한국재료학회지 (Korean Journal of Materials Research)

  • 제31권4호
  • /
  • Pages.224-231
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  • 2021
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  • 1225-0562(pISSN)
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  • 2287-7258(eISSN)
한국재료학회 (Materials Research Society of Korea)
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Facile Synthesis and Characterization of Reduced Graphene Oxide-Zinc Ferrite Nanocomposite as Adsorbent in Aqueous Media

  • Johra, Fatima Tuz (Department of Materials Science and Engineering, Kookmin University) ;
  • Jung, Woo-Gwang (Department of Materials Science and Engineering, Kookmin University)
  • 투고 : 2021.03.10
  • 심사 : 2021.04.15
  • 발행 : 2021.04.27
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초록

Here, Zn ferrite is synthesized along with reduced graphene oxide (rGO) by a facile one-step hydrothermal method. The difference between the synthesized nanocomposites with those in other reported work is that the reaction conditions in this work are 160 ℃ for 12 h. The synthesized products are characterized by field-emission scanning electron microscopy, X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, and attenuated total reflection. Further, the adsorption property of rGO-Zn ferrite (rGZF) nanocomposite is studied after confirming its successful synthesis. The adsorption capacity of rGZFs toward rhodamine B (RB) is > 9.3 mg/g, whereas that of bare ZF nanoparticles is 1.8 mg/g in aqueous media. The efficiencies of rGZF and bare ZF to remove RB are 99 % and 20 %, respectively. Employing rGZF, 60 % of RB is decomposed within 5 min. The kinetic study reveals that the adsorption process of removing RB by bare Zn ferrite follows pseudo-first-order kinetics. However, after zinc ferrite is incorporated with rGO, the kinetics changes to pseudo-second-order. Furthermore, the Langmuir isotherm is accomplished by the adsorption process employing rGZF, indicating that a monolayer adsorption process occurs. The thermodynamic parameters of the process are also calculated.

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과제정보

This study was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF), funded by the Ministry of Education, Science and Technology (NRF-2016R1D1A1A09917165).

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