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Application and testing of a triple bubbler sensor in molten salts

  • Williams, A.N. (Idaho National Laboratory) ;
  • Shigrekar, A. (University of Idaho) ;
  • Galbreth, G.G. (Idaho National Laboratory) ;
  • Sanders, J. (Idaho National Laboratory)
  • 투고 : 2019.08.14
  • 심사 : 2020.01.04
  • 발행 : 2020.07.25

초록

A triple bubbler sensor was tested in LiCl-KCl molten salt from 450 to 525 ℃ in a transparent furnace to validate thermal-expansion corrections and provide additional molten salt data sets for calibration and validation of the sensor. In addition to these tests, a model was identified and further developed to accurately determine the density, surface tension, and depth from the measured bubble pressures. A unique feature of the model is that calibration constants can be estimated using independent depth measurements, which allow calibration and validation of the sensor in an electrorefiner where the salt density and surface tension are largely unknown. This model and approach were tested using the current and previous triple bubbler data sets, and results indicate that accuracies are as high as 0.03%, 4.6%, and 0.15% for density, surface tension, and depth, respectively.

키워드

참고문헌

  1. M.A. Williamson, J.L. Willit, Pyroprocessing flowsheets for recycling used nuclear fuel, Nucl. Eng. Technol. 43 (2011) 329-334. https://doi.org/10.5516/NET.2011.43.4.329
  2. D. Vaden, S.X. Li, B.R. Westphal, K.B. Davies, T.A. Johnson, D.M. Pace, Engineering-scale liquid cadmium cathode experiments, Nucl. Technol. 162 (2008) 124-128. https://doi.org/10.13182/NT08-A3938
  3. J. Kim, J. Lee, S. Bae, S. Paek, H. Kim, T. Kim, T. Park, Automated high-temperature liquid level measurement system using a dynamic tube pressure technique, J. Ind. Eng. Chem. 49 (2017) 30-35. https://doi.org/10.1016/j.jiec.2016.10.041
  4. A.N. Williams, G.G. Galbreth, J. Sanders, Accurate determination of density, surface tension, and vessel depth using a triple bubbler system, J. Ind. Eng. Chem. 63 (2018) 149-156. https://doi.org/10.1016/j.jiec.2018.02.011
  5. A.N. Williams, A. Shigrekar, G.G. Galbreth, J. Sanders, Application of a triple bubbler sensor for determining the density, surface tension, and depth in molten salts, J. Nucl. Mater. Manag. 47 (2019) 47-52.
  6. C.W. Parmelee, K.C. Lyon, C.G. Harman, The Surface Tensions of Molten Glass, vol. XXXVI, University of Illinois Bulletin, 1939, p. 8.
  7. S. Sugden, The determination of surface tension from the maximum pressure in bubbles. Part II, J. Chem. Soc. Trans. 125 (1924) 29.
  8. G.G. Galbreth, M. Shaltry, G.L. Fredrickson, D. Vaden, B.E. Serrano, Sensor for Measuring Density and Depth of Molten Salt, Idaho Natl. Lab., 2016. FY-16 FT16INL04010404.
  9. M.V. Smirnov, V.P. Stepanov, Density and surface tension of molten alkali halides and their binary mixtures, Electrochim. Acta 27 (1982) 1551-1563. https://doi.org/10.1016/0013-4686(82)80082-0
  10. G.J. Janz, Thermodynamic and transport properties for molten salts: correlation equations for critically evaluated density, surface tension, electrical conductance, and viscosity data, J. Phys. Chem. Ref. Data 17 (1988).
  11. H. Ito, Y. Hasegawa, Densities of eutectic mixtures of molten alkali chlorides below 673K, J. Chem. Eng. Data 46 (2001) 1203-1205. https://doi.org/10.1021/je010092n
  12. K.J. Mysels, Improvements in the maximum-bubble pressure method of measuring surface tension, Langmuir 2 (1986) 428. https://doi.org/10.1021/la00070a009
  13. K.J. Mysels, The maximum bubble pressure method of measuring surface tension, revisited, Colloids Surface. 43 (1990) 241-262. https://doi.org/10.1016/0166-6622(90)80291-B
  14. T. Hosama, M. Aritomi, T. Kawa, Numerical calculation and measurement of bubble shape and excess pressure in dip-tube pressure measurement, Nucl. Technol. 120 (1997) 121-135. https://doi.org/10.13182/NT97-A35421
  15. T. Hosama, M. Aritomi, T. Kawa, Formulas to correct excess pressure and pressure shift to be used in volume measurement for plutonium nitrate solution, Nucl. Technol. 129 (2000) 218-235. https://doi.org/10.13182/NT00-A3058

피인용 문헌

  1. Remote Density Measurements of Molten Salts via Neutron Radiography vol.7, pp.5, 2020, https://doi.org/10.3390/jimaging7050088