DOI QR코드

DOI QR Code

Influence of Carbon Black Contents and Rubber Compositions on Formation of Wear Debris of Rubber Vulcanizates

  • Received : 2020.04.25
  • Accepted : 2020.05.28
  • Published : 2020.06.30

Abstract

Wear particles of the model tread compounds for bus and truck tires were made using a laboratory abrasion tester and characterized based on their size distributions, shapes, and crosslink densities. The influence of the carbon black contents and rubber compositions (NR= 100 and NR/BR= 80/20) on the production of wear particles was investigated. The wear particles were separated according to size using a sieve shaker. The shape properties of the wear particles were analyzed using an image analyzer and scanning electron microscopy (SEM). Their shapes were observed as tiny stick cookies or sausages with bumpy surfaces. The particle size distribution tended to be smaller with increasing carbon black content. Moreover, the particle size distributions of the NR = 100 samples were larger than that of the NR/BR blend samples. There were different filaments in the wear particles. The filament diameters tended to be thinner with increasing carbon black content. The crosslink density increased with increasing carbon black content, and the crosslink densities of the NR= 100 samples were lower than those of the NR/BR blend ones. The particle size distribution tended to be smaller with increasing crosslink density. Based on the experimental results, the wear particles can be produced by detaching debris from the main body through repetitive strain and recovery.

Keywords

References

  1. F. Sommer, V. Dietze, A. Baum, J. Sauer, S. Gilge, C. Maschowski, and R. Giere, "Tire abrasion as a major source of microplastics in the environment", Aerosol Air Qual. Res., 18, 2014 (2018). https://doi.org/10.4209/aaqr.2018.03.0099
  2. S. Wagner, T. Huffer, P. Klockner, M. Wehrhahn, T. Hofmann, and T. Reemtsma, "Tire wear particles in the aquatic environment - A review on generation, analysis, occurrence, fate and effects", Wear Res., 139, 83 (2018). https://doi.org/10.1016/j.watres.2018.03.051
  3. M. Dall'Osto, D. C. S. Beddows, J. K. Gietl, O. A. Olatunbosun, X. Yang, and R. M. Harrison, "Characteristics of tyre dust in polluted air: Studies by single particle mass spectrometry (ATOFMS)", Atmos. Environ., 94, 224 (2014). https://doi.org/10.1016/j.atmosenv.2014.05.026
  4. J. M. Panko, K. M. Hitchcock, G. W. Fuller, and D. Green, "Evaluation of tire wear contribution to PM2.5 in urban environments", Atmosphere, 10, 99 (2019). https://doi.org/10.3390/atmos10020099
  5. M. Salehi, J. W. M. Noordermeer, L. A. E. M. Reuvekamp, W. K. Dierkes, and A. Blume, "Measuring rubber friction using a Laboratory Abrasion Tester (LAT100) to predict car tire dry ABS braking", Tribol. Int., 131, 191 (2019). https://doi.org/10.1016/j.triboint.2018.10.011
  6. K. A. Grosch, "Rubber abrasion and tire wear", Rubber Chem. Technol., 81, 470 (2008). https://doi.org/10.5254/1.3548216
  7. Rubber, vulcanized or thermoplastic - Determination of resistance to abrasion using a driven, vertical abrasive disc, ISO 23233:2009.
  8. S-S. Choi and J-C. Kim, "Lifetime prediction and thermal aging behaviors of SBR and NBR composites using crosslink density changes", J. Ind. Eng. Chem., 18, 1166 (2012). https://doi.org/10.1016/j.jiec.2012.01.011
  9. P. J. Flory, "Statistical mechanics of swelling of network structures", J. Chem. Phys, 18, 108 (1950). https://doi.org/10.1063/1.1747424