한국환경농학회지 (Korean Journal of Environmental Agriculture)

  • 제39권2호
  • /
  • Pages.122-129
  • /
  • 2020
  • /
  • 1225-3537(pISSN)
  • /
  • 2233-4173(eISSN)
한국환경농학회 (The Korean Society of Environmental Agriculture)
권호 표지
DOI QR코드

DOI QR Code

시설재배 딸기의 생산단계에서 살충제 잔류량에 따른 반감기 및 감소상수 산출에 의한 안전성 평가

Residue Dissipation Kinetics and Safety Evaluation of Insecticides on Strawberry for the Harvest Periods in Plastic-covered Greenhouse Conditions

  • 장희라 (호서대학교 생명보건대학 식품제약공학부) ;
  • 유정선 (호서대학교 생명보건대학 식품제약공학부) ;
  • 반선우 (호서대학교 생명보건대학 식품제약공학부)
  • Chang, Hee-Ra (Department of Food & Pharmaceutical Engineering, College of Life & Health Sciences, Graduate School of Hoseo University) ;
  • You, Jung-Sun (Department of Food & Pharmaceutical Engineering, College of Life & Health Sciences, Graduate School of Hoseo University) ;
  • Ban, Sun-Woo (Department of Food & Pharmaceutical Engineering, College of Life & Health Sciences, Graduate School of Hoseo University)
  • 투고 : 2020.06.09
  • 심사 : 2020.06.17
  • 발행 : 2020.06.30
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

BACKGROUND: Dissipation patterns of insecticides (acequinocyl, clothianidin, diflubenzuron, thiacloprid, and thiamethoxam) on strawberry grown in plastic-covered greenhouse were evaluated at 7 intervals including the preharvest interval after application. This study was performed to determine the residue concentrations, half-lives and dissipation rates in strawberry for the harvest periods. METHODS AND RESULTS: Acequinocyl, clothianidin, diflubenzuron, thiacloprid, and thiamethoxam were applied in accordance with critical good agricultural practices for strawberry. Strawberry samples were collected at 0, 1, 2, 3, 5, 7 and 10 days after application. Quantitaion was performed by HPLC/DAD and HPLC-MSMS system with C18 column. The limit of quantitation (LOQ) values varied between were 0.00025~0.05 mg/kg on strawberry. The recoveries of acequinocyl, clothianidin, diflubenzuron, thiacloprid and thiamethoxam at two concentrations ranged from 70.9~104.9% on strawberry. The half-lives of pesticide dissipation on strawberry for two fields ranged from 1.3~8.2 days. The dissipation rates were evaluated according to the statistics method with a 95% confidence. CONCLUSION: The residue levels of insecticides (acequinocyl, clothianidin, diflubenzuron, thiacloprid, and thiamethoxam) on strawberry at 0-day after application were below the specified values by Korean MRL. To estimate dissipation rate constant of pesticides on crop for harvest periods, it is important to set the pre-harvest residue limit for human health and consumer protection in Korea.

키워드

참고문헌

  1. Kim YJ, Kim JH, Kwon YS, Song JW, Seo JS (2017) Residual characteristics and monitoring of cyenopyrafen and cyflumetofen in strawberries for export. Korean Journal of Environmental Agriculture, 36(4), 279-287. https://doi.org/10.5338/KJEA.2017.36.4.35.
  2. Lee HS, Hong SM, Kwon HY, Kim DB, Moon BC (2017) Comparison of residue patterns between foliar application and drenching in export strawberry. Journal of Applied Biological Chemistry, 60(4), 313-319. https://doi.org/10.3839/jabc.2017.049.
  3. Kwak SY, Lee SH, Jeong HR, Nam AJ, Sarker A, Kim HY, Lim CU, Cho HJ, Kim JE (2019) Variation of pesticide residues in strawberries by washing and boiling processes. Korean Journal of Environmental Agriculture, 38(4), 281-290. https://doi.org/10.5338/KJEA.2019.38.4.38.
  4. Lee DY, Jo HJ, Jeong DK, Goo YM, Hwang MR, Kang NJ, Kang KY, Kim JH (2018) Residual characteristics of pesticides used for powdery mildew control on greenhouse strawberry. Journal of Agriculture & Life Science, 52(2), 99-106. https://doi.org/10.14397/jals.2018.52.2.99
  5. Park, JE, Hwang, EJ, Chang, HR (2017) Sediment Toxicity Assessment of Pesticides using Chironomus riparius Acute and Chronic Effect. Korean Journal of Environmental Agriculture, 36(2), 80-86. https://doi.org/10.5338/KJEA.2017.36.2.18.
  6. Abdallah OI, El-Hamid RMA, Raheem EHA (2019) Clothianidin residues in green bean, pepper and watermelon crops and dietary exposure evaluation based on dispersive liquid-liquid microextraction and LC-MS/MS. Journal of Consumer Protection and Food Safety, 14(3), 293-300. https://doi.org/10.1007/s00003-019-01218-4
  7. Jin YD, Lim SJ, Kim SS, Choi GH, Lee HW, Jeong DY, Moon BC, Ro JH (2017) Effect of bagging technique on the residue patterns of thiacloprid and lufenuron in grape fruit (Vitis labrusca L.). The Korean Journal of Pesticide Science, 21(1), 42-48. https://doi.org/10.7585/kjps.2017.21.1.42
  8. Lee EY, Kim DK, Park IY, Noh HH, Park YS, Kim TH, Jin CW, Kim KI, Yun SS, et al. (2008) Residue patterns of indoxacarb and thiamethoxam in Chinese cabbage (Brassica campestris L.) grown under greenhouse conditions and their estimated daily intake. Korean Journal of Environmental Agriculture, 27(1), 92-98. https://doi.org/10.5338/KJEA.2008.27.1.092
  9. Lee EY, Noh HH, Park YS, Kang KW, Lee KH, Park HK, Yun SS, Jin CW, Han SK, Kyung KS (2009) Residual characteristics of Neonicotinoid Insecticide dinotefuran and thiacloprid in cucumber. The Korean Journal of Pesticide Science, 13(2), 98-104.
  10. Na TW, Rahman MM, Park JH, Yang A, Park KH, El-Aty AA, Shim JH (2012) Residual pattern of acequinocyl and hydroxyacequinocyl in perilla leaf grown under greenhouse conditions using ultra performance liquid chromatography-photo diode array detector with tandem mass confirmation. Journal of the Korean Society for Applied Biological Chemistry, 55(5), 657-662. https://doi.org/10.1007/s13765-012-2101-x
  11. Omirou M, Vryzas Z, Papadopoulou-Mourkidou E, Economou A (2009) Dissipation rates of iprodione and thiacloprid during tomato production in greenhouse. Food Chemistry, 116(2), 499-504. https://doi.org/10.1016/j.foodchem.2009.03.007
  12. Park JH, Lim JS, Yoon JY, Moon HR, Han YH, Lee YJ, Lee KS (2012) Establishment of Pre-Harvest Residue Limits (PHRLs) of Insecticide Clothianidin and Fungicide Fluquinconazole on Peaches during Cultivation Period. Korean Journal of Environmental Agriculture, 31(3), 271-276. https://doi.org/10.5338/KJEA.2012.31.3.271.
  13. Kim NK, Lee SH, Nam YJ, Moon KM, Park MH, Yun MH., Kim MY, Jang HM, Shin BS (2011) Monitoring of neonicotinoid pesticide residues in paprika using UPLC-MS/MS from Gyeongnam region. The Korean Journal of Pesticide Science, 15(1), 15-21.
  14. Park SH, Han CH, Kim AK, Shin JM, Lee JK, Park YH, Kim JM, Hwang LH, Chang MS, et al. (2014) Analysis of diflubenzuron in agricultural commodities by multiresidue method. The Korean Journal of Pesticide Science, 18(4), 269-277. https://doi.org/10.7585/kjps.2014.18.4.269.
  15. Stachniuk A, Szmagara A, Czeczko R, Fornal E (2017) LC-MS/MS determination of pesticide residues in fruits and vegetables. Journal of Environmental Science and Health, Part B, 52(7), 446-457. https://doi.org/10.1080/03601234.2017.1301755.
  16. Hwang EJ, Park JE, Kwon CH, Kim JS, Chang HR (2018) Residue dissipation behavior of bistrifluron and cyenopyrafen in peach for the cultivation periods under field conditions. Korean Journal of Environmental Agriculture, 37(1), 41-48. https://doi.org/10.5338/KJEA.2018.37.1.07.
  17. Moser H, Rombke J (2009) Ecotoxicological characterization of waste: results and experiences of an international ring test, pp. 73-75, Springer Science & Business Media.