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The properties of optical glass of BaO-GeO2-La2O3 system with ZnO

ZnO가 포함된 BaO-GeO2-La2O3 계 광학 유리 특성

  • Lee, Ji-Sun (Optic & Electric Components Materials Center, Korea Institute of Ceramic Engineering and Technology) ;
  • Lim, Tae-Young (Optic & Electric Components Materials Center, Korea Institute of Ceramic Engineering and Technology) ;
  • Hwang, Jonghee (Optic & Electric Components Materials Center, Korea Institute of Ceramic Engineering and Technology) ;
  • Lee, Youngjin (Optic & Electric Components Materials Center, Korea Institute of Ceramic Engineering and Technology) ;
  • Jeon, Dae-Woo (Optic & Electric Components Materials Center, Korea Institute of Ceramic Engineering and Technology) ;
  • Kim, Sun-Woog (Optic & Electric Components Materials Center, Korea Institute of Ceramic Engineering and Technology) ;
  • Ra, Yong-Ho (Optic & Electric Components Materials Center, Korea Institute of Ceramic Engineering and Technology) ;
  • Kim, Jin-Ho (Optic & Electric Components Materials Center, Korea Institute of Ceramic Engineering and Technology)
  • 이지선 (한국세라믹기술원 광전자부품소재센터) ;
  • 임태영 (한국세라믹기술원 광전자부품소재센터) ;
  • 황종희 (한국세라믹기술원 광전자부품소재센터) ;
  • 이영진 (한국세라믹기술원 광전자부품소재센터) ;
  • 전대우 (한국세라믹기술원 광전자부품소재센터) ;
  • 김선욱 (한국세라믹기술원 광전자부품소재센터) ;
  • 라용호 (한국세라믹기술원 광전자부품소재센터) ;
  • 김진호 (한국세라믹기술원 광전자부품소재센터)
  • Received : 2019.08.26
  • Accepted : 2019.10.01
  • Published : 2019.10.31

Abstract

The glass of $BaO-GeO_2-La_2O_3-ZnO$ system with a transmittance of more than 75 % at mid-wave infrared (MWIR) region in the range of $3{\mu}m$ to $5{\mu}m$ is manufactured and its property is evaluated. After selecting construction that can melt glass through flow button test, $BaO-GeO_2-La_2O_3$ system where 10 mol%, 20 mol% of ZnO were added respectively were melted at $1350^{\circ}C$ for 1 hour and $BaO-GeO_2-La_2O_3$ system of glass was manufactured. Among them, with 20 mol% of ZnO, 16 mol% BaO-56 mol% $GeO_2-8mol%$ $La_2O_3-16mol%$ ZnO system of glass was found to has less than $660^{\circ}C$ of glass transition temperature, more than 1.70 of refractive index, and more than 530 of knoop hardness. Therefore, it is concluded that glass of $BaO-GeO_2-La_2O_3-ZnO$ system of glass with 20 mol% ZnO has good melting conditions at low temperatures and excellent optical properties, thus, can be utilized for special optical materials field.

$3{\sim}5{\mu}m$ 범위의 중적외선에서 75 % 이상의 투과율을 갖는 $BaO-GeO_2-La_2O_3-ZnO$ 계 유리를 제조 및 특성을 평가하였다. Flow button test를 통해 유리 용융이 가능한 조성을 선택 후, ZnO를 10 mol%, 20 mol% 각각 첨가하여 $1350^{\circ}C$에서 1시간 동안 용융하여 $BaO-GeO_2-La_2O_3-ZnO$ 계 유리를 제조하였다. 이 중에서 ZnO를 20 mol% 포함하는 16 mol% BaO-56 mol% $GeO_2-8mol%$ $La_2O_3-20mol%$ ZnO 계 유리 전이 온도 $660^{\circ}C$ 이하, 굴절률 1.70 이상, Knoop 경도 530 이상 값을 가지는 것을 확인하였다. 따라서, ZnO를 20 mol% 포함하는 $BaO-GeO_2-La_2O_3-ZnO$ 계 유리는 저온에서 양호한 용융 상태와 우수한 광학적 특성을 확인하였고 특수 광학용 재료 분야에 충분히 활용이 가능하리라 판단되었다.

Keywords

References

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