DOI QR코드

DOI QR Code

광산란법을 이용한 국내 석탄화력발전소 굴뚝에서 배출되는 PM10, PM2.5 측정 및 분석

Measurement and analysis of PM10 and PM2.5 from chimneys of coal-fired power plants using a light scattering method

  • 신동호 (한국기계연구원 환경기계연구실) ;
  • 김영훈 (한국기계연구원 환경기계연구실) ;
  • 홍기정 (한국기계연구원 환경기계연구실) ;
  • 이건희 (한국기계연구원 환경기계연구실) ;
  • 박인용 (한국기계연구원 환경기계연구실) ;
  • 김학준 (한국기계연구원 환경기계연구실) ;
  • 김용진 (한국기계연구원 환경기계연구실) ;
  • 한방우 (한국기계연구원 환경기계연구실) ;
  • 황정호 (연세대학교 기계공학부)
  • Shin, Dongho (Department of Environmental Machinery, Korea Institute of Machinery & Materials) ;
  • Kim, Younghun (Department of Environmental Machinery, Korea Institute of Machinery & Materials) ;
  • Hong, Kee-Jung (Department of Environmental Machinery, Korea Institute of Machinery & Materials) ;
  • Lee, Gunhee (Department of Environmental Machinery, Korea Institute of Machinery & Materials) ;
  • Park, Inyong (Department of Environmental Machinery, Korea Institute of Machinery & Materials) ;
  • Kim, Hak-Joon (Department of Environmental Machinery, Korea Institute of Machinery & Materials) ;
  • Kim, Yong-Jin (Department of Environmental Machinery, Korea Institute of Machinery & Materials) ;
  • Han, Bangwoo (Department of Environmental Machinery, Korea Institute of Machinery & Materials) ;
  • Hwang, Jungho (Mechanical Engineering, Yonsei University)
  • 투고 : 2020.12.11
  • 심사 : 2020.12.23
  • 발행 : 2020.12.31

초록

Air pollutants emitted from chimneys of coal-fired power plants are considered to be a major source of fine particulate matter in the atmosphere. In order to manage fine particle in the chimney of a coal-fired power plant, it is necessary to know the concentration of fine particle emitted in real time, but the current system is difficult. In this study, a real-time measurement system for chimney fine particle was developed, and measurements were performed on six coal-fired power plants. Through the measurements, the mass concentration distribution according to the particle size could be secured. All six chimneys showed bimodal distribution, and the count median diameters of each mode were 0.5 and 1.1 ㎛. In addition, it was compared with the gravimetric measurement method, and it was determined that the relative accuracy for PM10 was within 20%, and the value measured using the developed measuring instrument was reliable. Finally, three power plants were continuously measured for one month, and as a result of comparing the concentration of PM10 according to the amount of power generation, it was confirmed that the PM10 discharged from the chimney increased in the form of an exponential function according to the amount of power generation.

키워드

참고문헌

  1. Baek, S., Jang, J., and Kim, Y. (2019). A study on repowering of 500 MW standard coal-fired power plant for performance improvement and emission reduction, Journal of The Korean Society of Combustion, 24(4), 37-44. https://doi.org/10.15231/jksc.2019.24.4.037
  2. Basu, P. (1999). Combustion of coal in circulating fluidized-bed boilers: a review, Chemical Engineering Science, 54, 5547-5557. https://doi.org/10.1016/S0009-2509(99)00285-7
  3. Cordoba, P. (2015). Status of flue gas desulphurisation (FGD) systems from coal-fired power plants: Overview of the physic-chemical control processes of wet limestone FGDs, Fuel, 144, 274-286. https://doi.org/10.1016/j.fuel.2014.12.065
  4. Fernandes, U., and Costa, M. (2012). Particle emissions from a domestic pellets-fired boiler, Fuel Processing Technology, 103, 51-56. https://doi.org/10.1016/j.fuproc.2011.08.020
  5. Goodarzi, F., and Sanei, H. (2009). Plerosphere and its role in reduction of emitted fine fly ash particles from pulverized coal-fired power plants, Fuel, 88(2), 382-386. https://doi.org/10.1016/j.fuel.2008.08.015
  6. Groves, J., and Cain, J.R. (2000). A survey of exposure to diesel engine exhaust emissions in the workplace, The Annals of Occupational Hygiene, 44(6), 435-447. https://doi.org/10.1016/S0003-4878(00)00002-8
  7. Higham, D.J., and Higham, N.J. (2016). MATLAB guide (3rd ed.), Philadelphia, Society for Industrial and Applied Mathematics, p. 177.
  8. ISO 23210 (2009). Stationary source emissions determination of PM10/PM2.5 mass concentration in flue gas measurement at low concentrations by use of impactors.
  9. Kim, H.C., Kim, S., Son, S.W., Lee, P., Jin, C.S., Kim, E., Kim, B.U., Ngan, F., Bae, C., Song, C.K., and Stein, A. (2016). Synoptic perspectives on pollutant transport patterns observed by satellites over East Asia: Case studies with a conceptual model, Atmospheric Chemistry and Physics Discussions, 1-30.
  10. Kim, H.B., Kim, D.S., Youn, J.S., Han, S., Jeon, Y.W., and Jeon, K.J. (2017). Comparison of measurement methods and size fraction of fine particles (PM10, PM2.5) from stationary emission source using Korean standard and ISO: coal power plant and refinery, Journal of Korean Society for Atmospheric Environment, 33, 342-350. https://doi.org/10.5572/KOSAE.2017.33.4.342
  11. Lee, H. (2020). 5 Power Generation Companies, "We will reduce fine dust with the best possible": Suspension of coal-fired power plants and promotion of upper limit restrictions… Reduction of 2,108 tons of fine dust emissions compared to the previous year_5 power generation companies, investment in eco-friendly facilities and promotion of indoor storage of outdoor storage facilities, Journal of Electrical World Monthly Magazine, 5, 38-40.
  12. Lee, S., Ho, C.H., and Choi, Y.S. (2011). High-PM10 concentration episodes in Seoul, Korea: Background sources and related meteorological conditions, Atmospheric Environment, 45(39), 7240-7247. https://doi.org/10.1016/j.atmosenv.2011.08.071
  13. Lewis, T.R., Green, F.H., Moorman, W.J., Burg, J.A., and Lynch, D.W. (1989). A chronic inhalation toxicity study of diesel engine emissions and coal dust, alone and combined, Journal of the American College of Toxicology, 8(2), 345-75. https://doi.org/10.3109/10915818909019560
  14. Nobuhiro, M., Yutaka, K., Tomoki, N., Kazuyuki, K., Lokesh, K.S., Takuya, I., Takeshi, K., and Yutaka M. (2010). Radiative transfer modeling of filter-based measurements of light absorption by particles: Importance of particle size dependent penetration depth, Journal of Aerosol Science, 41(4), 401-412. https://doi.org/10.1016/j.jaerosci.2010.02.002
  15. Park, H.S., Lee, D.A., Yang, J.G., and Jang, S.G. (2018). Emission characteristics of PM10 and PM2.5 in thermal power plants using different fuel types, Journal of Korean Society for Atmospheric Environment, 34(4), 534-541. https://doi.org/10.5572/KOSAE.2018.34.4.534
  16. Richard, D., William, R.S., David, M.A., and Leslie S. (1957). Isokientic sampling probes, Industrial and Engineering Chemistry, 49(2), 294-302. https://doi.org/10.1021/ie50566a049
  17. Meij, R., and Winkel, B. (2004). The emissions and environmental impact of PM10 and trace elements from a modern coal-fired power plant equipped with ESP and wet FGD, Fuel Processing Technology, 85, 641-656. https://doi.org/10.1016/j.fuproc.2003.11.012
  18. Ministry of Environment (2011). Particulate matter-automated measuring method in flue gas, Air Pollution Process Test Standard, ES01810.1a.
  19. Shin, D., Woo, C.G., Hong, K.J., Kim, H.J., Kim, Y.J., Lee, G.Y., Chun, S.N., Hwang, J., and Han, B. (2019). Development of a new dilution system for continuous measurement of particle concentration in the exhaust from a coal-fired power plant, Fuel, 257, 116045. https://doi.org/10.1016/j.fuel.2019.116045
  20. Shin, D., Woo, C.G., Hong, K.J., Kim, H.J., Kim, Y.J., Han, B., Hwang, J., Lee, G.Y., and Chun, S.N. (2020). Continuous measurement of PM10 and PM2.5 concentration in coal-fired power plant stacks using a newly developed diluter and optical particle counter, Fuel, 269, 117445. https://doi.org/10.1016/j.fuel.2020.117445
  21. Stolle, R., Koeser, H., and Gutberlet, H. (2014). Oxidation and reduction of mercury by SCR DeNOx catalysts under flue gas conditions in coal fired power plants, Applied Catalysis B: Environmental, 144, 486-497. https://doi.org/10.1016/j.apcatb.2013.07.040
  22. U.S. Environmental Protection Agency (USEPA) (1996). Air quality for particulate matter, National Center for Environmental Assessment, Office of Research and Development, Research Triangle Park, NC, Report No: EPA/600/p-95/001CF.
  23. Wada, M., Tsukada, M., Namiki, N., Szymanski, W.W., Noda, N., Makino, H., Kanaoka, C., and Kamiya, H. (2016). A two-stage virtual impactor for in-stack sampling of PM2.5 and PM10 in flue gas of stationary sources, Aerosol and Air Quality Research, 16, 36-45. https://doi.org/10.4209/aaqr.2015.06.0383