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Formation Characteristics of Hard Anodizing Films on 6xxx Aluminum Alloys

6xxx계 알루미늄 합금의 경질 아노다이징 피막 형성 특성 연구

  • Moon, Sanghyuck (Material Process Engineering, Gyeongsang National University) ;
  • Moon, Sungmo (Surface Technology Division, Korea Institute of Materials Science) ;
  • Lim, Sugun (Material Process Engineering, Gyeongsang National University)
  • 문상혁 (경상대학교 재료공정융합공학과) ;
  • 문성모 (재료연구소 표면기술연구본부) ;
  • 임수근 (경상대학교 재료공정융합공학과)
  • Received : 2019.08.15
  • Accepted : 2019.08.29
  • Published : 2019.08.30

Abstract

In this work, anodizing behavior of 6xxx series aluminum alloys was studied under constant current density and constant voltage conditions in 20% sulfuric acid solution by V-t curves, I-t curves, thickness measurement, observations of surface appearance and cross-sectional observation of anodizing films. The film growth rate of the anodizing films on Al6063, Al6061 and Al6082 obtained at 20 V were $0.63{\mu}m/min$. $0.46{\mu}m/min$ and $0.38{\mu}m/min$, respectively. Time to the initiation of imperfections at the oxide/substrate interface under constant current condition was shortened and colors of anodizing films became darker with the amount of alloying elements in 6xxx series aluminum alloys. Based upon the experimental results obtained in this work, it is concluded that maximum anodizing film thickness without interfacial defects is reduced with increasing amount of alloying elements and brighter anodizing films can be obtained by decreasing amount of alloying elements in the aluminum alloys.

Keywords

References

  1. Sungmo Moon, Anodic Oxidation Treatment Methods of Metals, Kor. Inst. Surf. Eng., 51 (2018) 1-10.
  2. 정용수, 박영희, 장관섭, 문성모, 최진섭, 정윤미, 실용표면처리기술시리즈 제 5권 양극산화, 화신문화(주), (2014) 3.
  3. S.-M. Moon and S.-I. Pyun, Growth Mechanism of Anodic Oxide Film on Pure Aluminium in Acidic and Alkaline Solutions, J. of Solid State Electrochemistry 2 (1998) 156-161. https://doi.org/10.1007/s100080050081
  4. S.-M. Moon and S.-I. Pyun, A review of Al anodizing, J. Corros. Sci. Soc. of Korea 26 (1997) 498-508.
  5. Y.-S. Kim, S.-I. Pyun, S.-M. Moon and J.-D. Kim, The Effects of Applied Potential and pH on the Electrochemical Dissolution of Barrier Layer in Porous Anodic Oxide Film on Pure Aluminium, Corrosion Science 38 (1996) 329-336. https://doi.org/10.1016/0010-938X(96)00131-X
  6. Sungmo Moon, Kihun Jeong, Sugun Lim. Formation Behavior of Anodic Oxide Films on Al 6061 Alloy in Sulfuric Acid Solution, J. Corros. Sci. Soc. of Korea 51 (2018) 393-399.
  7. Sungmo Moon, Cheolnam Yang, Sangjo Na, Formation Behavior of Anodic Oxide Films on Al7075 Alloy in Sulfuric Acid Solution, J. Kor. Inst. Surf. Eng., 47 (2014) 155-161. https://doi.org/10.5695/JKISE.2014.47.4.155
  8. Y. Ma, X. Zhou, G. E. Thompson, M. Curioni, M. Fowles, Discontinuities in the porous anodic film formed on AA2099-T8 aluminium alloy, Corrosion Science 53 (2011) 4141-4151. https://doi.org/10.1016/j.corsci.2011.08.023
  9. S. Moon, Y. Nam, C. Yang, Y. Jeong, Growth of anodic oxide films on AC2A alloy in sulphuric acid solution, Corrosion Science 53 (2011) 1547-1553. https://doi.org/10.1016/j.corsci.2011.01.029
  10. X. Zhou, G. e. Thompson, P. Skeldon, G. C. Wood, H. Habazaki, Film formation and detachment during anodizing of Al-Mg alloys, Corrosion Science 41 (1999) 1599-1613. https://doi.org/10.1016/S0010-938X(99)00007-4