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Mathematical and Experimental Study for Mixed Energetic Materials Combustion in Closed System

  • Kong, Tae Yeon (Department of Chemical Engineering, Pukyong National University) ;
  • Ryu, Byungtae (Agency for Defense Development) ;
  • Ahn, Gilhwan (Hanwha Corporation R&D Center) ;
  • Im, Do Jin (Department of Chemical Engineering, Pukyong National University)
  • Received : 2021.10.06
  • Accepted : 2021.11.02
  • Published : 2022.05.01

Abstract

Modelling the energy release performance of energetic material combustion in closed systems is of fundamental importance for aerospace and defense application. In particular, to compensate for the disadvantage of the combustion of single energetic material and maximize the benefits, a method of combusting the mixed energetic materials is used. However, since complicated heat transfer occurs when the energetic material is combusted, it is difficult to theoretically predict the combustion performance. Here, we suggest a theoretical model to estimate the energy release performance of mixed energetic material based on the model for the combustion performance of single energetic material. To confirm the effect of parameters on the model, and to gain insights into the combustion characteristics of the energetic material, we studied parameter analysis on the reaction temperature and the characteristic time scales of energy generation and loss. To validate the model, model predictions for mixed energetic materials are compared to experimental results depending on the amount and type of energetic material. The comparison showed little difference in maximum pressure and the reliability of the model was validated. Finally, we hope that the suggested model can predict the energy release performance of single or mixed energetic material for various types of materials, as well as the energetic materials used for validation.

Keywords

Acknowledgement

This study was financially supported by the defense acquisition program administration and Agency for Defense Development (ADD) contract. This research was also supported by the Korea Institute of Energy Technology Evaluation and Planning (KETEP) and the Ministry of Trade, Industry & Energy (MOTIE) of the Republic of Korea (No. 20194010201840).

References

  1. Francois, L., Dupays, J., Davidenko, D. and M. Massot, "Travelling Wave Mathematical Analysis and Efficient Numerical Resolution for a One-dimensional Model of Solid Propellant Combustion," Combust. Theor. Model., 24, 775-809(2020). https://doi.org/10.1080/13647830.2020.1752943
  2. Ulas, A., Risha, G. A. and Kuo, K. K., "An Investigation of the Performance of a Boron/Potassium-Nitrate Based Pyrotechnic Igniter," Propellants Explos. Pyrotech., 31(4), 311-317(2006) https://doi.org/10.1002/prep.200600047
  3. Han, D.-H., Sung, H.-G. and Ryu, B.-T., "Numerical Simulation for the Combustion of a Zirconium/Potassium Perchlorate Explosive inside a Closed Vessel," Propellants Explos. Pyrotech., 42(10), 1168-1178(2017). https://doi.org/10.1002/prep.201700068
  4. Kalpakli, B., Acar, E. B. and Ulas, A., "Improved Combustion Model of Boron Particles for Ducted Rocket Combustion Chambers," Combust. Flame, 179, 267-279(2017). https://doi.org/10.1016/j.combustflame.2017.02.015
  5. Jackson, T. L., Massa, L. and Brewster, M. Q., "Unsteady Combustion Modelling of Energetic Solids, Revisited," Combust. Theor. Model., 8(3), 513-532(2004). https://doi.org/10.1088/1364-7830/8/3/005
  6. Hernandez, A. M. and Stewart, D. S., "Computational Modelling of Multi-material Energetic Materials and Systems," Combust. Theor. Model., 24(3), 407-441(2020). https://doi.org/10.1080/13647830.2019.1689299
  7. Gonthier, K. A. and Powers, J. M., "Formulation, Predictions, and Sensitivity Analysis of a Pyrotechnically Actuated Pin Puller Model," J. Propul. Power, 10(4), 501-507(1994). https://doi.org/10.2514/3.23800
  8. Jang, S., Lee, H. and Oh, J., "Performance Modeling of a Pyrotechnically Actuated Pin Puller," Int'l J. of Aeronautical & Space Sci., 15(1), 102-111(2014). https://doi.org/10.5139/IJASS.2014.15.1.102
  9. Paul, B. H. and Gonthier, K. A., "Analysis of Gas-Dynamic Effects in Explosively Actuated Valves," J. Propul. Power, 26(3), 479-496(2012). https://doi.org/10.2514/1.43190
  10. Yang, L. C., "Effects of Fuel Particle Size and Impurity on Solid-to-solid Pyrotechnic Reaction Rate," 47th AIAA/ASME/SAE/ASEE Joint Propulsion Conference & Exhibition, San Diego, California (2011).
  11. Yang, L. C., "Reaction Rate Analysis for Selected Solid-to-solid Reaction Pyrotechnic Compositions," 48th AIAA/ASME/SAE/ASEE Joint Propulsion Conference & Exhibition, Atlanta, Georgia (2012).
  12. Kong, T. Y., Won, Y., Ryu, B., Ahn, G. and Im, D. J., "Mathematical Modeling of ZrKClO4 Nano Particle Energy Release," J. Nanosci. Nanotechnol., 17(11), 8372-8377(2017). https://doi.org/10.1166/jnn.2017.15146
  13. Johnston, I. A., "The Noble-Abel equation of state: Thermodynamic Derivations for Ballistics Modelling," DSTO-TN-0670, Defence Science and Technology Organisation, Edinburgh, Australia (2005).
  14. Nagasaka, Y. and Nagashima, A., "The Thermal Conductivity of Molten NaNO3 and KNO3", Int. J. Thermophys., 12(5), 769-781 (1991). https://doi.org/10.1007/BF00502404
  15. Varghese, P. L., "Investigation of Heat Transfer in Zirconium Potassium Perchlorate at Low Temperature: A Study of the Failure Mechanism of the NASA Standard Initiator," NASA-CR-184774, The University of Texas at Austin Center for Energy Studies, Austin, TX, United States (1989).
  16. Chen, K. S., "A Simplified Model of TiH1.65/KClO4 Pyrotechnic Ignition," SAND2009-1217, Sandia National Laboratories, Albuquerque, New Mexico (2009).
  17. Cha, S. et al., "Combustion Modeling of Explosive for Pyrotechnic Initiator," J. Korean Soc. Propuls. Eng., 21(6), 39-48(2017). https://doi.org/10.6108/KSPE.2017.21.6.039
  18. Manning, T. et al., "Formulation Development and Characterization of Cellulose Acetate Nitrate Based Propellants for Improved Insensitive Munitions Properties," Def. Technol., 10(2), 92-100(2014). https://doi.org/10.1016/j.dt.2014.05.011
  19. National Institute of Standards and Technology website; software available at http://webbook.nist.gov/chemistry/
  20. Holy, J. A., "Burn Rates of TiH2/KClO4/Viton and Output Testing of NASA SKD26100098-301 Pressure Cartridges," EG&G Mound Applied Technologies, NASA-CR-188357, Miamisburg, OH (1993).
  21. Yano, Y., "Condensed Phase Reaction of Boron with Potassium Nitrate," Propellants Explos. Pyrotech., 14(5), 187-189(1989). https://doi.org/10.1002/prep.19890140503