DOI QR코드

DOI QR Code

A Study on the Property Change of the Transparent Film for Vehicle Cover according to Weathering Test

차량 덮개용 투명 필름 내후 시험에 따른 물성변화 연구

  • Kim, Ji-Hoon (Defense Agency for Technology and Quality, Combat Material Center) ;
  • Kim, Byung-Soon (Defense Agency for Technology and Quality, Combat Material Center)
  • 김지훈 (국방기술품질원 전투물자센터) ;
  • 김병순 (국방기술품질원 전투물자센터)
  • Received : 2019.05.22
  • Accepted : 2019.08.02
  • Published : 2019.08.31

Abstract

In this study, we evaluated and analyzed the properties of polymeric transparent films used in military vehicle covers according to weathering test. Two types of polymer films (Film A and Film B) that are mostly used for military vehicle covers were selected. The weathering treatment condition and tester are described in KS K 0706, and the following weathering times were tested: 0hour, 40hours, 160hours and 320 hours. The tensile strength, elongation and thermal decomposition behavior and optical characteristics were analyzed. The tensile strength tended to decrease - increase - decrease with increasing weathering treatment time in both transparent films. The thermal decomposition temperature gradually decreased. Regarding the optical property, the light transmittance decreased and the haze tended to increase. However, film A showed almost similar optical characteristics after 160-hour weathering treatment.

본 연구에서는 군용 차량 덮개에 사용되는 고분자 투명 필름에 대한 내후 처리 후 광학적 특성에 대해 평가 및 분석을 진행하였다. 이를 위해서 군용 차량 덮개에 대부분 사용되고 있는 고분자 투명 필름 2종을 선정하여 내후 처리를 진행 하였다. 내후 처리는 KS K 0706에 명시된 내후 시험기를 사용하여 진행하였으며, 내후 처리 시간은 각각 0시간, 40시간, 160시간, 320시간으로 하였다. 내후 처리 이후 각 시간별로 내후 처리된 시료를 바탕으로 인장강도, 신도 및 열 분해 거동, 그리고 광학적 특성(광 투과율 및 흐림도)을 분석하였다. 분석 결과 2종 고분자 투명 필름 모두 처리 시간이 증가함에 따라 인장강도는 감소-증가-감소의 경향을 보이고 신도는 반대경향을 보임을 확인하였다. 또한 처리 시간이 길어질수록 열분해 온도가 점차 낮아지는 현상을 확인할 수 있었다. 마지막으로 광학적 특성의 경우 내후처리 시간이 길어질수록 투과율은 감소하고 흐림도는 증가하는 경향을 보였으나 일정 시간 이후에는 거의 유사한 변화거동을 보임을 알 수 있었다.

Keywords

References

  1. S. Chen, Y. Liu, C. Shao, R. Mu, Y. Lu, J. Zhang, D. Shen and X. Fan "Structural and Optical Properties of Uniform ZnO Nanosheets", Adv. Mater., Vol17, No.5, pp.586-590, Mar. 2005. DOI: https://doi.org/10.1002/adma.200401263
  2. J. Soulestin B. J. Rashmi, S. Bourbigot, M. F. Lacrampe, and P. Krawczak "Mechanical and Optical Properties of Polyamide 6/Clay Noncomposite Cast Films: Influence of the Degree of Exfoliation", Macromol. Mater. Eng., Vol297 No. 5, pp.444-454, Dec. 2012. DOI: https://doi.org/10.1002/mame.201100202
  3. S. M. Lee, V. Ischenko, E. Pippel, A. Masic, O. Moutanabbir, P. Fratzl, and M. Knez "An Alternative Route Towards Metal-Polymer Hybrid Materials Prepared by Vapor-Phase Processing", Adv. Funct. Mater., Vol21, No. 16, pp.3047-3055, Jun. 2011. DOI: https://doi.org/10.1002/adfm.201100384
  4. C. H. Park, S. J. Lee, T. H. Lee, and H. J. Kim, "Characterization of an acrylic polymer under hygrothermal aging as an optically clear adhesive for touch screen panels", International Journal of Adhesion and Adhesives, Vol636, pp.137-144, Sep. 2015. DOI: https://doi.org/10.1016/j.ijadhadh.2015.08.012
  5. H. Yabu and M. Shimomura, "Single-Step Fabrication of Transparent Superhydrophobic Porous Polymer Films", Chemistry of Materials, Vol17, No. 21, pp.5231-5234, Sep. 2005. DOI: https://doi.org/10.1021/cm051281i
  6. X. Yang and X. Ding, "Prediction of outdoor weathering performance of polypropylene filaments by accelerated weathering tests", Geotextiles and Geomembranes, Vol24 No. 2, pp.103-109, Jan. 2006. DOI: https://doi.org/10.1016/j.geotexmem.2005.11.002
  7. S. D. Hong, B. S. Kim, Y. M. Jeon, and J. S. Lee, "A Study on the Improved Lightfastness Test Method for Military Textile Products",, Textile Coloration and Finishing, Vol27, No.4 pp.288-300, Nov. 2015. DOI: https://dx.doi.org/10.5764/TCF.2015.27.4.288
  8. X. F. Yanga, D. E. Tallmana, G. P. Bierwagenb, S. G. Crollb, and S. Rohlika, "Blistering and degradation of polyurethane coatings under different accelerated weathering tests", Polymer Degradation and Stability, Vol77 Np. 1, pp.103-109, Feb. 2002. DOI: https://doi.org/10.1016/S0141-3910(02)00085-X
  9. Q. Zhao, Z. Jia, X. Li, Z. Ye "Surface degradation of unsaturated polyester resin in Xe artificial weathering environment", Materials and Design, Vol31, No. 9 pp.4457-4460, Apr. 2010. DOI: https://doi.org/10.1016/j.matdes.2010.04.004
  10. J. R. Lin and L. W. Chen, "Study on Shape-Memory Behavior of Polyether-Based Polyurethanes. I. Influence of the Hard-Segment Content", Journal of Applied Polymer Science, Vol69, No. 8, pp.1563-1574, Jan. 1998. DOI: https://doi.org/10.1002/(SICI)1097-4628(19980822)69:8<1563::AID-APP11>3.0.CO;2-W
  11. H. Miao, F. Bao, L. Cheng, and W. Shi "Fluorinated modification of hyperbranched polyesters used for improving the surface property of UV curing coatings", Journal of Fluorine Chemistry, Vol131, No.12 pp.1356-1361, Oct. 2010. DOI: https://doi.org/10.1016/j.jfluchem.2010.09.008