Nuclear Engineering and Technology

Korean Nuclear Society (한국원자력학회)
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Influences of heating processes on properties and microstructure of porous CeO2 beads as a surrogate for nuclear fuels fabricated by a microfluidic sol-gel process

  • Song, Tong (School of Nuclear Science and Technology, University of Science and Technology of China) ;
  • Guo, Lin (School of Nuclear Science and Technology, University of Science and Technology of China) ;
  • Chen, Ming (School of Nuclear Science and Technology, University of Science and Technology of China) ;
  • Chang, Zhen-Qi (School of Nuclear Science and Technology, University of Science and Technology of China)
  • Received : 2017.12.02
  • Accepted : 2018.09.28
  • Published : 2019.02.25
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Abstract

The control of microstructure is critical for the porous fuel particles used for infiltrating actinide nuclides. This study concerns the effect of heating processes on properties and microstructure of the fuel particles. The uniform gel precursor beads were synthesized by a microfluidic sol-gel process and then the porous $CeO_2$ microspheres, as a surrogate for the ceramic nuclear fuel particles, were obtained by heating treatment of the gel precursors. The fabricated $CeO_2$ microspheres have a narrow size distribution and good sphericity due to the feature of microfluidics. The effects of heating processes parameters, such as heating mode and peak temperatures on the properties of microspheres were studied in detail. An optimized heating mode and the peak temperature of $650^{\circ}C$ were selected to produce porous $CeO_2$ microspheres. The optimized heating mode can avoid the appearance of broken or crack microspheres in the heating process, and as-prepared porous microspheres were of suitable pore size distribution and pore volume for loading minor actinide (MA) solution by an infiltration method that is used for fabrication of MA-bearing nuclear fuel beads. After the infiltration process, $1000^{\circ}C$ was selected as the final temperature to improve the compressive strength of microspheres.

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References

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