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Morphological Characteristics According to the 3D Printing Extrusion Temperature of TPU Filaments for Different Hardnesses

경도별 TPU 필라멘트의 3D 프린팅 압출 온도 조건에 따른 모폴로지 특성

  • Jung, Imjoo (Department of Fashion and Textiles, Dong-A University) ;
  • Shin, Eunjoo (Department of Organic Materials and Polymer Engineering, Dong-A University) ;
  • Lee, Sunhee (Department of Fashion and Textiles, Dong-A University)
  • 정임주 (동아대학교 의상섬유학과) ;
  • 신은주 (동아대학교 유기재료고분자공학과) ;
  • 이선희 (동아대학교 의상섬유학과)
  • Received : 2022.01.12
  • Accepted : 2022.02.11
  • Published : 2022.02.28

Abstract

Thermoplastic polyurethane (TPU) is used in various fields because of its excellent elasticity, flexibility, mechanical strength, and shock absorption. In particular, in the fused deposition modeling (FDM), in which layers are extruded by heating and melting thermoplastic materials through a nozzle, the adhesion and mechanical properties of the output are affected according to the nozzle temperature. In this study, six types of TPU filaments with various hardnesses (65A, 75A, 80A, and 85A) were manufactured through commercial chip and synthesis (comp) and extruded under five nozzle temperature conditions (190℃, 200℃, 210℃, 220℃, and 230℃). Then, the most suitable nozzle temperature for the filament was confirmed, and the re-entrant pattern was printed. Extruded filaments and printed re-entrant patterns were analyzed through morphology analysis. Finally, the tensile properties of the two samples of the optimal printed condition for FDM 3D printing were examined. Consequently, the optimal nozzle temperature of each TPU filament was confirmed as 190℃ for Chip-65A, 210℃ for Chip-75A, 210℃ for Chip-80A, 200℃ for Chip-85A, 210℃ for Comp-75A, and 200℃ for Comp-85A. Through printing re-entrant patterns and morphologies, Chip-75A and Comp-75A were considered to be the most suitable for 3D printing. The tensile properties showed that Chip-75A was more flexible than Comp-75A.

Keywords

Acknowledgement

이 성과는 정부(과학기술정보통신부)의 재원으로 한국연구재단의 지원을 받아 수행된 연구임 (NRF-2021R1A4A1022059).

References

  1. A. K. Mishra, S. Chattopadhyay, and G. B. Nando, "Effect of Modifiers on Morphology and Thermal Properties of Novel Thermoplastic Polyurethane-Peptized Laponite Nanocomposite", J. Appl. Polym. Sci., 2010, 115, 558-569. https://doi.org/10.1002/app.30975
  2. A. Harynska, I. Carayon, P. Kosmela, A. Brillowska- Dabrowska, M. Lapinski, J. Kucinska-Lipka, and H. Janik, "Processing of Polyester-Urethane Filament and Characterization of FFF 3D Printed Elastic Porous Structures with Potential in Cancellous Bone Tissue Engineering", Materials, 2020, 13, 4457. https://doi.org/10.3390/ma13194457
  3. Y. Han and J. Kim, "A Study on the Mechanical Properties of Knit Fabric Using 3D Printing -Focused on PLA, TPU Filament-", J. Fash. Bus., 2018, 22, 93-105. https://doi.org/10.12940/JFB.2018.22.4.93
  4. J. Jeong, H. Park, Y. Lee, J. Kang, and J. Chun, "Developing Parametric Design Fashion Products Using 3D Printing Technology", Fash Text., 2021, 8, 22. https://doi.org/10.1186/s40691-021-00247-8
  5. S. Kim, H. Seong, Y. Her, and J. Chun, "A Study of the Development and Improvement of Fashion Products Using a FDM Type 3D Printer", Fash Text., 2019, 6, 9. https://doi.org/10.1186/s40691-018-0162-0
  6. J. Chun, "Development of Wearable Fashion Prototypes Using Entry-Level 3D Printers", J. Korean. Soc. Cloth. Text., 2017, 41, 468-486. https://doi.org/10.5850/JKSCT.2017.41.3.468
  7. A. Przybytek, I. Gubanska, J. Kucinska-Lipka, and H. Janik, "Polyurethanes as a Potential Medical-Grade Filament for Use in Fused Deposition Modeling 3D Printers - a Brief Review", Fibres Text. Eastern Eur., 2018, 6, 120-125.
  8. A. Harynska, I. Gubanska, J. Kucinska-Lipka, and H. Janik, "Fabrication and Characterization of Flexible Medical-Grade TPU Filament for Fused Deposition Modeling 3DP Technology", Polymers, 2018, 10, 1304. https://doi.org/10.3390/polym10121304
  9. J. Xiao and Y. Gao, "The Manufacture of 3D Printing of Medical Grade TPU", Prog Addit Manuf., 2017, 2, 117-123. https://doi.org/10.1007/s40964-017-0023-1
  10. L. Rodriguez-Parada, S. Rosa, and P. F. Mayuet, "Influence of 3D-Printed TPU Properties for the Design of Elastic Products", Polymers, 2021, 13, 2519. https://doi.org/10.3390/polym13152519
  11. P. Platek, K. Rajkowski, K. Cieplak, M. Sarzynski, J. Malachowski, R. Wozniak, and J. Janiszewski, "Deformation Process of 3D Printed Structures Made from Flexible Material with Different Values of Relative Density", Polyemers, 2020, 12, 2120. https://doi.org/10.3390/polym12092120
  12. M. S. Chaudhry and A. Czekanski, "Evaluating FDM Process Parameter Sensitive Mechanical Performance of Elastomers at Various Strain Rates of Loading", Materials, 2020, 13, 3202. https://doi.org/10.3390/ma13143202
  13. N. Vidakis, M. Petousis, A. Korlos, E. Velidakis, N, Mountakis, C. Charou, and A. Myftari, "Strain Rate Sensitivity of Polycarbonate and Thermoplastic Polyurethane for Various 3D Printing Temperatures and Layer Heights", Polymers, 2021, 13, 2752. https://doi.org/10.3390/polym13162752
  14. X. Lin, J. Gao, J. Wang, R. Wang, M. Gong, L. Zhang, Y. Lu, D. Wang, and L. Zhang, "Desktop Printing of 3D Thermoplastic Polyurethane Parts with Enhanced Mechanical Performance Using Filaments with Varying Stiffness", Addit. Manuf., 2021, 47, 102267.
  15. B. Arifvianto, T. N. Iman, B. T. Prayoga, R. Dharmastiti, U. A. Salim, M. Mahardika, and S. Suyitno, "Tensile Properties of the FFF-Processed Thermoplastic Polyurethane (TPU) Elastomer", Int. J. Adv. Manuf. Technol., 2021, 117, 1709-1719. https://doi.org/10.1007/s00170-021-07712-0
  16. F. Peng, B. D. Vogt, and M. Cakmak, "Complex Flow and Temperature History during Melt Extrusion in Material Extrusion Additive Manufacturing", Addit. Manuf., 2018, 22, 197-206. https://doi.org/10.1016/j.addma.2018.05.015
  17. D. A. Anderegg, H. A. Bryant, D. C. Ruffin, S. M. Skrip Jr, J. J. Fallon, E. L. Gilmer, and M. J. Bortner, "In-Situ Monitoring of Polymer Flow Temperature and Pressure in Extrusion Based Additive Manufacturing", Addit. Manuf., 2019, 26, 76-83. https://doi.org/10.1016/j.addma.2019.01.002
  18. C. Ge, S. Wang, W. Zheng, and W. Zhai, "Preparation of Microcellular Thermoplastic Polyurethane (TPU) Foam and Its Tensile Property", Polym. Eng. Sci., 2018, 58, E158-E166. https://doi.org/10.1002/pen.24813
  19. I. Jung, H. Kim, and S. Lee, "Charaterizations of 3D Printed Re-entrant Pattern/Aramid Knit Composite Prepared by Various Tilting Angles", Fash. Text., 2021, 8, 44. https://doi.org/10.1186/s40691-021-00273-6
  20. I. Jung and S. Lee, "Effect of Surface Roughness of Fabrics on Tensile Properties of 3D Printing Auxetic Re-entrant Pattern/ Textile Composites", Text. Sci. Eng., 2021, 58, 167-176. https://doi.org/10.12772/TSE.2021.58.167
  21. H, Kim, S. Kabir, and S. Lee, "Mechanical Properties of 3D Printed Re-entrant Pattern/neoprene Composite Textile by Pattern Tilting Angle of Pattern", J. Korean. Soc. Cloth. Text., 2021, 45, 106-122. https://doi.org/10.5850/JKSCT.2021.45.1.106
  22. S. Kabir and S. Lee, "Study of Shape Memory and Tensile Property of 3D Printed Sinusoidal Sample/Nylon Composite Focused on Various Thicknesses and Shape Memory Cycles", Polymers, 2020, 12, 1600. https://doi.org/10.3390/polym12071600
  23. S. Kabir, H. Kim, and S. Lee, "Physical Property of 3D-Printed Sinusoidal Pattern Using Shape Memory TPU Filament", Text. Res. J., 2020, 90, 2399-2410. https://doi.org/10.1177/0040517520919750
  24. H. Kim and S. Lee, "Mechanical Properties of 3D Printed Reentrant Pattern with Various Hardness Types of TPU Filament Manufactured through FDM 3D Printing", Text. Sci. Eng., 2020, 57, 166-176. https://doi.org/10.12772/tse.2020.57.166
  25. S. H. Lee, "Morphology and Properties of Textiles Manufactured by Three-Dimensional Printing Based on Fused Deposition Modeling", Text. Sci. Eng., 2015, 52, 272-279. https://doi.org/10.12772/TSE.2015.52.272
  26. S. Lee, "Evaluation of Mechanical Properties and Washability of 3D Printed Lace/Voil Composite Fabrics Manufactured by FDM 3D Printing Technology", Fashion Text. Res. J., 2018, 20, 353-359. https://doi.org/10.5805/SFTI.2018.20.3.353
  27. S. Lee, "Tensile Properties and Stiffnesses of 3D-Printed Lace/ Voile Composite Fabrics Manufactured by Various Roller Processes", Text. Sci. Eng., 2019, 56, 8-14. https://doi.org/10.12772/tse.2019.56.008
  28. M. Asensio, V. Costa, A. Nohales, O. Bianchi, and C. M. Gomez, "Tunable Structure and Properties of Segmented Thermoplastic Polyurethanes as a Function of Flexible Segment", Polymers, 2019, 11, 1910. https://doi.org/10.3390/polym11121910
  29. P. Kasprzyk, K. Blazek, P. Parcheta, and J. Datta, "Green Thermoplastic Poly(ether-urethane)s - Synthesis, Chemical Structure and Selected Properties Investigation", Polimery, 2020, 65, 672-680. https://doi.org/10.14314/polimery.2020.10.2
  30. P. Kasprzyk and J. Datta, "Effect of Molar Ratio [NCO]/[OH] Groups during Prepolymer Chains Extending Step on the Morphology and Selected Mechanical Properties of Final Bio-Based Thermoplastic Poly(ether-urethane) Materials", Polym. Eng. Sci., 2018, 58, E199-E206. https://doi.org/10.1002/pen.24874
  31. S. Charlon, J. L. Boterff, and J. Soulestin, "Fused Filament Fabrication of Polypropylene: Influence of the Bead Temperature on Adhesion and Porosity", Addit. Manuf., 2021, 38, 101838.
  32. X. Lin, P. Coates, M. Hebda, R. Wang, Y. Lu, and L. Zhang, "Experimental Analysis of the Tensile Property of FFF-printed Elastomers", Polym. Test., 2020, 90, 106687. https://doi.org/10.1016/j.polymertesting.2020.106687