한국분말재료학회지 (Journal of Powder Materials)

  • 제28권4호
  • /
  • Pages.293-300
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  • 2021
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  • 2799-8525(pISSN)
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  • 2799-8681(eISSN)
한국분말재료학회 (*구 분말야금학회) (The Korean Powder Metallurgy & Materials Institute)
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Fe83.2Si5.33-0.33xB10.67-0.67xPxCu0.8 나노결정질 연자성 합금의 P함량에 따른 미세구조 및 자기적 특성 변화 관찰에 관한 연구

A Study on the Microstructure and Magnetic Properties of Fe83.2Si5.33-0.33xB10.67-0.67xPxCu0.8 Nanocrystalline Soft Magnetic Alloys with varying P Content

  • 임현아 (한국재료연구원 분말재료연구본부) ;
  • 배경훈 (한국재료연구원 분말재료연구본부) ;
  • 남영균 (한국재료연구원 분말재료연구본부) ;
  • 안수봉 (한국재료연구원 분말재료연구본부) ;
  • 양상선 (한국재료연구원 분말재료연구본부) ;
  • 김용진 (한국재료연구원 분말재료연구본부) ;
  • 이정우 (부산대학교 재료공학부) ;
  • 정재원 (한국재료연구원 분말재료연구본부)
  • Im, Hyun Ah (Metal Powder Department, Korea Institute of Materials Science (KIMS)) ;
  • Bae, Kyoung-Hoon (Metal Powder Department, Korea Institute of Materials Science (KIMS)) ;
  • Nam, Yeong gyun (Metal Powder Department, Korea Institute of Materials Science (KIMS)) ;
  • An, Subong (Metal Powder Department, Korea Institute of Materials Science (KIMS)) ;
  • Yang, Sangsun (Metal Powder Department, Korea Institute of Materials Science (KIMS)) ;
  • Kim, Yong-Jin (Metal Powder Department, Korea Institute of Materials Science (KIMS)) ;
  • Lee, Jung Woo (Department of Materials Science and Engineering, Pusan National University) ;
  • Jeong, Jae Won (Metal Powder Department, Korea Institute of Materials Science (KIMS))
  • 투고 : 2021.04.15
  • 심사 : 2021.04.29
  • 발행 : 2021.08.28
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초록

We investigate the effect of phosphorous content on the microstructure and magnetic properties of Fe83.2Si5.33-0.33xB10.67-0.67xPxCu0.8 (x = 1-4 at.%) nanocrystalline soft magnetic alloys. The simultaneous addition of Cu and P to nanocrystalline alloys reportedly decreases the nanocrystalline size significantly, to 10-20 nm. In the P-containing nanocrystalline alloy, P atoms are distributed in an amorphous residual matrix, which suppresses grain growth, increases permeability, and decreases coercivity. In this study, nanocrystalline ribbons with a composition of Fe83.2Si5.33-0.33xB10.67-0.67xPxCu0.8 (x = 1-4 at.%) are fabricated by rapid quenching melt-spinning and thermal annealing. It is demonstrated that the addition of a small amount of P to the alloy improves the glass-forming ability and increases the resistance to undesirable Fex(B,P) crystallization. Among the alloys investigated in this work, an Fe83.2Si5B10P1Cu0.8 nanocrystalline ribbon annealed at 460℃ exhibits excellent soft-magnetic properties including low coercivity, low core loss, and high saturation magnetization. The uniform nanocrystallization of the Fe83.2Si5B10P1Cu0.8 alloy is confirmed by high-resolution transmission electron microscopy analysis.

키워드

과제정보

This research was supported by Civil-Military Technology Cooperation Program (18-CM-MA-15).

참고문헌

  1. J. Qiao and J. M. Pelletier: J. Mater. Sci. Technol., 30 (2014) 523. https://doi.org/10.1016/j.jmst.2014.04.018
  2. O. Gutfleisch, M. A. Willard, E. Bruck, C. H. Chen, S. G. Sankar and J. P. Liu: Adv. Mater., 23 (2011) 821. https://doi.org/10.1002/adma.201002180
  3. H. Shokrollahi and K. Janghorban: J. Mater. Process. Technol., 189 (2007) 1. https://doi.org/10.1016/j.jmatprotec.2007.02.034
  4. K. Takenakam, A. D. Setyawan, P. Sharma, N. Nishiyama and A. Makino: J. Magn. Magn. Mater., 401 (2016) 479. https://doi.org/10.1016/j.jmmm.2015.10.091
  5. J. D. Ayers, V. G. Harris, J. A. Sprague, W. T. Elam and H. N. Jones: Acta Mater., 46 (1998) 1861. https://doi.org/10.1016/S1359-6454(97)00436-9
  6. G. Herzer: J. Magn. Magn. Mater., 112 (1992) 258. https://doi.org/10.1016/0304-8853(92)91168-S
  7. X. D. Fan, H. Men, A. B. Ma and B. L. Shen: J. Magn. Magn. Mater., 326 (2013) 22. https://doi.org/10.1016/j.jmmm.2012.08.045
  8. G. Herzer: Soft Magnetic Materials-Nanocrystalline Alloys, Handbook of Magnetism and Advanced Magnetic Materials, (2007).
  9. T. Kulik: J. Non-Cryst. Solids, 287 (2001) 145. https://doi.org/10.1016/S0022-3093(01)00627-5
  10. T. Bitoh, A. Makino, A. Inoue and T. Masumoto: Mater. Trans., 44 (2003) 2011. https://doi.org/10.2320/matertrans.44.2011
  11. G. Herzer: Mater. Sci. Eng . A, 133 (1991) 1. https://doi.org/10.1016/0921-5093(91)90003-6
  12. M. Shi, R. Li, J. Wang, Z. Liu, X. Luo and T. Zhang: Philos. Mag. Lett., 93 (2013) 2182. https://doi.org/10.1080/14786435.2013.765986
  13. K. Suzuki, N. Kataoka, A. Inoue, A. Makino and T. Masumoto: Mater. Trans. JIM, 31 (1990) 743. https://doi.org/10.2320/matertrans1989.31.743
  14. Y. Yoshizawa, S. Oguma and K. Yamauchi: J. Appl. Phys., 64 (1988) 6044. https://doi.org/10.1063/1.342149
  15. Y. Yoshizawa and K. Yamauchi: Mater. Trans. JIM, 31 (1990) 307. https://doi.org/10.2320/matertrans1989.31.307
  16. H. R. Lashgari, D. Chu, S. Xie, H. Sun, M. Ferry and S. Li: J. Non-Cryst. Solids, 391 (2014) 61. https://doi.org/10.1016/j.jnoncrysol.2014.03.010
  17. A. Makino, T. Kubota, K. Yubuta, A. Inoue, A. Urata, H. Matsumoto and S. Yoshida: J. Appl. Phys., 109 (2011) 07A302. https://doi.org/10.1063/1.3535169
  18. A. D. Wang, H. Men, B. L. Shen, G. Q. Zie, A. Makino and A. Inoue: Thin Solid Films, 519 (2011) 8283 https://doi.org/10.1016/j.tsf.2011.03.110
  19. R.-M. Shi, Z. Wang, Y.-Y. Jia, Z.-P. Wen, B.-W. Wang and T. Zhang: J. Appl. Phys., 112 (2012) 08922.
  20. A. Makino, T. Kubota, M. Makabe, C. T. Chang and A. Inoue: Mater. Sci. Forum, 561-565 (2007) 1361.