueous solution by flexible metal-organic framework membranes, J. Mol. Liq. 324 (2021), 114718.
  3. D.M. Manohar, B.F. Noeline, T.S. Anirudhan, Adsorption performance of Al-pillared bentonite clay for the removal of cobalt(II) from aqueous phase, Appl. Clay Sci. 31 (2006) 194-206. https://doi.org/10.1016/j.clay.2005.08.008
  4. D. Cao, T. Guo, X. Zhao, Treatment of Sb(V) and Co(II) containing wastewater by electrocoagulation and enhanced Sb(V) removal with Co(II) presence, Sep. Purif. Technol. 227 (2019), 115649.
  5. X. Wang, Y. Liu, H. Pang, S. Yu, Y. Ai, X. Ma, G. Song, T. Hayat, A. Alsaedi, X. Wang, Effect of graphene oxide surface modification on the elimination of Co(II) from aqueous solutions, Chem. Eng. J. 344 (2018) 380-390. https://doi.org/10.1016/j.cej.2018.03.107
  6. A.L. Taka, E. Fosso-Kankeu, K. Pillay, X.Y. Mbianda, Removal of cobalt and lead ions from wastewater samples using an insoluble nanosponge biopolymer composite: adsorption isotherm, kinetic, thermodynamic, and regeneration studies, Environ. Sci. Pollut. Res. 25 (2018) 21752-21767. https://doi.org/10.1007/s11356-018-2055-6
  7. B. Onghena, S. Valgaeren, T. Vander Hoogerstraete, K. Binnemans, Cobalt(II)/nickel(II) separation from sulfate media by solvent extraction with an undiluted quaternary phosphonium ionic liquid, RSC Adv. 7 (2017) 35992-35999. https://doi.org/10.1039/C7RA04753C
  8. I. Narin, M. Soylak, Enrichment and determinations of nickel(II), cadmium(II), copper(II), cobalt(II) and lead(II) ions in natural waters, table salts, tea and urine samples as pyrrolydine dithiocarbamate chelates by membrane filtration-flame atomic absorption spectrometry combination, Anal. Chim. Acta 493 (2003) 205-212. https://doi.org/10.1016/S0003-2670(03)00867-5
  9. J. Geng, L. Ma, H. Wang, J. Liu, C. Bai, Q. Song, J. Li, M. Hou, S. Li, Amidoxime-grafted hydrothermal carbon microspheres for highly selective separation of uranium, J. Nanosci. Nanotechnol. 12 (2012) 7354-7363. https://doi.org/10.1166/jnn.2012.6518
  10. R. Mu, B. Liu, X. Chen, N. Wang, J. Yang, Adsorption of Cu(II) and Co(II) from aqueous solution using lignosulfonate/chitosan adsorbent, Int. J. Biol. Macromol. 163 (2020) 120-127. https://doi.org/10.1016/j.ijbiomac.2020.06.260
  11. A.H. Elmorsy, M. El-Toony, E. Al-Johani, S. Ghurzan, A comparative study on Co(II) removal capacity from water samples by sorption using limestone and nanolimestone, J. Water Reuse Desal. 9 (2019) 339-349. https://doi.org/10.2166/wrd.2019.060
  12. G. Yuan, H. Tu, J. Liu, C. Zhao, J. Liao, Y. Yang, J. Yang, N. Liu, A novel ion-imprinted polymer induced by the glycylglycine modified metalorganic framework for the selective removal of Co(II) from aqueous solutions, Chem. Eng. J. 333 (2018) 280-288. https://doi.org/10.1016/j.cej.2017.09.123
  13. A. Shahat, M.R. Awual, M. Naushad, Functional ligand anchored nanomaterial based facial adsorbent for cobalt(II) detection and removal from water samples, Chem. Eng. J. 271 (2015) 155-163. https://doi.org/10.1016/j.cej.2015.02.097
  14. M. Ceglowski, G. Schroeder, Preparation of porous resin with Schiff base chelating groups for removal of heavy metal ions from aqueous solutions, Chem. Eng. J. 263 (2015) 402-411. https://doi.org/10.1016/j.cej.2014.11.047
  15. M.R. Awual, M. Ismael, T. Yaita, Efficient detection and extraction of cobalt(II) from lithium ion batteries and wastewater by novel composite adsorbent, Sensor. Actuat. B: Chem. 191 (2014) 9-18. https://doi.org/10.1016/j.snb.2013.09.076
  16. W. Liu, J. Zhang, C. Cheng, G. Tian, C. Zhang, Ultrasonic-assisted sodium hypochlorite oxidation of activated carbons for enhanced removal of Co(II) from aqueous solutions, Chem. Eng. J. 175 (2011) 24-32. https://doi.org/10.1016/j.cej.2011.09.004
  17. S. Dimovic, I. Smiciklas, I. Plecas, D. Antonovic, M. Mitri c, Comparative study of differently treated animal bones for Co2+ removal, J. Hazard. Mater. 164 (2009) 279-287. https://doi.org/10.1016/j.jhazmat.2008.08.013
  18. X. Bi, R.J. Lau, K.-L. Yang, Preparation of ion-imprinted silica gels functionalized with glycine, diglycine, and triglycine and their adsorption properties for copper ions, Langmuir 23 (2007) 8079-8086. https://doi.org/10.1021/la7008072
  19. A.R.F. Pipi, S.A. Neto, P.F.P. Barbosa, D.R.D. Carmo, The use of titanium (IV) phosphate for metal removal from aqueous and alcoholic samples, SN Appl. Sci. 1 (2019) 929.
  20. N. Rahman, M. Nasir, A.A. Alothman, A.M. Al-Enizi, M. Ubaidullah, S.F. Shaikh, Synthesis of 2-mercaptopropionic acid/hydrous zirconium oxide composite and its application for removal of Pb(II) from water samples: Central composite design for optimization, J. King Saud Univ. Sci. 33 (2021), 101280.
  21. N. Rahman, P. Varshney, M. Nasir, Synthesis and characterization of poly-dopamine/hydrous zirconium oxide composite and its efficiency for the removal of uranium (VI) from water, Environ. Nanotechnol. Monit. Manage. 15 (2021), 100458.
  22. C.-S. Zhu, X. Dong, L.-P. Wang, Removal of Pb(II), Cu(II), and Zn(II) from aqueous solutions by amorphous Tin(IV) hydrogen phosphate immobilized on silica, Water, Air, Soil Pollut. 225 (2014) 1988.
  23. V. Demir, S. Bin-Shafique, Column studies on effect of phosphate immobilization on removal of metals from stormwater runoff in bioretention cell, Asian J. Chem. 25 (2013) 3909-3912. https://doi.org/10.14233/ajchem.2013.13841
  24. Y.-P. Zhu, Y.-L. Liu, T.-Z. Ren, Z.-Y. Yuan, Hollow manganese phosphonate microspheres with hierarchical porosity for efficient adsorption and separation, Nanoscale 6 (2014) 6627-6636. https://doi.org/10.1039/C4NR00629A
  25. M. Gong, Y. Zhang, Z. Yao, Y. Tang, Y. Chen, T. Lu, Facile synthesis and electrocatalytic application of phosphonate functionalized platinum nanodendrites, CrystEngComm 15 (2013) 8929-8932. https://doi.org/10.1039/c3ce41548a
  26. T.-Y. Ma, H. Li, A.-N. Tang, Z.-Y. Yuan, Ordered, mesoporous metal phosphonate materials with microporous crystalline walls for selective separation techniques, Small 7 (2011) 1827-1837. https://doi.org/10.1002/smll.201100389
  27. W. Feng, S. Zhang, Q. Zhong, G. Wang, X. Pan, X. Xu, W. Zhou, T. Li, L. Luo, Y. Zhang, Soil washing remediation of heavy metal from contaminated soil with EDTMP and PAA: properties, optimization, and risk assessment, J. Hazard. Mater. 381 (2020), 120997.
  28. X.-J. Zhang, T.-Y. Ma, Z.-Y. Yuan, Synthesis of hierarchically meso-/macro-porous titanium tetraphosphonate materials with large adsorption capacity of heavy metal ions, Chem. Lett. 37 (2008) 746-747. https://doi.org/10.1246/cl.2008.746
  29. Y. Guo, Z. Jia, Q. Shi, Z. Liu, X. Wang, L. Li, Zr (IV)-based coordination porous materials for adsorption of copper(II) from water, Microporous Mesoporous Mater. 285 (2019) 215-222. https://doi.org/10.1016/j.micromeso.2019.05.020
  30. Y. Guo, Z. Jia, Sandwiched Zr (IV)-based coordinate porous materials membranes for adsorption of copper(II) from water, Mater. Lett. 228 (2018) 239-241. https://doi.org/10.1016/j.matlet.2018.06.028
  31. X.-Z. Lin, T.-Z. Ren, Z.-Y. Yuan, Mesoporous zirconium phosphonate materials as efficient water-tolerable solid acid catalysts, Catal. Sci. Technol. 5 (2015) 1485-1494. https://doi.org/10.1039/C4CY01110D
  32. X.-J. Zhang, T.-Y. Ma, Z.-Y. Yuan, Titania-phosphonate hybrid porous materials: preparation, photocatalytic activity and heavy metal ion adsorption, J. Mater. Chem. 18 (2008) 2003-2010. https://doi.org/10.1039/b717060b
  33. H. Yuzer, M. Kara, E. Sabah, M.S. Celik, Contribution of cobalt ion precipitation to adsorption in ion exchange dominant systems, J. Hazard. Mater. 151 (2008) 33-37. https://doi.org/10.1016/j.jhazmat.2007.05.052
  34. Y. Zeng, T. Lan, M. Li, G. Yuan, F. Li, J. Liao, J. Yang, Y. Yang, N. Liu, Removal of Co(II) from aqueous solutions by pyridine schiff base-functionalized zirconium-based MOFs: a combined experimental and DFT study on the effect of ortho-, meta-, and para-substitution, J. Chem. Eng. Data 66 (2021) 749-760. https://doi.org/10.1021/acs.jced.0c00852
  35. G. Yuan, H. Tu, M. Li, J. Liu, C. Zhao, J. Liao, Y. Yang, J. Yang, N. Liu, Glycine derivative-functionalized metal-organic framework (MOF) materials for Co(II) removal from aqueous solution, Appl. Surf. Sci. 466 (2019) 903-910. https://doi.org/10.1016/j.apsusc.2018.10.129
  36. X. Zhao, Y. Luo, C. He, P. Zong, K. Zhang, J.M. Kebwaro, K. Li, B. Fu, Y. Zhao, Evaluation of permutite for removal of radiocobalt from nuclear wastewater, J. Radioanal. Nucl. Chem. 303 (2015) 837-844. https://doi.org/10.1007/s10967-014-3327-3
  37. M. Torkashvand, M.B. Gholivand, R. Azizi, Synthesis, characterization and application of a novel ion-imprinted polymer based voltammetric sensor for selective extraction and trace determination of cobalt (II) ions, Sensor. Actuat. B: Chem. 243 (2017) 283-291. https://doi.org/10.1016/j.snb.2016.11.094
  38. Y. Wang, X. Hu, Y. Liu, Y. Li, T. Lan, C. Wang, Y. Liu, D. Yuan, X. Cao, H. He, L. Zhou, Z. Liu, J.W. Chew, Assembly of three-dimensional ultralight poly(-amidoxime)/graphene oxide nanoribbons aerogel for efficient removal of uranium(VI) from water samples, Sci. Total Environ. 765 (2021), 142686.
  39. H.-T. Fan, J.-X. Liu, H. Yao, Z.-G. Zhang, F. Yan, W.-X. Li, Ionic imprinted silica-supported hybrid sorbent with an anchored chelating schiff base for selective removal of cadmium(II) ions from aqueous media, Ind. Eng. Chem. Res. 53 (2014) 369-378. https://doi.org/10.1021/ie4027814
  40. Y.-H. Huang, C.-L. Hsueh, H.-P. Cheng, L.-C. Su, C.-Y. Chen, Thermodynamics and kinetics of adsorption of Cu(II) onto waste iron oxide, J. Hazard. Mater. 144 (2007) 406-411. https://doi.org/10.1016/j.jhazmat.2006.10.061
  41. S.K. Milonjic, A consideration of the correct calculation of thermodynamic parameters of adsorption, J. Serb. Chem. Soc. 72 (2007) 1363-1367. https://doi.org/10.2298/JSC0712363M
  42. N. Rahman, A. Raheem, Graphene oxide/Mg-Zn-Al layered double hydroxide for efficient removal of doxycycline from water: taguchi approach for optimization, J. Mol. Liq. 354 (2022), 118899.
  43. I. Langmuir, The constitution and fundamental properties of solids and liquids. Part I. Solids, J. Am. Chem. Soc. 38 (1916) 2221-2295. https://doi.org/10.1021/ja02268a002
  44. K.Y. Foo, B.H. Hameed, Insights into the modeling of adsorption isotherm systems, Chem. Eng. J. 156 (2010) 2-10. https://doi.org/10.1016/j.cej.2009.09.013
  45. J. Liu, S. Shi, J. Shu, C. Li, H. He, C. Xiao, X. Dong, Y. He, J. Liao, N. Liu, T. Lan, Synthesis and characterization of waste commercially available poly-acrylonitrile fiber-based new composites for efficient removal of uranyl from U(VI)-CO3 solutions, Sci. Total Environ. 822 (2022), 153507.
  46. Y.-P. Zhu, T.-Z. Ren, Z.-Y. Yuan, Co2+-loaded periodic mesoporous aluminum phosphonates for efficient modified Fenton catalysis, RSC Adv. 5 (2015) 7628-7636. https://doi.org/10.1039/C4RA15032E
  47. T.-Y. Ma, X.-Z. Lin, X.-J. Zhang, Z.-Y. Yuan, High surface area titanium phosphonate materials with hierarchical porosity for multi-phase adsorption, New J. Chem. 34 (2010) 1209-1216. https://doi.org/10.1039/b9nj00775j