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표면 처리를 통한 친환경 방오 기술 및 실해역 평가 연구

Antifouling technology and sea trial verification according to surface treatment

  • 한덕현 (고등기술연구원 신소재공정센터) ;
  • 고혁준 (고등기술연구원 그린에너지인텔리전스센터) ;
  • 정항철 (고등기술연구원 신소재공정센터)
  • Han, Deok-Hyun (Advanced Materials and Processing Center, Institute for Advanced Engineering(IAE)) ;
  • Koh, Hyeok-Jun (Center for Green Energy and Industry Intelligence, Institute for Advanced Engineering(IAE)) ;
  • Jung, Hang-Chul (Advanced Materials and Processing Center, Institute for Advanced Engineering(IAE))
  • 투고 : 2022.12.05
  • 심사 : 2022.12.26
  • 발행 : 2022.12.31

초록

Antifouling paints that inhibit the attachment and contamination of marine organisms mainly use TBT compounds, but because of their toxic components, they cause ecosystem disturbance and environmental destruction problems, so It is necessary to research eco-friendly antifouling paints that are easy to maintain and effective antifouling technologies. In this study, physical surface treatment of silane coating and chemical antifouling technology were applied to the metal surface to secure the stability of the surface of the marine structure and inhibit the attachment and growth of marine organisms. Adhesion of marine organisms was evaluated according to the coating conditions through surface evaluation of the charged material for 15 months in the waters of the west coast of Korea. In accordance with ASTM D6990-05, antifouling properties fouling rates (FR) and physical degradation rates(PDR) were evaluated through visual inspection of the evaluation specimens. As a result of evaluating the antifouling performance of the coated surface, it was confirmed that the antifouling performance was maintained at the 50% level even after 15 months in the sample subjected to physical processing and silane coating.

키워드

과제정보

본 연구는 2022년도 산업통상자원부(MOTIE)의 재원으로 한국에너지기술평가원(KETEP)의 지원을 받아 수행한 연구과제입니다. (No. 20203040010240)

참고문헌

  1. H. W. Shin, Evaluation of antifouling system of new antifouling agents using spores of the green alga, Ulva pertusa and diatom, Nitzschia pungens, Korean J. Environ. Ecol., 29 (2015) 736-742. https://doi.org/10.13047/KJEE.2015.29.5.736
  2. S. M. Evans, The TBT ban: Out of the flying pan into the fire?, Mar. Poll. Bull., 40 (2000) 204-211. https://doi.org/10.1016/S0025-326X(99)00248-9
  3. International Maritime Organization(IMO), International convention on the control of harmful anti-fouling systems on ships, International Maritime Organization(IMO), London (2001) 22-25.
  4. J. Strand, Tributyltin accumulation and effects in marine molluscs from West Greenland, Environ. Pollut., 123 (2003) 31-37. https://doi.org/10.1016/S0269-7491(02)00361-5
  5. M. E. Stupak, Non-toxic alternative compounds for marine antifouling paints, Int. Biodeter Biodegr., 52 (2003) 49-52. https://doi.org/10.1016/S0964-8305(03)00035-0
  6. K. H. Park, Acute toxicity of antifouling agents(TBT, Sea-nine, Cu-pyrithione and Zn-pyrithione) to rockfish Sebastes schlegeli and amphipod Monocorophium acherusicum, J. Korean Soc. Mar. Environ. Engin., 9 (2006) 21-28.
  7. H. B. Rai, Chemotactic antifouling properties of methyl caproate: its implication for ship hull coatings, WSEAS Trans. Systems, 5 (2006) 2581-2585.
  8. S. E. Lee, Determination of new antifouling agents in seacoasts in Korea by gas chromatography-mass spectrometry, Anal. Sci. Technol., 21 (2008) 459-473.
  9. J. H. Jang, On the reduction of a shp resistance by attaching an air cavity to its flat bottom, JSNAK 36 (1999) 1-8.
  10. M. P. Shultz, Frictional resistance of antifouling coating systems, ASME J. Fluids Eng., 126 (2004) 1039-1047. https://doi.org/10.1115/1.1845552
  11. B. S. Yoon, Friction drag reduction technology by surface super-hydrophobicity, SNAK Naval Ship Technology Committee (2011).
  12. Y. F. Fu, Marine drag reduction of shark skin inspired riblet surfaces, Biosurface Biotribology, 3 (2017) 11-24. https://doi.org/10.1016/j.bsbt.2017.02.001
  13. G. D. Bixler, Bioinspired Surface for Low Drag, Self-Cleaning, and Antifouling: Shark Skin, Butterfly and Rice Leaf Effects, Ph.D The Ohio State University (2013)
  14. Y. Wenfa, Layer-by-layer deposited hybrid polymer coatings based on polysaccharides and zwitterionic silanes with marine antifouling properties, ACS Appl. Bio Mater., 4 (2021) 2385-2397. https://doi.org/10.1021/acsabm.0c01253
  15. POSCO, POSCO Magnesium aluminium alloy coating product(PosMAC) catalog, POSCO (2018)
  16. ASTM International, Standard practice for evaluating biofouling resistance and physical performance of marine coating systems, ASTM D6990-05 (2005)
  17. J. W. Gu, Ship maintenance and preservation(II), Journal of Korea Fishing Vessel Association, 14 (1983) 60-63.