열분해분석법을 이용한 고무 소재의 화학구조 분석 기법

  • Published : 2021.06.30

Abstract

Keywords

References

  1. R. S. Silas, J. Yates, and V. Thorton, "Determination of unsaturation distribution in polybutadienes by infrared spectrometry", Anal. Chem., 31, 529 (1959). https://doi.org/10.1021/ac50164a022
  2. D. L. Snavely and C. Angevine, "Near-IR spectrum of polybutadiene", J. Polym. Sci. A: Polym. Chem., 34, 1669 (1996). https://doi.org/10.1002/(SICI)1099-0518(19960715)34:9<1669::AID-POLA4>3.0.CO;2-N
  3. R. G. J. Miller and H. A. Willis, "Laboratory methods in vibrational spectroscopy", J. Appl. Chem., 6, 385 (1956). https://doi.org/10.1002/jctb.5010060903
  4. J. L. Binder, "Infrared spectra of polybutadienes", J. Polym. Sci. A, 3, 1597 (1965).
  5. J. Guilment and L. Bokobza, "Determination of polybutadiene microstructures and styrene-butadiene copolymers composition by vibrational techniques combined with chemometric treatment", Vib. Spectrosc., 26, 133 (2001). https://doi.org/10.1016/S0924-2031(01)00111-4
  6. G. Meszlenyi and G. Kortvelyessy, "Direct determination of vinyl acetate content of ethylene vinyl acetate copolymers in thick films by infrared spectroscopy", Polym. Test., 18, 551 (1999). https://doi.org/10.1016/S0142-9418(98)00053-1
  7. I. Poljansek, E. Fadjan, K. Burja, and D. Kukanja, "Emulsion copolymerization of vinyl acetate-ethylene in high pressure reactor-characterization by inline FTIR spectroscopy", Prog. Org. Coat., 76, 1798 (2013). https://doi.org/10.1016/j.porgcoat.2013.05.019
  8. R. J. Koopmans, R. van der Linden, and E. F. Vansnat, "The characterisation of newly developed and promising hydrolyzed ethylene vinyl acetate copolymers", J. Adhesion, 11, 191 (1980). https://doi.org/10.1080/00218468008078916
  9. Y. Kim and S.-S. Choi, "Microstructural analysis of SBR blends using infrared spectroscopy", Elast. Compos., 49, 103 (2014). https://doi.org/10.7473/EC.2014.49.2.103
  10. H. J. Harwood, "Characterization of the structures of diene polymers by NMR", Rubber Chem. Technol., 55, 769 (1982). https://doi.org/10.5254/1.3535903
  11. G. Van der Velden, C. Didden, T. Veermans, and J. Beulen, "A new method for the microstructure determination of polybutadiene with cis-1, 4, trans-1, 4, and vinyl-1, 2 units by carbon-13 NMR", Macromolecules, 20, 1252 (1987). https://doi.org/10.1021/ma00172a016
  12. G. P. M. Van der Velden and L. J. Fetters, "Microstructure determination of nondeuterated, partially deuterated, and perdeuterated polybutadienes with cis-1, 4, trans-1, 4, and vinyl-1, 2 units by carbon-13 NMR", Macromolecules, 23, 2470 (1990). https://doi.org/10.1021/ma00211a011
  13. S.-S. Choi, Y. Kim, and H.-M. Kwon, "Microstructural analysis and cis-trans ₩isomerization of BR and SBR vulcanizates reinforced with silica and carbon black using NMR and IR", RSC Adv., 4, 31113 (2014). https://doi.org/10.1039/C4RA03682D
  14. E. Kim and S.-S. Choi, "Comparison of vinyl acetate contents of poly(ethylene-co-vinyl acetate) analyzed by IR, NMR, and TGA", Elast. Compos., 50, 18 (2015). https://doi.org/10.7473/EC.2015.50.1.018
  15. S.-S. Choi and O.-B. Kim, "Change of terminal type of alkylphenol formaldehyde resole by thermal treatment", J. Ind. Eng. Chem., 30, 120 (2015). https://doi.org/10.1016/j.jiec.2015.05.012
  16. S.-S. Choi and O.-B. Kim, "Mass spectrometric monitoring of change of resole structures by compounding and curing of EPDM compound", Polym. Test., 58, 181 (2017). https://doi.org/10.1016/j.polymertesting.2016.12.032
  17. S.-S. Choi and S.-H. Ha, "Influence of sample preparation method and silver salt types on MALDI-TOFMS analysis of polybutadiene", Macromol. Res., 16, 108 (2008). https://doi.org/10.1007/BF03218838
  18. S.-S. Choi and H.-S. Chung, "Novel co-matrix systems for the MALDI-MS analysis of polystyrene using a UV absorber and stabilizer", Analyst, 138, 1256 (2013). https://doi.org/10.1039/c2an35718f
  19. S.-S. Choi, "Correlation of crosslink density with pyrolysis pattern of natural rubber vulcanizates with efficient vulcanizing cure system", J. Anal. Appl. Pyrolysis, 52, 105 (1999). https://doi.org/10.1016/S0165-2370(99)00041-8
  20. S.-S. Choi, "Characterization of bound rubber of filled styrene-butadiene rubber compounds using pyrolysis-gas chromatography", J. Anal. Appl. Pyrolysis, 55, 161 (2000). https://doi.org/10.1016/S0165-2370(99)00095-9
  21. S.-S. Choi, "Characteristics of pyrolysis patterns of polybutadienes with different microstructures", J. Anal. Appl. Pyrolysis, 57, 249 (2001). https://doi.org/10.1016/S0165-2370(00)00134-0
  22. S.-S. Choi, "Characteristics of pyrolysis pattern of styrene-butadiene rubbers with differing microstructures", J. Anal. Appl. Pyrolysis, 62, 319 (2002). https://doi.org/10.1016/S0165-2370(01)00128-0
  23. S.-S. Choi and D.-H. Han, "Pyrolysis of maleic anhydride-treated polybutadiene", J. Anal. Appl. Pyrolysis, 78, 58 (2007). https://doi.org/10.1016/j.jaap.2006.04.004
  24. S.-S. Choi and D.-H. Han, "Pyrolysis behaviors of poly(acrylonitrile-co-butadiene) with differing microstructures", J. Anal. Appl. Pyrolysis, 80, 53 (2007). https://doi.org/10.1016/j.jaap.2006.12.032
  25. S.-S. Choi and Y.-K. Kim, "Analysis of 5-ethylidene-2-norbornene in ethylene-propylene-diene terpolymer using pyrolysis-GC/MS", Polym. Test., 30, 509 (2011). https://doi.org/10.1016/j.polymertesting.2011.04.005
  26. S.-S. Choi and Y.-K. Kim, "Formation of C7-species pyrolysis products from ethylene-propylene heterosequences of poly(ethylene-co-propylene)", J. Anal. Appl. Pyrolysis, 92, 384 (2011). https://doi.org/10.1016/j.jaap.2011.07.014
  27. S.-S. Choi and Y.-K. Kim, "Analysis of pyrolysis products formed from ethylene-tetrafluoroethylene heterosequences of poly(ethylene-co-tetrafluoroethylene)", J. Anal. Appl. Pyrolysis, 92, 470 (2011). https://doi.org/10.1016/j.jaap.2011.09.001
  28. S.-S. Choi and Y.-K. Kim, "Microstructural analysis of poly(vinylidene fluoride) using benzene derivative pyrolysis products", J. Anal. Appl. Pyrolysis, 96, 16 (2012). https://doi.org/10.1016/j.jaap.2012.02.014
  29. S.-S. Choi and H.-M. Kwon, "Characterization of pyrolysis products formed from styrene-1,2-unit heterosequence of styrene-butadiene copolymer", J. Anal. Appl. Pyrolysis, 99, 1 (2013). https://doi.org/10.1016/j.jaap.2012.11.014
  30. S.-S. Choi and Y.-K. Kim, "Analysis of pyrolysis products of poly(vinylidene fluoride-co-hexafluoro-propylene) by pyrolysis-gas chromatography/mass spectrometry", J. Fluor. Chem., 165, 33 (2014). https://doi.org/10.1016/j.jfluchem.2014.06.004
  31. S.-S. Choi and H.-M. Kwon, "Analytical method for determination of butadiene and styrene contents of styrene-butadiene rubber vulcanizates without pretreatment using pyrolysis-gas chromatography/mass spectrometry", Polym. Test., 38, 87 (2014). https://doi.org/10.1016/j.polymertesting.2014.07.005
  32. S.-S. Choi and H.-M. Kwon, "Analytical method for determination of microstructures of solution styrene-butadiene copolymers using 2-phenylpropene/styrene ratio of pyrolysis products", Polym. Test., 44, 153 (2015). https://doi.org/10.1016/j.polymertesting.2015.04.005
  33. S.-S. Choi and E. Kim, "Analysis of pyrolysis products of ethylene-vinyl acetate coploymer (EVA) using pre-deacetylation", J. Anal. Appl. Pyrolysis, 127, 1 (2017). https://doi.org/10.1016/j.jaap.2017.09.015
  34. S.-S. Choi and E. Kim, "Pyrolysis behaviors of deacetylated poly(ethylene-co-vinyl acetate) depending on pyrolysis temperature", J. Anal. Appl. Pyrolysis, 130, 29 (2018). https://doi.org/10.1016/j.jaap.2018.02.001
  35. S.-S. Choi and H.-M. Kwon, "Considering factors on determination of microstructures of SBR vulcanizates using pyrolytic analysis", Polym. Test., 89, 106572 (2020). https://doi.org/10.1016/j.polymertesting.2020.106572
  36. 최성신, "적외선(IR) 분광법을 이용한 고무 소재의 원재료 분석 기법", 고무기술지, 20, 171 (2019).
  37. 최성신, "핵자기공명분광법(NMR)을 이용한 고무 소재 원재료 분석 기법", 고무기술지, 20, 249 (2019).
  38. 최성신, "질량분석법(MS)을 이용한 고무 소재의 원재료 분석 기법", 고무기술지, 21, 11 (2020).
  39. 최성신, "기체 크로마토그래피(GC)를 이용한 고무 첨가제와 추출물의 분리분석 기법", 고무기술지, 21, 68 (2020).
  40. S.-S. Choi, "Variation of pyrolysis pattern of polyisoprene depending on temperature", Bull. Korean Chem. Soc., 20, 1348 (1999). https://doi.org/10.5012/BKCS.1999.20.11.1348
  41. S.-S. Choi and J.-E. Ko, "Influence of thermal aging on pyrolysis pattern of carbon black-filled NR composite", Macromol. Res., 15, 482 (2007). https://doi.org/10.1007/BF03218819
  42. S.-S. Choi and D.-H. Han, "Pyrolysis paths of polybutadiene depending on pyrolysis temperature", Macromol. Res., 14, 354 (2006). https://doi.org/10.1007/BF03219094