Applied Chemistry for Engineering (공업화학)

The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
권호 표지
DOI QR코드

DOI QR Code

Adsorption Behavior of Heavy Metals and Organics in the Mixed Packed Column of Scoria/Activated Carbon

스코리아/활성탄의 혼합 충전탑에서의 중금속 및 유기물의 흡착 거동

  • Kim, Seung-Geon (Department of Chemical and Biological Engineering, Jeju National University) ;
  • Moon, Soo-Hyoung (Water Resources Research Team, Jeju Province Development Co.) ;
  • Lee, Ho-Won (Department of Chemical and Biological Engineering, Jeju National University)
  • 김승건 (제주대학교 생명화학공학과) ;
  • 문수형 (제주특별자치도개발공사 수자원연구팀) ;
  • 이호원 (제주대학교 생명화학공학과)
  • Received : 2021.01.04
  • Accepted : 2021.01.20
  • Published : 2021.02.10
Download PDF
⟨ Previous Next ⟩

Abstract

Adsorption properties of heavy metals and organics in the mixed packed column of scoria and activated carbon, as well as physicochemical properties and functional groups of scoria were investigated. As the mixing ratio of scoria increased, the average removal ratios of cadmium, nickel, chromium, and lead ions increased, but that of benzene and toluene decreased. The mixed packed column of scoria and activated carbon could be effectively used for the simultaneous removal of heavy metals and organics. Scoria has Si-H and Si-O functional groups, and it was confirmed that Si-O functional groups greatly contributed to the adsorption of heavy metals.

스코리아와 활성탄의 혼합 충전탑에서 중금속과 유기물의 흡착 특성, 스코리아의 물리화학적 특성과 관능기를 조사하였다. 스코리아의 혼합비율이 증가할수록 카드뮴, 니켈, 크롬, 납 이온의 평균제거율은 증가하였으나, 벤젠과 톨루엔의 평균 제거율은 감소하였다. 스코리아와 활성탄의 혼합 충전탑은 중금속과 유기물의 동시 제거에 효과적으로 사용될 수 있었다. 스코리아는 Si-H와 Si-O 작용기를 갖고 있으며, 이중 Si-O 관능기가 중금속의 흡착에 크게 기여함을 확인할 수 있었다.

Keywords

References

  1. S. P. Park, A study on Jeju island side volcano, J. Chonnam National University, 30, 159-166 (1985).
  2. J. M. Morgan-Sagastume and A. Noyola, Evaluation of an aerobic submerged filter packed with volcanic scoria, Bioresour. Technol., 99, 2528-2536 (2008). https://doi.org/10.1016/j.biortech.2007.04.068
  3. C. H. Jeong and G. Y. Jeong, Effect of groundwater anions and pH on the sorption removal of heavy metals by bentonite, Econ. Environ. Geol., 33, 31-40 (2000).
  4. U. Wingenfelder, C. Hansen, G. Furrer and R. Schulin, Removal of heavy metals from mine waters by natural zeolites, Environ. Sci. Technol., 39, 4606-4613 (2005). https://doi.org/10.1021/es048482s
  5. M. G. Fonseca, M. M. Oliveira and L. N. H, Removal of cadmium, zinc, manganese and chromium cations from aqueous solution by a clay mineral, J. Hazard. Mater., B137, 288-292 (2006).
  6. J. H. Potgieter, S. S. Potgieter-Vermaak and P. D. Kalibantona, Heavy metals removal from solution by palygorskite clay, Miner. Eng., 19, 463-470 (2006). https://doi.org/10.1016/j.mineng.2005.07.004
  7. S. H. Moon, H. W. Lee, J. H. Kim, K. K. Kang and Y. S. Mok, Characteristics of volcanic cinders and their adsorption trait for heavy metal removal, Res. J. Chem. Environ., 15, 920-927 (2011).
  8. M. Yavuz, F. Gode, E. Pehlivan, S. Ozmert and Y. C. Sharma, An economic removal of Cu2+ and Cr3+ on the new adsorbents: Pumice and polyacrylonitrile/pumice composite, Chem. Eng. J., 137, 453-461 (2007). https://doi.org/10.1016/j.cej.2007.04.030
  9. M. R. Moufti, A. A. Sabtan, O. R. El-mahsy and W. M. Shehata, Assessment of the industrial utilization of scoria materials in central Harrat Rahat, Eng. Geol., 57, 155-162 (2000). https://doi.org/10.1016/S0013-7952(00)00024-7
  10. T. Depci, T. Efe, M. Tapan, A. Ozvan, M. Aclan and T. Uner, Chemical characterization of patnos scoria, Physicochem. Probl. Miner. Process, 48, 303-315 (2012).
  11. M. Selvaraj, B. H. Kim and T. G. Lee, FTIR studies on selected mesoporous metallosilicate molecular sieves, Chem. Lett., 34, 1290-1291 (2005). https://doi.org/10.1246/cl.2005.1290
  12. D. Stryahilev, F. Diehl and B. Schroder, The splitting of absorption bands in IR spectra of anisotropic SiH monolayers covering the internal surfaces in μc-Si:H, J. Non-Crystalline Solids, 266-269, 166-170 (2000). https://doi.org/10.1016/S0022-3093(99)00800-5