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Preparation of RBPM-Ru based on FPSu and its characterization through image segmentation

  • Kothandaraman, D (School of Computer Science and Artificial Intelligence, SR University) ;
  • Krishnaveni, V (Department of Chemistry, Anna University)
  • Received : 2020.10.30
  • Accepted : 2021.10.18
  • Published : 2021.11.25

Abstract

A membrane technology is one of the basic categories of water purification technologies that are used to treat wide range of salinity water from brackish to sea water. Bipolar membrane (BPM) is a special type of catalytic ion exchange membrane (IEM) which involves water dissociation reaction in intermediate layer. Here monopolar and bipolar IEMs with Ru (water dissociation catalyst) as intermediate layer (IL) are prepared with resin and glass fiber reinforcements using functionalized polysulfone polymer (RBPM-Ru). The prepared RBPM-Ru was characterized using universal testing machine, thermo gravimetric analysis, contact angle and chemical stability through conductivity and water absorption studies. In addition the present study highlights the new method of characterizing RBPM-Ru especially through image segmentation technique as one of the prior characteristic technique before SEM analysis to confirm its bi-layer formation in a single membrane because of its advantages like no cost requirement and less time consumption method with the same quality of accuracy. The performance of RBPM-Ru in a two-compartment electrodialytic cell was evaluated using correlated parameters such as pH, concentration and conductivity studies in both compartments. By using current voltage graph (I-V) the importance of incorporating catalytic material in IL for enhancing BPM water dissociation reaction were identified. Finaly it can be concluded that RBPM-Ru was expected to have better process efficiency due to lower co-ion leakage capacity when compared with results of polystyrene-divinylbenzene (PSDVB) based BPM under similar experimental conditions.

Keywords

Acknowledgement

Authors would like to thank the management of S R University, Warangal, TS for providing the facility.

References

  1. Anh, N.T.L., Kim, Y.C. and Lee, G.S. (2012), "Morphological gradient applied to new active contour model for color image segmentation", Proceedings of the 6th International Conference on Ubiquitous Information Management and Communication, Kuala Lumpur, Malaysia, February.
  2. Amanpreet K. and Navjot K. (2015), "Image Segmentation Techniques", Int. Res. J. Eng. Technol., 2(2), 944-947.
  3. Aritomi, T., van der Boomgaard, T. and Strathmann, H. (1996), "Current voltage curve of a bipolar membrane at high current density", Desalination, 104, 13-18. https://doi.org/10.1016/0011-9164(96)00021-5
  4. Bae, B., Miyatake, K. and Watanabe, M. (2008), "Sulfonated poly (arylene ether sulfone) ionomers containing fluorenyl groups for fuel cell applications", J. Membr. Sci., 310, 110-118. https://doi.org/10.1016/j.memsci.2007.10.037
  5. Cho, C.G., Kim, S.H., Park, Y.C., Kim, H. and Park, J.W. (2008), "Fuel cell membranes based on blends of PPO with poly (styrene-b-vinylbenzylphosphonic acid) copolymers", J. Membr. Sci., 308, 96-106. https://doi.org/10.1016/j.memsci.2007.09.052.
  6. Dai, Y., Jian, X., Liu, X. and Guiver, M.D. (2001), "Synthesis and characterization of sulfonated poly (phthalazinone ether sulfone ketone) for ultrafiltration and nanofiltration membranes", J. Appl. Polym. Sci., 79, 1685. https://doi.org/10.1002/1097-4628 (20010228)79:9<1685::AID-APP180>3.0.CO;2-L.
  7. Dhandapani, K., Venugopal, K. and Kumar, J.V. (2019), "Ecofriendly and green synthesis of carbon nanoparticles from rice bran: characterization and identification using image processing technique", Int. J. Plast. Technol., 23(1), 56-66. https://doi.org/10.1007/s12588-019-09240-9.
  8. Dias, C.R., de Pinho, M.N. (1999), "Water structure and selective permeation of cellulose based membranes", J. Mol. Liq., 80(2-3), 117-132. https://doi.org/10.1016/S0167-7322(99)80003-8.dlrj
  9. Eman, S.M., Tarek, S.J., Heba, A., Youssef, H.F., Ahmed, M.S. and Eglal, R.S. (2019), "Desalting enhancement for blend polyethersulfone/polyacrylonitrile membranes using nano-zeolite A", Membr. Water Treat., 10(6), 451-460. https://doi.org/10.12989/mwt.2019.10.6.451.
  10. Fahimuddin, S., Anil, K.S. and Syed, M.A. (2016), "Detection and analysis of diabetic myonecrosis using an improved hybrid image processing model", Proceeding of 2nd International Conference on Advances in Electrical, Electronics, Information, Communication and Bio-Informatics, IEEE, February.
  11. Fu, R.Q., Xu, T.W., Wang, G., Yang, W.H. and Pan, Z.X. (2003), "PEG - catalytic water splitting in the interface of a bipolar membrane", J. Colloid Interf. Sci., 263(2), 386-390. https://doi.org/10.1016/S0021-9797(03)00307-2.
  12. Ganesan. P., Sathish, B.S., Joseph, L.M.I.L., Subramanian, K.M., Kalist, V. and Vasanth, K. (2019), "Retinal blood vessels and optical disc segmentation in branch retinal vein occluded fundus images using digital image processing techniques", Res. J. Pharm. Technol., 12(4), 1901-1906. https://doi.org/10.5958/0974-360X.2019.00313.5.
  13. Guan, R., Zou, H., Lu, D., Gong, C. and Liu, Y. (2005), "Polyether sulfone sulfonated by Chlorosulphonic acid and its membrane characteristics", Eur. Polym. J., 41(7), 1554-1560. https://doi.org/10.1016/j.eurpolymj.2005.01.018.
  14. Hao, J.H., Yu, L.X., Chen, C.X., Li, L. and Jiang, W.J. (2001), "Preparation of Bipolar Membranes (I)", J. Appl. Polym. Sci., 80(10), 1658-1663. https://doi.org/10.1002/app.1260.
  15. Hemalatha, R.J., Thamizhvani, T.R., Dhivya, A.J.A., Joseph, J.E., Babu, B. and Chandrasekaran, R. (2018), "Active contour based segmentation techniques for medical image analysis", Med. Biol. Image Anal., 4, 17. https://doi.org/10.5772/intechopen.74576.
  16. Jehad, M.S., Emad, M.A., Jamel, A.O. and Abdullah, M.N. (2020), "Water cost analysis of different membrane distillation process configurations for brackish water desalination", Membr. Water Treat., 11(5), 363-374. https://doi.org/10.12989/mwt.2020.11.5.363.
  17. Kim, J.S., Cho, E.H., Rhim, J.W., Park, C.J. and Park, S.G. (2015), "Preparation of bi-polar membranes and their application to hypochlorite production" Membr. Water Treat., 6(1), 27-42. https://doi.org/10.12989/mwt.2015.6.1.027.
  18. Kang, M.S., Tanioka, A. and Moon, S.H. (2002), "Effects of interface hydrophilicity and metallic compounds on water-splitting efficiency in bipolar membranes", Korean J. Chem. Eng., 19(1), 99-106. https://doi.org/10.1007/BF02706881.
  19. Kang, M.S., Choi, Y.J. and Moon, S.H. (2004), "Effects of inorganic substances on water splitting in ion-exchange membranes II: Optimal contents of inorganic substances in preparing bipolar membranes", J. Colloid Interf. Sci., 273(2), 533-539. https://doi.org/10.1016/j.jcis.2004.01.051.
  20. Kumar, M. and Shahi, V.K. (2010), "Heterogeneous-homogeneous composite bipolar membrane for the conversion of salt of homologous carboxylates into their corresponding acids and bases", J. Membr. Sci., 349(1-2), 130-137. https://doi.org/10.1016/j.memsci.2009.11.041.
  21. Lee, H., Sarfert, F., Strathmann, H. and Moon, S.H. (2002), "Designing of an electrodialysis desalination plant", Desalination, 142(3), 267-286. https://doi.org/10.1016/S0011-9164(02)00208-4.
  22. Lee, C. and Bae, S. (2019), "Special issue on advanced water treatment technologies", Membr. Water Treat., 10(3), 191-250. https://doi.org/10.12989/mwt.2019.10.3.191
  23. Nagarale, R.K., Gohil, G.S., Shahi, V.K. and Rangarajan, R. (2005), "Preparation and electrochemical characterization of sulfonated polysulfone cation-exchange membranes: Effects of the solvents on the degree of sulfonation", J. Appl. Polym. Sci., 96(6), 2344. https://doi.org/10.1002/app.21630.
  24. Nagarale, R.K., Gohil, G.S. and Shahi, V.K. (2006), "Recent developments on ion-exchange membranes and electro-membrane processes", Adv. Colloid Interf. Sci., 119, 97-130. https://doi.org/10.1016/j.cis.2005.09.005.
  25. Rad, A.E., Mohd Rahim, M.S. and Kolivand, H. (2017), "Morphological region-based initial contour algorithm for level set methods in image segmentation", Multimed Tools Application, 76, 21852201. https://doi.org/10.1007/s11042-015-3196-y.
  26. Sachdeva, S., Ram, R.P., Singh, J.K. and Kumar, A. (2008), "Synthesis of anion exchange polystyrene membranes for the electrolysis of sodium chloride" AIChE Journal, 54, 940-949. https://doi.org/10.1002/aic.11435
  27. Sathish, B.S., Ganesan, P., Leo Joseph, L.M.I., Palani, K. and Murugesan, R. (2021), "A two-level approach to color space-based image segmentation using genetic algorithm and feed-forward neural network", Adv. Intell. Sys. Comput., 1133, 67-78. https://doi.org/10.1007/978-981-15-3514-7_6.
  28. Strathmann, H., Krol, J.J., Rapp, H.J. and Eigenberger, G. (1997), "Limiting current density and water dissociation in bipolar membranes", J. Membr. Sci., 125(1), 123-142. https://doi.org/10.1016/S0376-7388(96)00185-8.
  29. Subhankar, B., Sanghamitra, M., Malini, B., Deepthi, M.V. and Sailaja, R.R.N. (2018), "Polysulfone/nanocomposites mixed matrix ultrafiltration membrane for the recovery of Maillard reaction products", Membr. Water Treat., 9(2), 105-113. https://doi.org/10.12989/mwt.2018.9.2.105.
  30. Tanaka, Y. (2007), "Water dissociation", Membr. Sci. Technol., 12, 139-185. https://doi.org/10.1016/S0927-5193(07)12008-8.
  31. Tanioka, A., Shimizu, K., Hosono, T., Eto, R. and Osaki, T. (1999), "Effect of interfacial state in bipolar membrane on rectification and water splitting", Colloids Surf A, 159(2-3), 395-404. https://doi.org/10.1016/S0927-7757(99)00315-5.
  32. Venugopal, K. and Dharmalingam, S. (2016), "Composite ion exchange membrane based electrodialysis cell for desalination as well as acid and alkali productions", Int. J. Trend Res. Develop., 3(2), 631-640.
  33. Venugopal, K., Murugappan, M. and Dharmalingam, S. (2017), "Acid and base recovery from brine solution using PVP intermediate-based bipolar membrane through water splitting technology", Appl. Water Sci., 7(4), 1747-1759. https://doi.org/10.1007/s13201-015-0346-3.
  34. Vyas, P.V., Shah, B.G., Trivedi, G.S., Ray, P., Adhikary, S.K. and Rangarajan, R. (2001), "Characterization of heterogeneous anion-exchange membrane", J. Membr. Sci., 187(1-2), 39-46. https://doi.org/10.1016/S0376-7388(00)00613-X.
  35. Wilhelm, F.G., Punt, I., van der Vegt, N.F.A., Wessling, M. and Strathmann, H. (2001), "Optimization strategies for the preparation of bipolar membranes with reduced salt ion leakage in acid-base electrodialysis", J. Membr. Sci., 182(1-2), 13-28. https://doi.org/10.1016/S0376-7388(00)00519-6.