Journal of Electrochemical Science and Technology

The Korean Electrochemical Society (한국전기화학회)
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A New Fe (III)-Selective Membrane Electrode Based on Fe (II) Phthalocyanine

  • Ozer, Tugba (Faculty of Chemistry-Metallurgy, Department of Bioengineering, Yildiz Technical University) ;
  • Isildak, Ibrahim (Faculty of Chemistry-Metallurgy, Department of Bioengineering, Yildiz Technical University)
  • Received : 2019.03.31
  • Accepted : 2019.05.03
  • Published : 2019.09.30
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Abstract

A new miniaturized all solid-state contact Fe (III)-selective PVC membrane electrode based on Fe (II) phthalocyanine as a neutral carrier was described. The effects of the membrane composition and foreign ions on the electrode performance was investigated. The best performance was obtained with a membrane containing 32% poly (vinyl chloride), 64% dioctylsebacate, 3% Fe (II) phthalocyanine, and 1% potassium tetrakis (p-chlorophenyl) borate. The electrode showed near Nernstian response of $26.04{\pm}0.95mV/decade$ over the wide linear concentration range $1.0{\times}10^{-6}$ to $1.0{\times}10^{-1}M$, and a very low limit of detection $1.8{\pm}0.5{\times}10^{-7}M$. The potentiometric response of the developed electrode was independent at pH 3.5-5.7. The lifetime of the electrode was approximately 3 months and the response time was very short (< 7 s). It exhibited excellent selectivity towards Fe (III) over various cations. The miniaturized all solid-state contact Fe (III)-selective membrane electrode was successfully applied as an indicator electrode for the potentiometric titration of $1.0{\times}10^{-3}M$ Fe (III) ions with a $1.0{\times}10^{-2}M$ EDTA and the direct determination of Fe (III) ions in real water samples.

Keywords

References

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