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Distribution of Persistent Organic Pollutants (POPs) in Different Sizes of Particles in the Ambient Air of the Pyeongteak Area

평택지역 대기 중 먼지 입경별 잔류성유기오염물질 분포특성 연구

  • Kim, Dong-Gi (Environment Research Planning Team, Gyeonggi-do Institute of Health and Environment) ;
  • Woo, Jung-Sik (Environment Research Planning Team, Gyeonggi-do Institute of Health and Environment) ;
  • Kim, Yong-Jun (Environment Research Planning Team, Gyeonggi-do Institute of Health and Environment) ;
  • Jung, Hye-Eun (Environment Research Planning Team, Gyeonggi-do Institute of Health and Environment) ;
  • Park, Ju-Eun (Environment Research Planning Team, Gyeonggi-do Institute of Health and Environment) ;
  • Cho, Duck-Hee (Environment Research Planning Team, Gyeonggi-do Institute of Health and Environment) ;
  • Moon, Hee-Chun (Environment Research Planning Team, Gyeonggi-do Institute of Health and Environment) ;
  • Oh, Jo-Gyo (Environment Research Planning Team, Gyeonggi-do Institute of Health and Environment)
  • 김동기 (경기도보건환경연구원 환경연구기획팀) ;
  • 우정식 (경기도보건환경연구원 환경연구기획팀) ;
  • 김용준 (경기도보건환경연구원 환경연구기획팀) ;
  • 정해은 (경기도보건환경연구원 환경연구기획팀) ;
  • 박주은 (경기도보건환경연구원 환경연구기획팀) ;
  • 조덕희 (경기도보건환경연구원 환경연구기획팀) ;
  • 문희천 (경기도보건환경연구원 환경연구기획팀) ;
  • 오조교 (경기도보건환경연구원 환경연구기획팀)
  • Received : 2020.03.02
  • Accepted : 2020.03.27
  • Published : 2020.04.30

Abstract

Objectives: The concentration distributions of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs), dioxin-like polychlorinated biphenlys (dl-PCBs), and polycyclic aromatic hydrocarbons (PAHs) in fine particles were investigated to provide basic data on POP behavior and composition analysis. Methods: The concentrations of PCDD/Fs, dl-PCBs, and PAHs by particle size were evaluated for TSP, PM10, and PM2.5. Also, fine dust component analysis and factor analysis were performed to identify the source of PCDD/Fs. Results: The particle size distribution was found to account for 24.3% of >10 ㎛, 14.5% of 2.5-10 ㎛, and 61.2% of <2.5 ㎛. The average contributions of coarse particles (>2.5 ㎛) and fine particles (<2.5 ㎛) were PCDD/Fs 67%, dl-PCBs 66%, benzo (a) pyrene 83% and PAHs 84%, and the contributions of fine particles (<2.5 ㎛) were higher than coarse particles (>2.5 ㎛). However, the contributions of coarse particles increased in April to September with higher temperatures, while those of fine particles increased in February to March with lower temperatures. Conclusions: Low chlorinated (4Cl-5Cl) PCDD/Fs were more adsorbed compared to coarse particles due to the influence of pollutant migration from particulate to gas phase according to temperature rise, whereas high chlorinated (6Cl-8Cl) PCDD/Fs were more adsorbed compared to fine particles. PCDD/Fs sources were assessed to be major sources of emissions, such as incineration facilities and/or open burning.

Keywords

References

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