DOI QR코드

DOI QR Code

Hybrid neutralization and membrane process for fluoride removal from an industrial effluent

  • Meftah, Nouha (University of Gabes, National Engineering School of Gabes, Chemical Process Engineering Department, Process Engineering and Industrial System Research Laboratory) ;
  • Ezzeddine, Abdessalem (University of Gabes, National Engineering School of Gabes, Chemical Process Engineering Department, Process Engineering and Industrial System Research Laboratory) ;
  • Bedoui, Ahmed (University of Gabes, Faculty of Sciences of Gabes, Department of Chemistry) ;
  • Hannachi, Ahmed (University of Gabes, National Engineering School of Gabes, Chemical Process Engineering Department, Process Engineering and Industrial System Research Laboratory)
  • Received : 2019.11.27
  • Accepted : 2020.05.18
  • Published : 2020.07.25

Abstract

This study aims to investigate at a laboratory scale fluorides removal from an industrial wastewater having excessive F- concentration through a hybrid process combining neutralization and membrane separation. For the membrane separation operation, both Reverse Osmosis (RO) and Nanofiltration (NF) were investigated and confronted. The optimized neutralization step with hydrated lime allowed reaching fluoride removal rates of 99.1± 0.4 %. To simulate continuous process, consecutive batch treatments with full recirculation of membrane process brines were conducted. Despite the relatively high super saturations with respect to CaF2, no membrane cloaking was observed. The RO polishing treatment allowed decreasing the permeate fluoride concentration to 0.9± 0.3 mg/L with a fluoride rejection rate of 93± 2% at the optimal transmembrane pressure of around 100 psi. When NF membrane was used to treat neutralization filtrate, the permeate fluoride concentration dropped to 1.1± 0.4 mg/L with a fluoride rejection rate of 88± 5% at the optimal pressure of around 80 psi. Thus, with respect to RO, NF allowed roughly 20% decrease of the driving pressure at the expense of only 5% drop of rejection rate. Both NF and RO permeates at optimal operating transmembrane pressures respect environmental regulations for reject streams discharge into the environment.

Keywords

References

  1. Adimalla, N., Marsetty, S. K. and Xu, P. (2019), "Assessing groundwater quality and health risks of fluoride pollution in the Shasler Vagu (SV) watershed of Nalgonda, India", Human Ecological Risk Assessment J., 1-20. https://doi.org/10.1080/10807039.2019.1594154.
  2. Ahada, C. P. and Suthar, S. (2017), "Assessment of human health risk associated with high groundwater fluoride intake in southern districts of Punjab", Exposure Health, India, https://doi.org/10.1007/s12403-017-0268-4.
  3. Albustami S. F. and Hilakosa S. W. (2014), "FSA Neutralization with Calcium Compounds", Procedia Engineering, 83, 286-290. https://doi.org/10.1016/j.proeng.2014.09.007.
  4. APHA (1998), "Standard Methods for the Examination of Water and Wastewater, twentieth edition. American Public Health Association/American Water Works Association/Water Environment Federation", Washington, DC., USA.
  5. Bejaoui I., Mnif A. and Hamrouni B. (2014), "Performance of reverse osmosis and nanofiltration in the removal of fluoride from model water and metal packaging industrial effluent", Separation Sci. Technol., 49, 1135-1145. https://doi.org/10.1080/01496395.2013.878956.
  6. Benamor T., Kassem M., Hajjaji W., Jamoussi F., Benamor M. and Hafiane A. (2018), "Stugy of defluoridation of water using natural clay minerals", Clays Clay Minerals, 66(6), 493-499. https://doi.org/10.1346/CCMN.2018.064117.
  7. Ben Rejeb F., Yacoubi S. and Hannachi A. (2019), "Steady state simulation for predicting some calcium salts supersaturation in polluted coastal region seawater", J. Biodiversity Environ. Sci., 15(6), 122-132.
  8. Boubakri A., Helali N., Tlili M. and Amor M. B. (2014), "Fluoride removal from diluted solutions by Donnan dialysis using full factorial design", Korean J. Chem. Eng., 31(3), 461-466. https://doi.org/10.1007/s11814-013-0263-9.
  9. Bouhadjar S. I., Kopp H., Britsch P., Deowan S. A., Hoinkis J. and Bundschuh J. (2019), "Solar powered nanofiltration for drinking water production from fluoride-containing groundwater-A pilot study towards developing a sustainable and low-cost treatment plant", J. Environ. Manage., 231, 1263-1269. https://doi.org/10.1016/j.jenvman.2018.07.067.
  10. Dhillon A., Prasad S. and Kumar D. (2016), "Recent advances and spectroscopic perspectives in fluoride removal", Appl. Spectroscopy Rev., 45, 175-230. http://dx.doi.org/10.1080/05704928.2016.1213737.
  11. Elfil H. and Hannachi A. (2006), "Reconsidering water scaling tendency", Assessment, AIChE J., 52(10), 3583-3591. https://doi.org/10.1002/aic.10965
  12. Ezzeddine A., Bedoui A., Hannachi A. and N. Bensalah (2014a), "Removal of fluoride from aluminum fluoride manufacturing wastewater by precipitation and adsorption processes", Desalination Water Treat., 54, 2280-2292. http://dx.doi.org/10.1080/19443994.2014.899515.
  13. Ezzeddine A., Meftah N. and Hannachi A. (2014b), "Removal of fluoride from an industrial wastewater by a hybrid process combining precipitation and reverse osmosis", Desalination Water Treat., 55, 2618-2625. http://dx.doi.org/10.1080/19443994.2014.959737.
  14. Ezzeddine A. and Hannachi A. (2017), "Use of natural Tunisian clays for defluoridation of industrial wastewater", Desalination Water Treat., 87, 188-198. https://doi.org/10.5004/dwt.2017.20979.
  15. Fordyce F. M. (2011), "Fluorine: human health risks", Encyclopedia of Environmental Health, Burlington: Elsevier, 2, 776-785. https://doi.org/10.1016/B978-0-444-52272-6.00697-8
  16. Harrak N. L., Elazhar F., Belhamidi S., Elazhar M., Touir J. and Elmidaoui A. (2015), "Performances comparison of two membranes processes: Nanofiltration and reverse osmosis in brackish water desalination", J. Mater. Environ. Sci., 6(2), 383-390.
  17. Hchaichi H., Elfil H., Guichardon P. and Hannachi H. (2013), "Scaling tendency assessment in reverse osmosis modules", Desalination Water Treat., 51, 892-898. https://doi.org/10.1080/19443994.2012.715410
  18. Kabir H., Kumar Gupta A. and Tripathy S. (2019), "Fluoride and human health: Systematic appraisal of sources, exposures, metabolism, and toxicity", Critical Rev. Environ. Sci. Technol., 1-78. https://doi.org/10.1080/10643389.2019.1647028.
  19. Kawakami T., Nishino M., Imai Y., Miyazaki H. and Amarasooriya A. G. (2018), "De-fluoridation of drinking water by co-precipitation with magnesium hydroxide in electrolysis", Cogent Eng., 5, 84-98. https://doi.org/10.1080/23311916.2018.1558498.
  20. McCann, H. G. (1968), "The solubility of fluorapatite and its relationship to that of calcium fluoride", Arch. Oral Biology, 13, 987-1001. https://doi.org/10.1016/0003-9969(68)90014-9
  21. McCann, H. G. (1968), "The solubility of fluorapatite and its relationship to that of calcium fluoride", Arch. Oral Biology, 13(8), 987-1001. https://doi:10.1016/0003-9969(68)90014-9.
  22. Meftah, N., Mejdi, M., Ezzeddine, A., Bedoui, A. and Hannachi, A. (2020), "Nanofiltration polishing membrane process for fluoride removal", Desalination Water Treat. (Accepted). https://doi.org/10.5004/dwt.2020.26029.
  23. Minyaoui, K., Hchaichi, H., Pontie, M. and Hannachi, A. (2017), "Integrated approach for brackish water desalination and distribution: which desalination technology to choose?", Desalination Water Treat., 73, 121-126. https://doi.org/10.5004/dwt.2017.20861.
  24. Owusu-Agyeman, I., Reinwald, M., Jeihanipour, A. and Chafer, A.I. (2019), "Removal of fluoride and natural organic matter from natural tropical brackish waters by nanofiltration/reverse osmosis with varying water chemistry", Chemosphere, 217, 47-58. https://doi.org/10.1016/j.chemosphere.2018.10.135.
  25. Patnaik, P.C., Swain, S.K., Patel, S.B., Patnaik, T., Muller, F., Delpeux-Ouldriane, S. and Dey, R.K. (2018), "Kinetics and thermodynamics of defluoridation of drinking water using high performance hybrid zirconium (IV)-hexamethylenediamine: A comparative aspect with ion-exchanger amorphous zirconium (IV) phosphate", Surfaces Interfaces, 13, 22-32. https://doi.org/10.1016/j.surÞn.2018.07.001.
  26. Ram, B.J. (2017), "Concentrations of fluoride in water and plasma for US children and adolescents: Data from NHANES 2013- 2014", Environ. Toxicology Pharmacology, 50, 20-31. http://dx.doi.org/10.1016/j.etap.2017.01.006.
  27. Sahli, M.A., Annouar, S. and Tahaikt, M. (2007), "Fluoride removal for underground brackish water by adsorption on the natural chitosan and by electrodialysis", Desalination, 212, 37-45. https://doi.org/10.1016/j.desal.2006.09.018.
  28. Tunisian standard NT.106.002, "Relative to wastewaters (Environmental protection)" (1989). Off. J. Tunisian Repub, 59, 1332-1338. http://www.citet.nat.tn/Portail/doc/SYRACUSE/40964/norme-tunisienne-nt-106-002-norme-tunisienne-nt-106-002-1989-relative-aux-rejets-d-effluents-dans-le?_lg=fr-FR.
  29. WHO (World Health Organization) (2017), "Guidelines for Drinking-water Quality: fourth edition incorporating the first addendum", Geneva, Switzerland.
  30. Yahyavi, H., Kaykhaii, M. and Mirmoghaddam, M. (2015), "Recent developments in methods of analysis for fluoride determination", Desalination Water Treat.. https://doi.org/10.1080/10408347.2014.985814.