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Ferrate(VI)를 이용한 다양한 수중 환경에서의 tetracycline의 분해 특성 및 반응 경로 연구

Degradation characteristics and reaction pathways of tetracycline by ferrate(VI) in various aqueous conditions

  • 박경덕 (부경대학교 지구환경시스템과학부) ;
  • 김일규 (부경대학교 환경공학과)
  • Park, Kyeong-Deok (Division of Earth Environmental System Science, Pukyong National University) ;
  • Kim, Il-Kyu (Department of Environmental Engineering, Pukyong National University)
  • 투고 : 2020.10.16
  • 심사 : 2020.12.20
  • 발행 : 2021.02.15

초록

Tetracycline is one of the most commonly used as antibiotics for the livestock industry and it is still widely used nowadays. Tetracycline and its metabolites are excreted with excrement, which is difficult to completely removed with conventional sewage treatment, therefore it is apprehended that the tetracycline-resistant bacteria occurs. In this study, the oxidant named ferrate(VI) was used to degrade the tetracycline and investigate the reaction between ferrate(VI) and tetracycline under various aqueous conditions. The highest degradation efficiency of tetracycline occurred in basic condition (pH 10.1 ± 0.1) because of the pKa values of tetracycline and ferrate(VI). The results also showed the effect of water temperature on the degradation of tetracycline was not significant. In addition, the dosage of ferrate(VI) was higher, the degradation of tetracycline and the self-degradation of ferrate(VI) also higher, finally the efficiency of ferrate(VI) was lower. The results said that the various mechanisms effects the reaction of ferrate(VI) oxidation, it required the consideration of the characteristics of the target compound for optimal degradation efficiency. Additionally, intermediate products were detected with LC/MS/MS and three degradation pathways were proposed.

키워드

과제정보

이 논문은 2019년도 부경대학교 연구년 교수 지원사업에 의하여 연구되었음.

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