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Effects of Different Photo-thermal Curing Conditions on the Curing and Mechanical Properties of Dual Curable Resin TPEE Mono-filament

광·열복합경화조건에 따른 폴리우레탄 아크릴레이트계 수지를 이용한 TPEE Mono-filament의 경화성 및 물성 연구

  • Choi, Joo Hwan (Busan Textile Materials Promotion Center, Korea Dyeing & Finishing Technology Institute) ;
  • Kim, A Rong (Busan Textile Materials Promotion Center, Korea Dyeing & Finishing Technology Institute)
  • Received : 2019.09.13
  • Accepted : 2019.10.05
  • Published : 2019.10.31

Abstract

Flexibility and hardness are very important for expressing color in textile materials using UV curing technology. In the preceding study, the lack of hardness resulted in dye migration challenges. In this study, we investigated the effects of an oligomer, hardener content ratios, and curing time on the UV and thermal dual curable resin on thermoplastic copolyester (TPEE) mono-filament while maintaining flexibility. We observed that an O-3 oligomer with $13,000mPa{\cdot}s$ viscosity, 11.25:4.65 ratio of HDI/Photoinitiator, photocuring time of 40 s, and thermal curing time of 5 min, showed the best formula conditions. By dual curable resin treatment of the TPEE filament, the tensile strength increased under all UV and heat treatments, but the elongation increased after 10 min of heat treatment. We also observed the surface and cross-section of the dual curing TPEE mono-filament.

Keywords

References

  1. T. H. Oh, "Trend of Eco-friendly Fiber Technology Development", Textopia, 2017.
  2. M. M. El-Molla, "Synthesis of Polyurethane Acrylate Oligomers as Aqueous UV-curable Binder for Inks of Ink Jet in Textile Printing and Pigment Dyeing", Dyes. Pigm., 2007, 74, 371-379. https://doi.org/10.1016/j.dyepig.2006.02.021
  3. K. Lawson, "The Status of UV/EB Curable Products in North America", RadTech Asia'99 Conf. Proc., Kuala Laumpur, pp.1-14, 1999.
  4. J. H. Jang, "Textile Finishing Technology of UV Curing", Fiber Technol. Ind., 2003, 7, 303-321.
  5. E. Dzunuzovic, S. Tasic, B. Bozic, and D. Babic, "UV Curable Hyper Branched Urethane Acrylate Oligomers Containing Soybean Fatty Acids", Prog. Org. Coat., 2004, 52, 136-143. https://doi.org/10.1016/j.porgcoat.2004.10.003
  6. N. S. Allen, "Photoinitiators for UV and Visible Curing of Coatings: Mechanisms and Properties", J. Photochem. Photobiol. A: Chem., 1996, 100, 101-107. https://doi.org/10.1016/S1010-6030(96)04426-7
  7. J. H. Choi, Y. H. Yoon, and C. H. Jeong, "Effects of Different Synthesis Conditions on Mechanical and Curing Properties of UV Curable Resin Films", Text. Sci. Eng., 2018, 55, 215-220. https://doi.org/10.12772/TSE.2018.55.215
  8. S. A. Seyedmehdi and M. Ebrahimi, "The Impact of Hardener Concentration, Curing Temperature, Thickness and Alumina Trihydrate (ATH) on Superhydrophobic Modified-polyurethane Coatings for Insulators", Progr. Org. Coat., 2018, 124, 99-103. https://doi.org/10.1016/j.porgcoat.2018.07.037
  9. J. W. Bae, J. H. Jung, H. S. Wang, S. H. Kim, I. J Kim, I. J. Kim, and K. G. Song, "Dual Curing Characteristics of Photocurable Acrylate Monomers", Polymer(Korea), 2017, 41, 361-366. https://doi.org/10.7317/pk.2017.41.2.361
  10. Y. Bi, Z. Li, N. Wang, and L. Zhang, "Preparation and Characterization of UV/thermaldual-curable Polyurethane Acrylate Adhesive for Inertial Confinement Fusion Experiment", Int. J. Adhes. Adhes., 2016, 66, 9-14. https://doi.org/10.1016/j.ijadhadh.2015.11.009
  11. Y. J. Park, D. H. Lima, H. J. Kim, D. S. Park, and I. K. Sung, "UV-andthermal-curing Behaviors of Dual-curable Adhesives Based on Epoxy Acrylate Oligomers", Int. J. Adhes. Adhes., 2009, 29, 710-717. https://doi.org/10.1016/j.ijadhadh.2009.02.001
  12. D. Kunwong, N. Sumanochitraporn, and S. Kaewpirom, "Curing Behavior of a UV-curable Coating based on Urethane Acrylate Oligomer: the Influence of Reactive Monomers", Songklanakarin J. Sci. Technol., 2011, 33, 201-207.
  13. J. Y. Choi, D. J. Lee, and H. D. Kim, "Preparation and Properties of UV-Curable Polyurethane Acrylates(I)", J. Korean Soc. Dyers Finish., 1999, 11, 1-7.
  14. C. Decker, F. Masson, and R. Schwalm, "Dual-Curing of Waterborne Urethane-Acrylate Coatings by UV and Thermal Processing", Macromol. Mater. Eng., 2003, 288, 17-28. https://doi.org/10.1002/mame.200290029
  15. J. H. Sim, J. H. Kim, S. M. Park, K. H. Koo, K. W. Jang, and J. S. Bae, "Mechanical Characteristics of CF Laminated Prepreg with UV-thermal Dual Curable Epoxy Resin", J. Korean Soc. Dyers Finish., 2017, 29, 37-44.