Membrane and Water Treatment

  • 제10권3호
  • /
  • Pages.239-244
  • /
  • 2019
  • /
  • 2005-8624(pISSN)
  • /
  • 2092-7037(eISSN)
테크노프레스 (Techno-Press)
권호 표지
DOI QR코드

DOI QR Code

Pilot scale membrane separation of plating wastewater by nanofiltration and reverse osmosis

  • Jung, Jaehyun (Department of Environment and Energy, Sejong University) ;
  • Shin, Bora (Department of Environment and Energy, Sejong University) ;
  • Lee, Jae Woo (Department of Environmental Engineering, Korea University) ;
  • Park, Ki Young (Department of Civil and Environmental System Engineering, Konkuk University) ;
  • Won, Seyeon (Han-River Environment Research Center, Water Environment Chemistry Research Lab) ;
  • Cho, Jinwoo (Department of Environment and Energy, Sejong University)
  • 투고 : 2018.10.24
  • 심사 : 2018.12.27
  • 발행 : 2019.05.25
⟨ 이전 논문 다음 논문 ⟩

초록

Plating wastewater containing various heavy metals can be produced by several industries. Specifically, we focused on the removal of copper (Cu2+) and nickel (Ni+) ions from the plating wastewater because all these ions are strictly regulated when discharged into watershed in Korea. The application of both nanofiltration (NF) and reverse osmosis (RO) technologies for the treatment of wastewater containing copper and nickel ions to reduce fresh water consumption and environmental degradation was investigated. In this work, the removal of copper (Cu2+) and nickel (Ni+) ions from synthetic water was studied on pilot scale remove by before using two commercial nanofiltration (NF) and reverse osmosis(RO) spiral-wound membrane modules (NE2521-90 and RE2521-FEN by Toray Chemical). The influence of main operating parameters such as feed concentration on the heavy metals rejection and permeate flux of both membranes, was investigated. Synthetic plating wastewater samples containing copper ($Cu^{2+}$) and nickel ($Ni^{2+}$) ions at various concentrations(1, 20, 100, 400 mg/L) were prepared and subjected to treatment by NF and RO in the pilot plant. The results showed that NF, RO process, with 98% and 99% removal for copper and nickel, respectively, could achieve high removal efficiency of the heavy metals.

키워드

과제정보

연구 과제번호 : Technologies for the Risk Assessment & Management Program

연구 과제 주관 기관 : Korea Ministry of the Environment (MOE)

참고문헌

  1. Agridiotis, V., Forster, C.F. and Carliell-Marquet, C. (2007), "Addition of Al and Fe salts during treatment of paper mill effluents to improve activated sludge settlement characteristics", Bioresour. Technol., 98(15), 2926-2934. https://doi.org/10.1016/j.biortech.2006.10.004
  2. Ahn, K.H., Song, K.G., Cha, H.Y. and Yeom, I.T. (1999), "Removal of ions in nickel electroplating rinse water using lowpressure nanofiltration", Desalination, 122(1), 77-84. https://doi.org/10.1016/S0011-9164(99)00029-6
  3. Akbal, F. and Camci, S. (2011), "Copper, chromium and nickel removal from metal plating wastewater by electrocoagulation", Desalination, 269(1-3), 214-222. https://doi.org/10.1016/j.desal.2010.11.001
  4. Al-Rashdi, B., Somerfield, C. and Hilal, N. (2011), "Heavy metals removal using adsorption and nanofiltration techniques", Separation Purification Rev., 40(3), 209-259. https://doi.org/10.1080/15422119.2011.558165
  5. Bes-Pia, A., Mendoza-Roca, J.A., Alcaina-Miranda, M.I., Iborra-Clar, A. and Iborra-Clar, M.I. (2003), "Combination of physicochemical treatment and nanofiltration to reuse wastewater of a printing, dyeing and finishing textile industry", Desalination, 157(1-3), 73-80. https://doi.org/10.1016/S0011-9164(03)00385-0
  6. Chaabane, T., Taha, S., Ahmed, M.T., Maachi, R. and Dorange, G. (2006), "Removal of copper from industrial effluent using a spiral wound module-Film theory and hydrodynamic approach", Desalination, 200(1-3), 403-405. https://doi.org/10.1016/j.desal.2006.03.348
  7. Ciardelli, G., Corsi, L. and Marcucci, M. (2001), "Membrane separation for wastewater reuse in the textile industry", Resour., Conserv. Recycling, 31(2), 189-197. https://doi.org/10.1016/S0921-3449(00)00079-3
  8. Gherasim, C.V. and Mikulasek, P. (2014), "Influence of operating variables on the removal of heavy metal ions from aqueous solutions by nanofiltration", Desalination, 343, 67-74. https://doi.org/10.1016/j.desal.2013.11.012
  9. Gozalvez-Zafrilla, J.M., Sanz-Escribano, D., Lora-Garcia, J. and Hidalgo, M.L. (2008), "Nanofiltration of secondary effluent for wastewater reuse in the textile industry", Desalination, 222(1-3), 272-279. https://doi.org/10.1016/j.desal.2007.01.173
  10. Kotrappanavar, N.S., Hussain, A.A., Abashar, M.E.E., Al-Mutaz, I.S., Aminabhavi, T.M. and Nadagouda, M.N. (2011), "Prediction of physical properties of nanofiltration membranes for neutral and charged solutes", Desalination, 280(1-3), 174-182. https://doi.org/10.1016/j.desal.2011.07.007
  11. Lin, Y.L., Chiang, P.C. and Chang, E.E. (2007), "Removal of small trihalomethane precursors from aqueous solution by nanofiltration", J. Hazardous Mater., 146(1-2), 20-29. https://doi.org/10.1016/j.jhazmat.2006.11.050
  12. Mohammad, A.W., Othaman, R. and Hilal, N. (2004), "Potential use of nanofiltration membranes in treatment of industrial wastewater from Ni-P electroless plating", Desalination, 168, 241-252. https://doi.org/10.1016/j.desal.2004.07.004
  13. Murthy, Z.V.P. and Chaudhari, L.B. (2008), "Application of nanofiltration for the rejection of nickel ions from aqueous solutions and estimation of membrane transport parameters", J. Hazardous Mater., 160(1), 70-77. https://doi.org/10.1016/j.jhazmat.2008.02.085
  14. Nam, A., Kweon, J., Ryu, J., Lade, H. and Lee, C. (2015), "Reduction of biofouling using vanillin as a quorum sensing inhibitory agent in membrane bioreactors for wastewater treatment", Membr. Water Treat., 6(3), 189-203. https://doi.org/10.12989/mwt.2015.6.3.189
  15. Rozzi, A., Antonelli, M. and Arcari, M. (1999), "Membrane treatment of secondary textile effluents for direct reuse", Water Sci. Technol., 40(4-5), 409-416. https://doi.org/10.2166/wst.1999.0617
  16. Saffaj, N., Loukili, H., Younssi, S.A., Albizane, A., Bouhria, M., Persin, M. and Larbot, A. (2004), "Filtration of solution containing heavy metals and dyes by means of ultrafiltration membranes deposited on support made of Moroccan clay", Desalination, 168, 301-306. https://doi.org/10.1016/j.desal.2004.07.013
  17. Song, W., Lade, H., Yu, Y. and Kweon, J. (2018). "Effects of Nacetylcysteine on biofilm formation by MBR sludge", Membr. Water. Treat., 9(3), 195-203. https://doi.org/10.12989/MWT.2018.9.3.195
  18. Tanninen, J., Manttari, M. and Nystrom, M. (2006), "Nanofiltration of concentrated acidic copper sulphate solutions", Desalination, 189(1-3), 92-96. https://doi.org/10.1016/j.desal.2005.06.017
  19. Tchobanoglous, G., Burton, F.L. and Stensel, H.D. (2003), Wastewater engineering treatment and reuse (No. 628.3 T252s), McGraw-Hill Higher Education, Boston, U.S.A.
  20. Ujang, Z. and Anderson, G.K. (1996), "Application of lowpressure reverse osmosis membrane for Zn2+ and Cu2+ removal from wastewater", Water Sci. Technol., 34(9), 247-253. https://doi.org/10.2166/wst.1996.0223
  21. Wang, Z., Liu, G., Fan, Z., Yang, X., Wang, J. and Wang, S. (2007), "Experimental study on treatment of electroplating wastewater by nanofiltration", J. Membr. Sci., 305(1-2), 185-195. https://doi.org/10.1016/j.memsci.2007.08.011