DOI QR코드

DOI QR Code

Experimental Study on Hydrogen Sulfide Abatement in Sewage Odor Using Microbial Deodorants on the Market

시판용 미생물탈취제를 이용한 하수 악취 내 황화수소 저감에 관한 실험적 연구

  • Park, Sang Jin (Department of Railroad Civil System Engineering/Odor&VOC Research Center, Woosong University) ;
  • Kwon, Soo Youl (Department of Environmental Health, Korea National Open University)
  • 박상진 (우송대학교 철도건설시스템학부/악취VOC연구센터) ;
  • 권수열 (한국방송통신대학교 보건환경학과)
  • Received : 2020.02.24
  • Accepted : 2020.03.16
  • Published : 2020.04.30

Abstract

Objectives: This study was conducted to estimate a technology to reduce hydrogen sulfide (H2S) in sewage odor using microbial deodorant. Methods: After injecting five commercially available microbial deodorants into fresh sewage, the concentration of hydrogen sulfide over time was measured using the headspace method. H2S concentration in odor samples was measured using gas chromatograph/FPD. Calculated odor concentration and calculated odor intensity by H2S concentration remaining after treatment with microbial deodorant were evaluated theoretically. Results: The rate of H2S abatement by microbial deodorant differed depending on the experimental conditions and the type of deodorant, but it was found to range from 63 to 82%. Especially, two deodorants showed high H2S reduction rates of over 80% on average. However, based on the best deodorant, the theoretically calculated odor concentration by H2S after microbial deodorant treatment was 4,400 OUk, and the theoretical odor intensity was also rated at 4 degrees or higher. Conclusions: In conclusion, microbial deodorant is considered to have a relatively high effect on reducing H2S in sewage odor. However, even after treatment with microbial deodorant, calculated odor concentration and calculated odor intensity were relatively high. This is thought to be caused by other odorous substances besides H2S.

Keywords

References

  1. Seoul Development Institute. A Solution of Foul Odor of Roadside Gutters in Seoul. Seoul: Seoul Development Institute Press; 2007; p.129-156.
  2. Seoul Development Institute. A study on the Reduction Solution for Sewer Foul Odor Discharged from a Septic Tank. Seoul: Seoul Development Institute Press; 2009; p.95-128.
  3. Nam YK, Kim JS, Song JH. The Effect of Electrode Materials on Odor Removal in an Electrolytic System; Proceeding of the 48th of KOSAE Korean Society for Atmos. Environ. 2012; 24.
  4. Kang HI, Namgung HJ, Cho JI, Yoo SS, Lee BJ, Ji HK. Removal of Hydrogen Sulfide in Septic Tanks for Treating Black Water via an Immobilized Media of Sulfur?Oxidizing Bacteria. Int. J. Environ. Res. Public Health. 2020; 17: 684-695. https://doi.org/10.3390/ijerph17030684
  5. Park SJ, et. al. Survey on the Status of Odor Generation in Main Sewer and Establish the Countermeasure to Improve the Living Environmental Condition in Daejeon City. Daejeon: Woosong Univ. Press; 2018.
  6. Park SJ. Remote monitoring and real-time abatement of odor emitted from sewer using odor sensors, wireless communication technique and microbial deodorant. Global NEST Journal. 2018; 20(3): 646-653. https://doi.org/10.30955/gnj.002740
  7. Jeon EC, Son HK, Sa JH. Emission Characteristics and Factors of Selected Odorous Compounds at a Wastewater Treatment Plant. Sensors. 2009; 9: 311-326. https://doi.org/10.3390/s90100311
  8. E. Alinezhad, M. Haghighib, F. Rahmanic, H. Keshizadeha, M. Abdia, K. Naddaf. Technical and economic investigation of chemical scrubber and bio?filtration in removal of $H_2S $and $NH_3$ from wastewater treatment plant. J. of Environ. Management. 2019; 241: 32-43. https://doi.org/10.1016/j.jenvman.2019.04.003
  9. García JT, Antonio VR, Castillo LG, Carrillo JM. Evaluation of Sulfide Control by Air-Injection in Sewer Force Mains Field and Laboratory Study. Sustainability. 2017; 9: 402-421. https://doi.org/10.3390/su9030402
  10. Choi II, Lee HJ, Shin JD, Kim HY. Evaluation of the Effectiveness of Five Odor Reducing Agents for Sewer System Odors Using an On-Line Total Reduced Sulfur Analyzer. Sensors(Basei). 2012; 12(12): 16892-16906. https://doi.org/10.3390/s121216892
  11. Park SJ, Hirai H, Shoda M. Treatment of exhaust gases from a night soil treatment plant by a combined deodorization system of activated carbon fabric reator with peat biofilter inoculated with Thiobacillus thioparus DW44. J. of Ferment. Bioeng. 1993; 76(5): 423-426. https://doi.org/10.1016/0922-338X(93)90039-B
  12. Weon YD, Park SB, Lee WK, Ryu BH, Song SK. Continuous Dedorizaion of Malodorous Sulfur Compounds Using Immobilized Thiobacillus neapolitanus R-10. J. of Korean Environ. Sci. Society. 1995; 4(3): 295-301.
  13. Kim JD, et. al. Isolation and Identification of a Lactic Acid Bacterial Strain KJ-108 and Its Capability for Deodorizing Malodorous Gases Under Anaerobic Culture Conditions. J. Microbiol. Biotechonol. 2013; 13(2): 207-216.
  14. Kim SK, Kang CM, Chung SY, Oh JS, Kim SD, Yoon HS, Lee JW. Study on Desulfurizing Microbe Selection and Its Deodorizing Effect in Dry Anaerobic Digestion. J. of Korean Society of Environ. Technology. 2011; 12(2): 118-124.
  15. Oh KH, Chpi IH, Cho YC. Isolation and Characterization of Ammonia -removing Bacteria from a Food-wastewater Treatment Facility. J. of Korean Society of Environ. Engineers. 2008: 30(6): 653-658.
  16. Park SJ, Kwon SY. Odor Characteristics of Malodorous Sulfur-containing Gas Emitted from a Sewer and Its Outlet. J Environ. Health Sci. 2014; 40(6): 477-483.
  17. Park SJ, Kwon SY. Odor Characteristics and Concentration of Malodorous Volatile Organic Compounds Emitted from a Sewer and Its Outlet. J Environ. Health Sci. 2017; 43(6): 457-466.
  18. Han, JS, Park, SJ. A Study of the Correlation between the Concentration and Dilution Factor of Sulfur Compounds, $NH_3$, and TMA. Korean J. Odor Research and Engr. 2012: 11: 87-93.
  19. Japan Association on Odor Environment. Chapter 3 Correlation equation between odor intensity and odor compounds concentration - Handbook of Odor Prevention Law, 6th ed.; Tokyo; Gyosei digital Press; 2012. p. 380-333.
  20. Wu, C., Liu, J., Zhao, P., Piringer, M., Schauberger, G. Conversion of the chemical concentration of odorous mixtures into odour concentration and odour intensity: A comparison of methods. Atmos. Environ. 2016; 12(7): 283-292.
  21. Han, J.S.; Lim, Y.J.; Park, S.J. A Study on the Calculation Methods of Odor Threshold Values of the Specified Offensive Odor Substances. J. Odor Research and Engr. 2012; 11: 24-33.
  22. Nagata, N. Measurement of Odor Threshold by Triangle Odor Bag Method. Available:https://www.env.go.jp/en/air/odor/measure/02_3_2.pdf [accessed on 10 January 2019].
  23. Leonardos, G, Kendall, D, Barnard, N. Odor Threshold Determinations of 53 Odorant Chemicals. J. Air Pollut. Control Assoc. 1969; 19: 91-95. https://doi.org/10.1080/00022470.1969.10466465
  24. Busan Metropolitan City/Saha-Gu. Status of Odor and Environmental Conditions in Sin-pyoung & Jang-rim Industrial Complex. Daejeon; Woosong University Press; 2008; p.510-513.