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A critical review of slag and fly-ash based geopolymer concrete

  • Akcaoglu, Tulin (Department of Civil Engineering, Faculty of Engineering, Eastern Mediterranean University) ;
  • Cubukcuoglu, Beste (Department of Civil Engineering, Faculty of Civil and Environmental Engineering, Near East University) ;
  • Awad, Ashraf (Department of Civil Engineering, Faculty of Engineering, Eastern Mediterranean University)
  • 투고 : 2019.04.08
  • 심사 : 2019.10.15
  • 발행 : 2019.11.25

초록

Today, concrete remains the most important, durable, and reliable material that has been used in the construction sector, making it the most commonly used material after water. However, cement continues to exert many negative effects on the environment, including the production of carbon dioxide (CO2), which pollutes the atmosphere. Cement production is costly, and it also consumes energy and natural non- renewable resources, which are critical for sustainability. These factors represent the motivation for researchers to examine the various alternatives that can reduce the effects on the environment, natural resources, and energy consumption and enhance the mechanical properties of concrete. Geopolymer is one alternative that has been investigated; this can be produced using aluminosilicate materials such as low calcium (class F) FA, Ultra-Fine GGBS, and high calcium FA (class C, which are available worldwide as industrial, agricultural byproducts.). It has a high percentage of silica and alumina, which react with alkaline solution (activators). Aluminosilicate gel, which forms as a result of this reaction, is an effective binding material for the concrete. This paper presents an up-to-date review regarding the important engineering properties of geopolymer formed by FA and slag binders; the findings demonstrate that this type of geopolymer could be an adequate alternative to ordinary Portland cement (OPC). Due to the significant positive mechanical properties of slag-FA geopolymer cements and their positive effects on the environment, it represents a material that could potentially be used in the construction industry.

키워드

참고문헌

  1. Abhilash, C., Sashidhar, I.V. and Reddy, R. (2016), "Strength properties of FA and GGBS based geopolymer concrete", Int. J. Chem. Tech. Res., 9(3), 350-356.
  2. Ajay, R. (2017), "Effect of synthesis parameters on compressive strength of FA-GGBS based geopolymer", Master Thesis, National Institute of Technology Rourkela.
  3. Apoorva, S. and Namrata, F.D. (2016), "Investigations on the strength characteristics of geopolymer concrete at ambient and oven curing", Int. J. Scientif. Res. Publ., 6(1), 22-24.
  4. Arbi, K., Nedeljkovic, M., Zuo. Y. and Ye, G. (2016), "Durability of alkali-activated FA and Slag concrete", Delft University of Technology, Netherlands.
  5. Arun, B.R., Nagaraja, P.S. and Mahalingasharma, S.J. (2018), "Combined effect of flyash & GGBS on workability and mechanical properties of self compacting geopolymer concrete", Int. J. Pure Appl. Math., 119(15), 1369-1380.
  6. Chaliasou, N.A. (2015), "Recycling of FA-Slag based geopolymer cement", Master Thesis, University of Bath, Bath, UK.
  7. Chen, C.C., Diaz, I., Menozzi, K. and Murillo, L. (2015), "An experimental study on Slag/FA-based geopolymer concrete an experimental study on Slag/FA-based geopolymer concrete", Proceedings of ISER 11th International Conference, San Francisco, USA, November.
  8. Chi, M. (2016), "Mechnical strength and durability of alkali activated FA/Slag concrete", J. Marine Sci. Technol., 24(5), 958-967. https://doi.org/10.6119/JMST-016-0603-1.
  9. Criado, M., Aperador, W. and Sobrados, I. (2016), "Microstructural and mechanical properties of Alkali activated colombian raw materials", Mater. J., 9, 158-161. https://doi.org/10.3390/ma9030158.
  10. Davidovits, J., Izquierdo, M., Querol, X., Antennuci, D., Nugteren, H., Butselaar-Orthlieb, V., ... & Luna, Y. (2014), "The European research project GEOASH: geopolymer cement based on European coal FAes", Geopolymer Institute Library, Paris, France.
  11. Deb, P.S., Nat, P. and Sarker, P.K. (2015), "Drying shrinkage of slag blended FA geopolymer concrete cured at room temperature", Procedia Eng., 125, 594-600. https://doi.org/10.1016/j.proeng.2015.11.066
  12. Devi, S., Lakshmi, V.V. and Alakanandana, A. (2017), "Impacts of cement industry on environment - an overview", Asia Pacific J. Res., 1(17), 156-161.
  13. Dhavamani, A. and Sundararajan, R. (2018), "Effects of FA and blast furnace slag on the performance of self-compacting geopolymer concrete", Int. J. Civil Eng. Technol., 9(1), 953-964.
  14. Gao, X., Yu, Q.L. and Brouwers, H.J.H. (2016), "Assessing the porosity and shrinkage of alkali activated slag-FA composites designed applying a packing model", Constr. Build. Mater., 119, 175-184. https://doi.org/10.1016/j.conbuildmat.2016.05.026.
  15. Ghosh, K. and Rasayan, P.G. (2018), "Effect of variation of slag content on chemical, engineering and microstructural properties of thermally cured FA-Slag based geopolymer composites", Rasayan J. Chem., 11(1), 426-439.
  16. Gopalakrishnan, R. and Chinnaraju, K. (2016), "Durability of alumina silicate concrete based on Slag/Fly-ash blends against acid and chloride environments", Mater. Technol., 50(6), 929-937. https://doi.org/10.17222/mit.2015.230.
  17. Hameed, A.M., Rawdhan, R.R. and Al-Mishhadani, S.A. (2017), "Effect of various factors on the manufacturing of geopolymer mortar", Arch. Sci., 1(3), 1-8. https://doi.org/10.5114/aoms.2017.64712
  18. Jawahar, J. and Mounika, G. (2016), "Strength properties of FA and GGBS based geo polymer concrete", Asian J. Civil Eng., 17, 127-135.
  19. Jawahar, J., Lavanya, D. and Sashidhar, C. (2016), "Performance of FA and GGBS based geopolymer concrete in acid environment", Int. J. Res. Scientif. Innov., 3(2), 101-104.
  20. Jeyasehar, A., Salahuddin, M. and Thirugnanasambandam, S. (2013), "Development of fa based geopolymer concrete precast elements", Annamalai University.
  21. Jindal, B.B. (2018), "Feasibility study of ambient cured geopolymer concrete-A review", Adv. Concrete Constr., 6(4), 387-405. https://doi.org/10.12989/acc.2018.6.4.387.
  22. Kim, H. and Kim, Y. (2012), "Characteristics of the geopolymer using FA and blast furnace slag with Alkaline activators", Proceedings of the 4th International Conference on Chemical, Biological and Environmental Engineering, 43, IACSIT Press, Singapore.
  23. Kumar, S., Vasugi, J., Ambily, P.S. and Bharatkumar, B.H. (2013), "Development and determination of mechanical properties of FA and slag blended geo polymer concrete", Int. J. Scientif. Eng. Res., 4(8), 1-6.
  24. Lee, N.K., An, G.H., Koh, K.T. and Ryu, G.S. (2016), "Improved reactivity of FA-Slag geopolymer by the addition of silica fume", Adv. Mater. Sci. Eng., 2016, Article ID 2192053, 11. http://dx.doi.org/10.1155/2016/2192053.
  25. Liu, Y., Zhang, K., Feng, E., Zhao, H. and Liu, F. (2017), "Synthesis of geopolymer composites from a mixture of ferronickel slag and FA", Mater. Sci. Eng., 82(1), 012038. https://doi.org/10.1088/1757-899X/182/1/012038.
  26. Mahendran and Arunachelam, N. (2016), "Performance of FA and copper slag based geopolymer concrete", Ind. J. Sci. Technol., 9(2), 2-6.
  27. Marcin, M., Sisol, M. and Brezani, I. (2016), "Effect of slag addition on mechanical properties of FA based geopolymers", International Conference on Ecology and new Building materials and products, ICEBMP, 151, 191-197.
  28. Mathew, N.S. and Usha, S. (2015), "Study on strength and durability of FA and GGBFS based geopolymer concrete", Int. Res. J. Eng. Technol. (IRJET), 2(5), 1330-1339.
  29. Mehta, A. and Kumar, K. (2016), "Strength and durability characteristics of FA and slag based geopolymer concrete". Int. J. Civil Eng. Technol., 7(5), 305-314.
  30. Mithanthaya and Rao, N.B. (2015), "Effect of glass powder and GGBS on strength of FA based geopolymer concrete", Int. J. Eng. Trend. Technol. (IJETT), 19(2), 66-71. https://doi.org/10.14445/22315381/IJETT-V19P213
  31. Naidu, G., Prasad, A.S.S.N., Adiseshu, S. and Satayanarayana, P.V.V. (2012), "A study on strength properties of geopolymer concrete with addition of G.G.B.S", Int. J. Eng. Res. Develop., 2(4), 19-28.
  32. Oss, V. (2018), Minerals Yearbook, United States Geological Survey, USA.
  33. Partha, D., Pradip, N. and Prabir, S. (2013), "Strength and permeation properties of slag blended FA based geopolymer concrete", Adv. Mater. Res., 651, 168-173. https://doi.org/10.4028/www.scientific.net/AMR.651.168.
  34. Parthiban, K., Saravanarajamohan, S., Shobana, A. and Bhaskar, A. (2013), "Effect of replacement of slag on the mechanical properties of flyash based geopolymer concrete", Int. J. Eng. Technol. (IJET), 5(3), 2555-2561.
  35. Pilehvar, S., Cao, V.D., Szczotok, A.M., Carmona, M., Lanzon, L.V.M., Pamies, R. and Kjoniksen, A.L. (2018), "Physical and mechanical properties of FA and slag geopolymer concrete containing different types of micro-encapsulated phase change materials", Constr. Build. Mater., 173, 28-39. https://doi.org/10.1016/j.conbuildmat.2018.04.016.
  36. Pradip, N and Prabir, S. (2017), "Fracture properties of GGBFSblended FA geopolymer concrete cured in ambient temperature", Mater. Struct., 50(1), 1-29. https://doi.org/10.1016/j.conbuildmat.2018.09.138.
  37. Pratap, B. and Abhilash, P. (2016), "Studies on mechanical properties of geo polymer concrete with flyash and slag for different molarities", Int. J. Eng. Technol. (IJET), 3(8), 1117-1122.
  38. Qureshi, M.S. and Tuvar, T. (2017), "An experimental investigation on GGBFS and FA based geopolymer concrete", IJSTE-Int. J. Sci. Technol. Eng., 3(11), 1-6.
  39. Rajan, B.R. and Ramujee. K. (2015), "Strength & development of FA and GGBS based feopolymer mortar", Int. J. Recent Adv. Eng. Technol. (IJRAET), 3(1), 42-45.
  40. Rajini, B. and Rao, A.V. (2014), "Mechanical properties of geopolymer concrete with FA and GGBS as source materials", Int. J. Innov. Res. Sci., Eng. Technol., 3(9), 15944-15953. https://doi.org/10.15680/IJIRSET.2014.0309023
  41. Rashad, A.M. (2013), "Properties of alkali-activated fly ash concrete blended with slag", Iran. J. Mater. Sci. Eng., 10(1), 57-64.
  42. Shah, A. (2017), "Optimum utilization of GGBS in FA based geopolymer concrete", Kalpa Publ. Civil Eng., 1, 431-440. https://doi.org/10.29007/8g7b
  43. Shaikh, F.U. (2014), "Effects of Alkali solutions on corrosion durability of geopolymer concrete", Adv. Concrete Constr., 2(2), 109-123. https://doi.org/10.12989/acc.2014.2.2.109.
  44. Sheral, R.B., Sutar, D. and Jagdane, P. (2016), "Utilization of Waste Materials (GGBS+FA)", Int. J. Lat. Technol. Eng., Manage. Appl. Sci. (IJLTEMAS), 5(7), 67-71.
  45. Singh, J.P., Sinha, D.K, Kumar, S, Jain, M.K. and Kumar, A. (2018), "ETP sludge as filler and the role of AOD slag & GBFS in FA-slag-sludge blended geopolymer", MOJ Civil Eng., 4(5), 379-384. https://doi.org/10.15406/mojce.2018.04.00132
  46. Srinivas, T. and Rao, N.V.R. (2016), "Development and optimization of mix design of low calcium FA and slag based geopolymer concrete for standard grade", IOSR J. Mech. Civil Eng. (IOSR-JMCE), 13(4), 39-47.
  47. Srinivas, T. and Rao, N.V.R. (2016), "Studies on acid attack resistance of low calcium fly ash and slag based geopolymer concrete", Int. J. Res. Eng. Technol., 5(20), 216-227.
  48. Takekar, A. and Patil, G.R. (2017), "Experimental study on mechanical properties of FA and GGBS based geopolymer concrete", Int. Res. J. Eng. Technol. (IRJET), 4(8), 18-23
  49. Thakkar, S.P., Bhorwani, D.J. and Ambaliya, R. (2014), "Geopolymer concrete using different source materials", Int. J. Emerg. Technol. Adv. Eng., 4(4), 10-16.
  50. UNEP (2017), The Emissions Gap Report 2017, United Nations Environment Program (UNEP), Nairobi United Nations Environment Program, Paris, France.
  51. Wardhono, A., David, W.L., Sutikno, and Dani, H. (2017), "The effect of slag addition on strength development of Class C FA geopolymer concrete at normal temperature", Proceedings of the Green Construction and Engineering Education (GCEE) Conference, Malang, East Java, September.
  52. Zaina, F.F., Amli, S.F.M., Hussin, K., Rahmat, A. and Abdullah, M.A.B. (2017), "Corrosion studies of FA and FA-slag based geopolymer", Mater. Sci. Eng., 209, 1-6. https://doi.org/10.1016/0921-5093(95)10120-9