Journal of the Korean Institute of Gas (한국가스학회지)

The Korean Institute of GAS (한국가스학회)
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Determination of Flash Point for n-Octane+n-Nonane and n-Nonane+n-Decane Systems by Seta flash Apparatus

Seta flash 장치에 의한 n-Octane + n-Nonane계 및 n-Nonane + n-Decane계의 인화점 결정

  • Ha, Dong-Myeong (Dept. of Occupational Health and Safety Engineering, Semyung University) ;
  • Lee, Sungjin (Dept. of Clinical Laboratory Science, Semyung University)
  • 하동명 (세명대학교 보건안전공학과) ;
  • 이성진 (세명대학교 임상병리학과)
  • Received : 2020.10.15
  • Accepted : 2020.12.03
  • Published : 2020.12.31
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Abstract

In order to guarantee safe storage and transportation of a flammable liquid solution, it is very important to know its flash point information. In this paper, flash points of n-octane+n-nonane system and n-nonane+n-decane system were measured by Seta flash apparatus and an empirical equation is proposed for the accurate estimation of flash point. Empirical equation is used to predict flash point of n-octane+n-nonane system and n-nonane+n-decane system, which were also compared to Unifac-based model. Absolute average errors of flash point data predicted by Unifac-based model are 0.7℃ and 0.6℃ for n-octane+n-nonane system and n-nonane+n-decane system, respectively. Absolute average errors of flash point data predicted by empirical equation are 0.2℃ and 0.4℃ for n-octane+n-nonane system and n-nonane+n-decane system, respectively. In conclusion, empirical equation proposed in this paper, presented the most satisfactory.

인화성 액체 용액을 안전하게 저장하고 운반하기 위해서는, 인화점 정보를 알고 있는 것이 매우 중요하다. 이 논문에서는 n-octane+n-nonane 계와 n-nonane+n-decane 계의 인화점을 Seta flash 장치로 측정하였으며, 인화점을 정확하게 예측하기 위한 경험식을 제시한다. 경험식은 n-octane+n-nonane 계와 n-nonane+n-decane 계의 인화점을 예측하기 위해 사용되었으며, 또한 Unifac 식에 기반을 둔 계산 모델과 비교하였다. Unifac 식을 이용한 예측 결과의 절대평균오차는 n-octane+n-nonane 계의 경우 0.7℃였고, n-nonane+n-decane 계의 경우 0.6℃이었다. 경험식에 의한 예측값의 절대평균오차는 n-octane+n-nonane 계의 경우 0.2℃였고, n-nonane+n-decane 계의 경우 0.4℃이었다. 결론적으로, 본 논문에서 제시된 경험식은 매우 만족한 결과를 나타내었다.

Keywords

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