Fig. 1. Comparison of experimental flash points with calculated flash points for n-propanol(1)+n-hexanol(2) system.
Fig. 2. Comparison of experimental flash points with calculated flash points for n-butanol(1)+n-hexanol(2) system.
Table 1. Antoine coefficients of pure components
Table 2. Estimated lower explosive limit(LELm), normal boiling point(Tnb,m) and average number of carbon atoms(n) for n-propanol(1)+n-hexanol(2) system
Table 3. Estimated lower explosive limit(LELm), normal boiling point(Tnb,m) and average number of carbon atoms(n) for n-butanol(1)+n-hexanol(2) system
Table 4. Estimated and mearsured flash points for n-propanol(1) +n-hexanol(2)
Table 5. Estimated and mearsured flash points for n-butanol(1) +n-hexanol(2)
참고문헌
- L. Y. Phoon, A. A. Mustaffa, H. Hashim, and R. Mat, "A Review of Flash Point Prediction Models for Flammable Liquid Mixtures", Ind. Eng. Chem. Res., Vol. 53, pp. 12553-12565, 2014. https://doi.org/10.1021/ie501233g
- J. R. Rowley, D. K. Freeman, R. L. Rowley, J. L. Oscarson, N. F. Giles and W. V. Wilding, "Flash Point : Evaluation, Experimentation and Estimation", Int J Themophys, Vol. 31, pp. 875-887, 2010. https://doi.org/10.1007/s10765-010-0716-x
- D. A. Crowl and J. F. Louver, "Chemical Process Safety Fundamentals with Applications", Prentice-Hall, 1990.
- S. Y. Kim and B. S. Lee, "Multivariate Statistical Analysis and Prediction for the Flash Points of Binary Systems Using Physical Properties of Pure Substances", KIGAS, Vol. 11, No. 3, pp. 13-18, 2007.
- D. M. Ha and S. J. Lee, "Dew Point Prediction by Lower Flash Points of Binary Mixtures", J. Korean Soc. Saf., Vol. 32, No. 6, pp. 34-39, 2017. https://doi.org/10.14346/JKOSOS.2017.32.6.34
- W. A. Affens and G.W. Mclaren, "Flammability Properties of Hydrocarbon Solutions in Air", J. of Chem. Ind. Eng. Chem. & Eng. Data, Vol. 17, No. 4, pp. 482-488, 1972. https://doi.org/10.1021/je60055a040
- B. Hanley, "A Model for the Calculation and the Verification of Closed Cup Flash Points for Multicomponent Mixtures", Process Saf. Prog., Vol. 17, No. 2, pp. 86-97, 1998. https://doi.org/10.1002/prs.680170204
- B. E. Poling, J. M. Prausnitz, and J. P. O'Connell, "The Properties of Gases and Liquids", 5th Ed., McGraw-Hill, New York, 2001.
- H. J. Liaw, Y. H. Lee, C. L. Tang, H. H. Hsu, and J. H. Liu, "A Mathematical Model for Predicting the Flash Point of Binary Solutions", J. of Loss Prevention in the Process Industries, Vol. 15, pp. 429-438, 2002. https://doi.org/10.1016/S0950-4230(02)00068-2
- H. L. Chatelier, "Estimation of Firedamp by Flammability Limits", Ann. Minmes, Vol. 19, No. 8, pp. 388-395, 1891.
- J. Wang and Z. H. Bao, "Investigation on Vapor-Liquid Equilibrium for 2-Propanol + 1-Butanol + 1-Pentanol at 101.3 kPa", Fluid Phase Equilibria, Vol. 341, pp. 30-34, 2013. https://doi.org/10.1016/j.fluid.2012.12.020
- H. J. Liaw, V. Gerbaud, and Y. H. Li, "Prediction of Miscible Mixtures Flash-Point from UNIFAC Group Contribution Method", Fluid Phase Equilibria, Vol. 300, pp. 70-82, 2013. https://doi.org/10.1016/j.fluid.2010.10.007
- D. M. Ha and S. J. Lee, "The Measurement and Prediction of Maximum Flash Point Behavior for Binary Solution", Fire Sci. Eng., Vol. 27, No. 5, pp. 1-5, 2013. https://doi.org/10.7731/KIFSE.2013.27.5.1
- In 2011 Annual Book of ASTM Standards, "Standard Test Methods for Flash Point of Liquids by Tag Open-Cup Apparatus(ASTM D1310)", West Conshohocken, PA, 2007.
- J. Gmehing, U. Onken, and W. Arlt, "Vapor-Liquid Equilibrium Data Collection", Vol. 1, Part1-Part7, DECHEMA, 1980.
- L. Caoire, S. Paulmier, and V. Naudet, "Estimation of Closed Cup Flash Points of Combustible Solvent Blends",
- S. Y. Kim, B. S. Lee, C.B. Chung, and S. H. Choi, "Prediction of Flash Point of Binary Systems by Using Multivariate Statistical Analysis", KIGAS, Vol. 10, No. 4, pp. 29-33, 2006.
- D. M. Ha and S. J. Lee, "Prediction of Lower Explosive Limits of Binary Liquid Mixtures by Means of Solution Thermodynamics", KIGAS, Vol. 13, No. 5, pp. 20-24, 2009.
- D. M. Ha, "Prediction of Explosive Limits by Using Flash Points for Alcohol Compounds", Theories and Applications of Chemical Engineering, Vol. 7, No. 2, pp. 3023, 2001.
- D. M. Ha and S. J. Lee, "The Measurement and Estimation of Lower Flash Points for the n-Propanol+ Acetic acid and n-Propanol+n-Propionic acid Systems", J. Korean Soc. Saf., Vol. 22, No. 4, pp. 37-42, 2007.