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This study analyzed ignition probability about Lithium-polymer batteries of what variously were being produced wearable devices recently. The study analyzed ignition probability by PCM(Protection Circuit Module) operating state and overcharged, over-discharged, exposed to high temperatures of Lithium polymer batteries, analyzing wearable devices on the market. Then it classified experimental results to implement analysis comparison about weight, X-ray imaging, battery decomposition. With these experiments, the study analyzed combustion-possibility and fire patterns. These statistics will be used to measure and verify the cause of a fire when identify wearable devices using Lithium-polymer batteries.