청정기술 (Clean Technology)

  • 제26권4호
  • /
  • Pages.251-256
  • /
  • 2020
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  • 1598-9712(pISSN)
  • /
  • 2288-0690(eISSN)
한국청정기술학회 (The Korean Society of Clean Technology)
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Markable Green Synthesis of Gold Nanoparticles Used As Efficacious Catalyst for the Reduction of 4-Nitrophenol

  • Rokade, Ashish A. (Department of Industrial Chemistry, Pukyong National University) ;
  • Yoo, Seong Il (Department of Polymer Engineering, Pukyong National University) ;
  • Jin, Youngeup (Department of Industrial Chemistry, Pukyong National University) ;
  • Park, Seong Soo (Department of Industrial Chemistry, Pukyong National University)
  • 투고 : 2020.10.22
  • 심사 : 2020.12.03
  • 발행 : 2020.12.31
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초록

The biocompatibility and plasmonic properties of Au nanoparticles make them useful for photothermal therapy, drug delivery, imaging, and many other fields. This study demonstrated a novel, facile, economic, and green synthetic method to produce gold nanoparticles. Gold nanoparticles (AuNPs) with spherical and triangular shapes were effectively synthesized using only Schisandra chenesis fruit extract as the capping and reducing agent. The shape of the AuNPs could be engineered simply by adjusting the molar concentration of HAuCl4 in the reaction mixture. The as-synthesized AuNPs were characterized using UV-VIS spectroscopy, transmission electron microscopy (TEM), X-ray diffraction (XRD), dynamic light scattering (DLS), and energy dispersive X-ray analysis (EDXA). This study revealed that by using the HAuCl4 concentration in the AuNP synthesis, the shape and size of the AuNPs could be controlled by the concentration of HAuCl4 and Schisandra chinensis fruit extract as a surfactant. The as-synthesized AuNPs samples had sufficient colloidal stability without noticeable aggregation and showed the predominant growth of the (111) plane of face-centered cubic gold during the crystal growth. The catalytic efficiency of the AuNPs synthesized using Schisandra chenesis fruit extract was examined by monitoring the catalytic reduction of 4-nitrophenol to 4-aminophenol using Ultraviolet-visible spectroscopy (UV-Vis spectroscopy). The synthesized AuNPs showed good catalytic activity to reduce 4-nitrophenol to 4-aminophenol, revealing their practical usefulness.

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참고문헌

  1. Zhang, Q., Li, W., Moran, C., Zeng, J., Chen, J., Wen, L-P., and Xia, Y., "Seed-Mediated Synthesis of Ag Nanocubes with Controllable Edge Lengths in the Range of 30-200 nm and Comparison of Their Optical Properties," J. Am. Chem. Soc., 132, 11372-11378 (2010). https://doi.org/10.1021/ja104931h
  2. Pietrobon, B., and Kitaev, V., "Photochemical Synthesis of Monodisperse Size-Controlled Silver Decahedral Nanoparticles and Their Remarkable Optical Properties," Chem. Mater, 20(16), 5186-5190 (2008). https://doi.org/10.1021/cm800926u
  3. Zhang, J., Langille, M. R., and Mirkin, C. A., "Photomediated Synthesis of Silver Triangular Bipyramids and Prisms: The Effect of pH and BSPP," J. Am. Chem. Soc, 132(35), 12502-12510 (2010). https://doi.org/10.1021/ja106008b
  4. Crespo-Biel, O., Ravoo, B. J., Huskens, J., and Reinhoudt, D. N., "Writing with Molecules on Molecular Printboards," Dalton. Trans, 23, 2737-2741 (2006).
  5. Gupta, K., Jana, P. C., and Meikap, A. K., "Optical and Electrical Transport Properties of Polyaniline-Silver Nanocomposite," Synth. Met. 160(13), 1566-1573 (2010). https://doi.org/10.1016/j.synthmet.2010.05.026
  6. Liz-Marzan, L. M., "Tailoring Surface Plasmons through the Morphology and Assembly of Metal Nanoparticles," Langmuir, 22(1), 32-41 (2006). https://doi.org/10.1021/la0513353
  7. Manivasagan, P., Bharathiraja, S., Moorthy, M. S., Oh, Y-O., Song, K., Seo, H., and Oh, J., "Anti-EGFR Antibody Conjugation of Fucoidan-Coated Gold Nanorods as Novel Photothermal Ablation Agents for Cancer Therapy," ACS Appl. Interfaces, 9(17), 14633-14646 (2017). https://doi.org/10.1021/acsami.7b00294
  8. Manivasagan, P., Bharathiraja, S., Bui, N. Q., Jang, B., Oh, Y-O., Lim, I. G., and Oh, J., "Doxorubicin-Loaded Fucoidan Capped Gold Nanoparticles for Drug Delivery and Photoacoustic Imaging," Int. J. Biol. Macromol, 91, 578-588 (2016). https://doi.org/10.1016/j.ijbiomac.2016.06.007
  9. Sun, H., Yuan, Q., Zhang, B., Ai, K., Zhang, P., and Lu, L., "Gd Functionalized Gold Nanorods for Multimodal Imaging Application," Nanoscale, 3, 1990-1996 (2011). https://doi.org/10.1039/c0nr00929f
  10. Xia, Y., Xiong, Y., Lim, B., and Skrabalak, S. E., "Shape-Controlled Synthesis of Metal Nanocrystals: Simple Chemistry Meets Complex Physics?" Angew. Chem. Int. Ed., 48(1), 60-103 (2009). https://doi.org/10.1002/anie.200802248
  11. Varma, R. S., "Greener Approach to Nanomaterials and Their Sustainable Applications," Current Opinion in Chem. Eng., 1(2), 123-128 (2012). https://doi.org/10.1016/j.coche.2011.12.002
  12. Rokade, A. A., Kim, J. H., Lim, S. R., Yoo, S. I., Jin, Y. E., and Park, S. S., "A Novel Green Synthesis of Silver Nanoparticles Using Rubus crataegifolius Bge Fruit Extract," J. Clus. Sci., 28(4), 2017-2026 (2017). https://doi.org/10.1007/s10876-017-1196-y
  13. Patil, M. P., Ngabire, D., Thi, H. H. P., Kim, M-D., and Kim, G-D., "Eco-friendly Synthesis of Gold Nanoparticles and Evaluation of Their Cytotoxic on Cancer Cells," J. Clus. Sci., 28(1), 119-132 (2017). https://doi.org/10.1007/s10876-016-1051-6
  14. Patil, M. P., Rokade, A. A., Ngabire, D., and Kim, G-D., "Green Synthesis of Silver Nanoparticles Using Water Extract from Galls of Rhus Chinensis and Its Antibacterial Activity," J. Clus. Sci., 27(5), 1737-1750 (2016). https://doi.org/10.1007/s10876-016-1037-4
  15. Sharma, R. K., Gulati, S., and Mehata, S., "Preparation of Gold Nanoparticles Using Tea: A Green Chemistry Experiment," J. Chem. Educ., 89(10), 1316-1318 (2012). https://doi.org/10.1021/ed2002175
  16. Shankar, S. S., Rai, A., Ahmad, A., and Sastry, M., "Controlling the Optical Properties of Lemongrass Extract Synthesized Gold Nanotriangles and Potential Application in Infrared-Absorbing Optical Coatings," Chem. Mater., 17(3), 566-572 (2005). https://doi.org/10.1021/cm048292g
  17. Xie, J., Lee, J. Y., and Wang, D. I. C., "Synthesis of Single-Crystalline Gold Nanoplates in Aqueous Solutions through Biomineralization by Serum Albumin Protein," J. Phys. Chem. C, 111(28), 10226-10232 (2007). https://doi.org/10.1021/jp0719715
  18. El-Seedi, H. R., El-Shabasy, R. M., Khalifa, S. A. M., Saeed, A., Shah, A., Shah, R., Iftikhar, F. J., Abdel-Daim, M. M., Omri, A., Hajrahand, N. H., Sabir, J. S. M., Zou, X., Halabi, M. F., Sarhan, W., and Guo, W., "Metal Nanoparticles Fabricated by Green Chemistry Using Natural Extracts: Biosynthesis, Mechanisms, and Applications," RSC Adv., 9, 24539-24559 (2019). https://doi.org/10.1039/C9RA02225B
  19. Yong, C., Jinbao, T., Xiaoke, W., Fengxiang, S., and Shujuan, L., "An Immunostimulatory Polsaccharide (SCP-IIa) from the Fruit of Schisandra (Turcz.) Brazil," Inter. J. Biol. Macromol, 50(3), 844-848 (2012). https://doi.org/10.1016/j.ijbiomac.2011.11.015
  20. Tafesh, A. M., and Weiguny, J., "A Riview of the Selective Catalytic Reduction of Aromatic Nitro Compounds into Arometic Amines, Isocyanates, and Ureas Using CO," Chem. Rev., 96(6), 2035-2052 (1996). https://doi.org/10.1021/cr950083f
  21. Esumi, K., Isono, R., and Yoshimura, T., "Preparation of PAMAN- and PPI-Metal (Silver, Platinum, and Palladium) Nanocomposites and Their Catalytic Activities for Reduction of 4-Nitrophenol," Langmuir, 20(1), 237-243 (2004). https://doi.org/10.1021/la035440t
  22. Pradhan, N., Pal, A., and Pal, T., "Silver Nanoparticle Catalyzed Reduction of Aromatic Nito compounds," Colloids Surf. A, 196(2), 247-257 (2002). https://doi.org/10.1016/S0927-7757(01)01040-8
  23. Philip, D., "Rapid Green Synthesis of Spherical Gold Nanoparticles Using Mangifera Indica Leaf," Spectrochimica Acta Part A, 77(4), 807-810 (2010). https://doi.org/10.1016/j.saa.2010.08.008
  24. Liang, M., Su, R., Huang, R., Qi, W., Yu, Y., Wang, L., and He, Z., "Facile in Situ Synthesis of silver Nanoparticles on Procyanidin-Grafted Eggshell Membrane and Their Catalytic Properties," ACS Appl. Mater. Interfaces, 6(7), 4638-4649 (2014). https://doi.org/10.1021/am500665p