Korean Chemical Engineering Research

The Korean Institute of Chemical Engineers (한국화학공학회)
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Bubble-Point Measurement of Binary Mixture for the CO2 + Caprolactone Acrylate System in High Pressure

  • Jeong, Jong-Dae (Department of Chemical and Biomolecular Engineering, Chonnam National University) ;
  • Byun, Hun-Soo (Department of Chemical and Biomolecular Engineering, Chonnam National University)
  • Received : 2019.07.08
  • Accepted : 2019.08.06
  • Published : 2019.12.01
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Abstract

Experimental data of phase equilibrium is reported for caprolactone acrylate in supercritical carbon dioxide. Bubble-point data was measured by synthetic method at temperatures ranging from (313.2 to 393.2) K and pressures up to 55.93 MPa. In this research, the solubility of carbon dioxide for the (carbon dioxide + caprolactone acrylate) system decreases as temperature increases at a constant pressure. The (carbon dioxide + caprolactone acrylate) system exhibits type-I phase behavior. The experimental result for the (carbon dioxide + caprolactone acrylate) system was correlated with Peng-Robinson equation of state using mixing rule. The critical property of caprolactone acrylate was predicted with the Joback and Lyderson method.

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References

  1. https://www.ulprospector.com/en/la/Adhesives/Detail/2097/46197/SR495B
  2. Yeo, S. D. and Kiran, E., "Formation of Polymer Particles with Supercritical Fluids: A Review," J. of Supercritical Fluids, 34, 287-308(2005). https://doi.org/10.1016/j.supflu.2004.10.006
  3. McHugh, M. A. and Krukonis, V. J., Supercritical Fluid Extraction, 2nd ed., Butterworth-Heinemann, Stoneham, 1994.
  4. Yim, J. H., Choo, Y. S. and Byun, H. S., "Phase Behaviour for the ($CO_2$+1-butyl-2-pyrrolidone) and ($CO_2$+1-octyl-2-pyrrolidone) Systems at Temperatures from (313.2 to 393.2) K and Pressures up to 28 MPa," J. of Chemical Thermodynamics, 130, 140-146(2019). https://doi.org/10.1016/j.jct.2018.10.002
  5. Cho, S. H., Lee, B. S. and Byun, H. S., "Phase Behaviors for the Tetrahydrofurfuryl Methacrylate and Poly(tetrahydrofurfuryl methacrylate) in Supercritical Carbon Dioxide," J. of $CO_2$ Utilization, 25, 39-45(2018). https://doi.org/10.1016/j.jcou.2018.03.010
  6. Lee, H., Jeong, J. D. and Byun, H. S., "Phase Equilibrium of Binary Mixture for the (Carbon Dioxide + 1-Phenyl-2-Pyrrolidone) System at High Pressure," Korean Chemical Engineering Research, 56(5), 732-737(2018). https://doi.org/10.9713/kcer.2018.56.5.732
  7. Byun, H. S. and Rhee, S. Y., "Phase Equilibria Measurement of Binary Mixtures for Triethylene Glycol Dimethacrylate and Triethylene Glycol Diacrylate in Supercritical $CO_2$," Korean J. of Chemical Engineering, 34(4), 1170-1176(2017). https://doi.org/10.1007/s11814-016-0332-y
  8. Yoon, Y. D. and Byun, H. S., "Experimental Measurement and Correlation of Phase Behavior for the $CO_2$ + Heptafluorobutyl Acrylate and $CO_2$ + Heptafluorobutyl Methacrylate Systems at High Pressure," Korean J. of Chemical Engineering, 31, 522-527 (2014). https://doi.org/10.1007/s11814-013-0256-8
  9. Cho, D. W., Shin, J., Bae, W., Kim, H., Lee, J. H. and Shin, M. S., "High-pressure Phase Behavior of Tri-ethylene Glycol Dimethacrylate and Tetra-ethylene Glycol Dimethacrylate in Supercritical Carbon Dioxide," Fluid Phase Equilibria, 319, 37-41(2012). https://doi.org/10.1016/j.fluid.2011.12.011
  10. Jang, Y. S., Kim, S. H., Yoo, K. P. and Byun, H. S., "Phase Behavior Measurement for the Binary Mixture of $CO_2$ + Neopentyl Glycol Diacrylate and $CO_2$ + Neopentyl Glycol Dimethacrylate Systems at High Pressure," Fluid Phase Equilibria, 302, 234-240(2011). https://doi.org/10.1016/j.fluid.2010.09.003
  11. Peng, D. Y. and Robinson, D. B., "A New Two-Constant Equation of State," Ind. Eng. Chem. Fundam., 15, 59-63(1976). https://doi.org/10.1021/i160057a011
  12. Poling, B. E., Prausnitz, J. M. and O'Connell, J. P., The Properties of Liquids and Gases, 5thed., McGraw-Hill, New York, 2001.
  13. Lee, B. S., Yeo, W. H. and Byun, H. S., "Phase Behavior for the Poly(phenyl methacrylate) and Phenyl Methacrylate in Supercritical Carbon Dioxide and Dimethyl Ether," J. Chem. Eng. Data, 62, 1876-1883(2017). https://doi.org/10.1021/acs.jced.7b00220
  14. Byun, H. S., "Phase Equilibria Measurement of Binary Mixture for the Propoxylated Neopentyl Glycol Diacrylate in Supercritical Carbon Dioxide," Korean Chemical Engineering Research, 54, 206-212(2016). https://doi.org/10.9713/kcer.2016.54.2.206
  15. Chirico, R. D., Frenkel, M., Diky, V. V., Marsh, K. N. and Wilhoit, R. C., "ThermoML-An XML-Based Approach for Storage and Exchange of Experimental and Critically Evaluated Thermophysical and Thermochemical Property Data. 2. Uncertainties," J. of Chemical Engineering Data, 48, 1344-1359(2003). https://doi.org/10.1021/je034088i
  16. Yoon, S. D. and Byun, H. S., "Phase Behaviour for the (Carbon Dioxide + 1,3-Butanediol Diacrylate) and (Carbon Dioxide +1,3-Butanediol Dimethacrylate) Systems at Elevated Pressures and Temperatures," J. of Chemical Thermodynamics, 71, 91-97(2014). https://doi.org/10.1016/j.jct.2013.11.030
  17. Jang, Y. S. and Byun, H. S., "Cloud-Point and Bubble-Point Measurement for the Poly(2-butoxyethyl acrylate) + Cosolvent Mixture and 2-Butoxyethyl Acrylate in Supercritical Fluid Solvents," J. of Chemical and Engineering Data, 59, 1391-1399(2014). https://doi.org/10.1021/je400896u
  18. Scott, R. L. and van Konynenburg, P. B., "Static Properties of Solutions - van der Waals and Related Models for Hydrocarbon Mixtures," Discuss. Faraday Soc., 49, 87-97(1970). https://doi.org/10.1039/df9704900087
  19. Rowlinson, J. S. and Swinton, F. L., Liquid and Liquid Mixtures, 3rd ed., Butterworth, Boston, 1982.
  20. Kuester, J. L. and Mize, J. H., Optimization Techniques with Fortran, McGraw-Hill, New York, 1973.
  21. https://scientificpolymer.com/shop/caprolactone-acrylate-2/.