Membrane and Water Treatment

  • 제10권2호
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  • Pages.113-120
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  • 2019
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  • 2005-8624(pISSN)
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  • 2092-7037(eISSN)
테크노프레스 (Techno-Press)
권호 표지
DOI QR코드

DOI QR Code

Surface properties and interception behaviors of GO-TiO2 modified PVDF hollow fiber membrane

  • Li, Dongmei (Faculty of Civil and Transportation Engineering, Guangdong University of Technology) ;
  • Liang, Jinling (Faculty of Civil and Transportation Engineering, Guangdong University of Technology) ;
  • Huang, Mingzhu (Foshan Water Affairs Group Co. Ltd.) ;
  • Huang, Jun (Faculty of Civil and Transportation Engineering, Guangdong University of Technology) ;
  • Feng, Li (Faculty of Civil and Transportation Engineering, Guangdong University of Technology) ;
  • Li, Shaoxiu (Faculty of Civil and Transportation Engineering, Guangdong University of Technology) ;
  • Zhan, Yongshi (The Affiliated High School of South China Normal University)
  • 투고 : 2018.02.05
  • 심사 : 2018.10.11
  • 발행 : 2019.03.25
⟨ 이전 논문 다음 논문 ⟩

초록

To investigate surface properties and interception performances of the new modified PVDF membrane coated with Graphene Oxide (GO) and nano-$TiO_2$ (for short the modified membrane) via the interface polymerization method combined with the pumping suction filtration way, filtration experiments of the modified membrane on Humic Acid (HA) were conducted. Results showed that the contact angle (characterizing the hydrophilicity) of the modified membrane decreased from $80.6{\pm}1.8^{\circ}$ to $38.6{\pm}1.2^{\circ}$. The F element of PVDF membrane surface decreased from 60.91% to 17.79% after covered with GO and $TiO_2$. O/C element mass ratio has a fivefold increase, the percentage of O element on the modified membrane surface increased from 3.83 wt% to 20.87%. The modified membrane surface was packed with hydrophilic polar groups (like -COOH, -OH, C-O, C=O, N-H) and a functional hydrophilic GO-polyamide-$TiO_2$ composite configuration. This configuration provided a rigid network structure for the firm attachment of GO and $TiO_2$ on the surface of the membrane and for a higher flux as well. The total flux attenuation rate of the modified membrane decreased to 35.6% while 51.2% for the original one. The irreversible attenuation rate has dropped 71%. The static interception amount of HA on the modified membrane was $158.6mg/m^2$, a half of that of the original one ($295.0mg/m^2$). The flux recovery rate was increased by 50%. The interception rate of the modified membrane on HA increased by 12% approximately and its filtration cycle was 2-3 times of that of the original membrane.

키워드

과제정보

연구 과제 주관 기관 : National Natural Science Foundation of China

참고문헌

  1. Aryanti, P.T.P., Yustiana, R., Purnama, R.E.D. and Wenten, I.G. (2015), "Performance and characterization of PEG400 modified PVC ultrafiltration membrane", Membr. Water Treat., 6(5), 379-392. https://doi.org/10.12989/mwt.2015.6.5.379
  2. Chen, C. (2016), "The preparation of high performance of polyvinylidene fluoride ultrafiltration membrane", New Chem. Mater., 44(9), 70-71.
  3. Choi, W., Choi, J., Bang, J. and Lee, J. (2013), "Layer-by-layer assembly of graphene oxide nanosheets on polyamide membranes for durable reverse-osmosis applications", ACS Appl. Mater. Interfaces, 5(23), 12510-12519. https://doi.org/10.1021/am403790s
  4. Du, J.R., Peldszus, S., Huck, P.M. and Feng, X.S. (2009), "Modification of poly(vinylidene fluoride) ultrafiltration membranes with poly(vinyl alcohol) for fouling control in drinking water treatment", Water Res., 43(18), 4559-4568. https://doi.org/10.1016/j.watres.2009.08.008
  5. Loo, S.L., Fane, A.G., Krantz, W.B. and Lim, T.T. (2012), "Emergency water supply: A review of potential technologies and selection criteria", Water Res., 46(10), 3125-3151. https://doi.org/10.1016/j.watres.2012.03.030
  6. Pan, L., Zhu, X., Xie, X. and Liu, Y. (2015), "Smart hybridization of $TiO_2$ nanorods and Fe3O4 nanoparticles with pristine graphene nanosheets: Hierarchically nanoengineered ternary heterostructures for high-rate lithium storage", Adv. Funct. Mater., 25(22), 3341-3350. https://doi.org/10.1002/adfm.201404348
  7. Pan, L., Liu, Y., Xie, X., Ye, X. and Zhu, X. (2016), "Multidimensionally ordered, multi-functionally integrated r-$GO@TiO_2(b)@Mn_3O_4$ yolk-membrane-shell superstructures for ultrafast lithium storage", Nano Res., 9(7), 2057-2069. https://doi.org/10.1007/s12274-016-1096-8
  8. Pan, L., Zhou, Z.W., Liu, Y.T. and Xie, X.M. (2018), "A universal strategy for the in-situ synthesis of $TiO_2$(B) nanosheets on pristine carbon materials for high-rate lithium storage", J. Mater. Chem. A., 6(16), 7070-7079. https://doi.org/10.1039/C8TA01499J
  9. Sarihan, A. and Eren, E. (2017), "Novel high performanced and fouling resistant PSf/ZnO membranes for water treatment", Membr. Water Treat., 8(6), 563-574. https://doi.org/10.12989/MWT.2017.8.6.563
  10. Sathish, K.R., Arthanareeswaran, G., Paul, D. and Kweon, J.H. (2015), "Modification methods of polyethersulfone membranes for minimizing fouling: Review", Membr. Water Treat., 6(4), 323-337. https://doi.org/10.12989/mwt.2015.6.4.323
  11. Shawky, H.A., Chae, S.R., Lin, S. and Wiesner, M.R. (2011), "Synthesis and characterization of a carbon nanotube/polymer nanocomposite membrane for water treatment", Desalination, 272(1-3), 46-50. https://doi.org/10.1016/j.desal.2010.12.051
  12. Subasi, Y. and Cicek, B. (2017), "Recent advances in hydrophilic modification of PVDF ultrafiltration membranes: A review: Part II", Membr. Technol., 2017(11), 5-11. https://doi.org/10.1016/S0958-2118(17)30233-1
  13. Tarboush, B.J.A., Rana, D., Matsuura, T., Arafat, H.A. and Narbaitz, R.M. (2008), "Preparation of thin-film-composite polyamide membranes for desalination using novel hydrophilic surface modifying macromolecules", J. Membr. Sci, 325(1), 166-175. https://doi.org/10.1016/j.memsci.2008.07.037
  14. Tavakolmoghadam, M., Mohammadi, T. and Hemmati, M. (2016), "Preparation and characterization of PVDF/$TiO_2$ composite ultrafiltration membranes using mixed solvents", Membr. Water Treat., 7(5), 377-401. https://doi.org/10.12989/mwt.2016.7.5.377
  15. Wang, D.S., Zhao, Y.M., Xie, J.K., Chow, C.W.K. and Leeuwen, J.V. (2013), "Characterizing DOM and removal by enhanced coagulation: a survey with typical Chinese source waters", Sep. Purif. Technol., 110, 188-195. https://doi.org/10.1016/j.seppur.2013.03.020
  16. Wang, X.P., Liu, Z.M., Ye, X.P., Hu, K., Zhong, H.Q., Yuan, X.C., Xiong, H.L. and Guo, Z.Y. (2015), "A facile one-pot method to two kinds of graphene oxide-based hydrogels with broadspectrum antimicrobial properties", Chem. Eng. J., 260, 331-337. https://doi.org/10.1016/j.cej.2014.08.102
  17. Wu, J., Tang, Q., Sun, H., Lin, J., Ao, H., Huang, M. and Huang, Y. (2008), "Conducting film from graphite oxide nanoplatelets and poly(acrylic acid) by layer-by-layer self-assembly", Langmuir, 24(9), 4800-4805. https://doi.org/10.1021/la800095z
  18. You, Y.T., Wang, Y. and Zhang, X. (2012), "Synthesis and properties of $TiO_2$/PVDF hybrid membrane", Chin. J. Mater Res., 26(3), 247-254.
  19. Zaaba, N.I., Foo, K.L., Hashim, U., Tan, S.J., Liu, W.W. and Voon, C.H. (2017), "Synthesis of graphene oxide using modified hummers method: Solvent influence", Procedia Eng., 184, 469-477. https://doi.org/10.1016/j.proeng.2017.04.118
  20. Zheng, X., Xu, Q., He, L., Yu, N., Wang, S., Chen, Z. and Fu, J. (2011), "Modification of graphene oxide with amphiphilic double-crystalline block copolymer polyethylene-bpoly(ethylene oxide) with assistance of supercritical $CO_2$ and its further functionalization", J. Phys. Chem. B, 115(19), 5815-5826. https://doi.org/10.1021/jp2018082