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세라믹-세라믹 컴포넌트 접합용 글라스 실란트의 제조 및 접합력 평가

Fabrication and Adhesion Strength Evaluation of Glass Sealants for Ceramic to Ceramic Component Joining

  • 허유진 (한국세라믹기술원 나노소재.공정센터) ;
  • 김효태 (한국세라믹기술원 나노소재.공정센터)
  • Heo, Yu Jin (Nanomaterials and Nanotechnology Center Korea Institute of Ceramic Engineering and Technology) ;
  • Kim, Hyo Tae (Nanomaterials and Nanotechnology Center Korea Institute of Ceramic Engineering and Technology)
  • 투고 : 2019.12.02
  • 심사 : 2019.12.28
  • 발행 : 2019.12.30

초록

전력저장용 전기에너지 저장장치의 일종인 NaS 전지 단위 셀을 개발함에 있어서 알파-알루미나 절연세라믹 캡과 베타-알루미나 전해질 튜브 간의 세라믹-세라믹 상호 접합을 위하여 글라스 기반의 실링소재가 필요하다. 본고에서는 이 세라믹-세라믹 접합용 글라스 실링 페이스트를 제조함에 있어서, 열간 칭법에 의한 글라스 프릿 제조와 상분석, 분말입도 분석 및 글라스 조성에 따른 열팽창계수 변화 및 표면거칠기를 분석하였다. 또한 글라스 실란트의 접합력 평가를 위해 종래 솔더 볼 조인트의 접합력 평가용 분석장비인 Dage bond tester를 이용하여 세라믹-세라믹 컴포넌트의 작은 접합면에 대한 접합력 측정 방법을 제안하였다.

Glass base sealant is required as a ceramic-ceramic joining material between α-alumina insulation cap and β-alumina electrolyte tube in the development of NaS battery cell package for electrical energy storage system. The fabrication of glass frit by thermal quenching method, phase analysis, particle size analysis, coefficient of thermal expansion and surface roughness according to the glass compositions were analyzed for the fabrication of glass sealing paste for ceramic-ceramic joining. Also, a new evaluation method of the adhesion strength of glass sealant at the small area in ceramic-ceramic joining component was proposed using conventional Dage bond tester that was used to measure the adhesion of solder ball joint.

키워드

참고문헌

  1. Y. T. Kim, "Battery Technology for Clean Energy Policy of Korea", Asia Clean Energy Forum 2018 (2018).
  2. NGK Insulators Inc., "NAS ENERGY STORAGE SYSTEM: Sodium Sulfur Battery", (2019) from www.ngk.co.jp/nas.
  3. Z. Wen, J. Cao, Z. Gu, X. Xu, F. Zhang, and Z. Lin, "Research on Sodium Sulfur Battery for Energy Storage", Solid State Ion., 179, 1697 (2008). https://doi.org/10.1016/j.ssi.2008.01.070
  4. J. L. Sullivan, and L. Gaines, "A Review of Battery Life-Cycle Analysis: State of Knowledge and Critical Needs", by Center for Transportation Research Energy Systems Division, Argonne National Laboratory, ANL/ESD/10-7 (2010).
  5. S. H. Kee, Z. F. Xu, J. P. Jung, and W. J. Kim, "Joining of Ceramic and Metal using Active Metal Brazing", J. Microelectron. Packag. Soc., 18(3), 1 (2011). https://doi.org/10.6117/KMEPS.2011.18.3.001
  6. S. Song, Z. Wen, Q. Zhang, and Y. Liu, "A Novel Bi-doped Borosilicate Glass as Sealant for Sodium Sulfur Battery. Part 1. Thermophysical Characteristics and Structure", J. Power Sources, 195, 384 (2010). https://doi.org/10.1016/j.jpowsour.2009.06.041
  7. G. Zhang, Z. Wen, X. Wu, and G. Ma, "Improvement of Sealing Performance for NaS Battery by Surface Modification Process", Solid State Ionics: Ionics for Sustainable World, 152, (2013).
  8. P. Prigent, M. L. Boucheto, and J. Poirier, "Andalucite: An Amazing Refractory Raw Materials with Excellent Ccorrosion Resistance to Sodium Vapors", Ceram. Int., 37, 2287 (2011). https://doi.org/10.1016/j.ceramint.2011.03.024
  9. L. C. Klein, and C. J. Brinker, "Behavior of Silicate and Borosilicate Glasses in Contact with Metallic Sodium. II. Borosilicate Glasses", Phys. Chem. Glasses, 22, 22 (1981).
  10. Y. B. Son, S. W. Kim, and M. H. Kim, "Study on Filler Effects of High temperature Glass Sealant", J. Microelectron. Packag. Soc., 6(1), 51 (1999).
  11. J. Konig, R. R. Petersen, and Y. Yue, "Influence of the Glass Particle Size on the Foaming Process and Physical Characteristics of Foam Glasses", J. Non-cryst. Solids., 447, 190 (2016). https://doi.org/10.1016/j.jnoncrysol.2016.05.021
  12. C. H. Kim, Y. J. Heo, and H. T. Kim, "Porosity control of the sealing glass for joining alumina components in a NaS battery cell packaging", J. Microelectron. Packag. Soc., 23(4), 57 (2016). https://doi.org/10.6117/kmeps.2016.23.4.057
  13. A. Selcuk, and A. Atkinson, "Measurement of Mechanical Strength of Glass-to-Metal Joints", Fuel Cells, 15(4), 595 (2015). https://doi.org/10.1002/fuce.201500028
  14. Schott AG, "Sodium resistant sealing glasses", from www.schott.com/epackaging
  15. S. Song, Z. Wen, and Y. Liu, "Development and characterization of $Bi_2O_3$-containing glass-ceramic sealants for sodium sulfur battery", J. Non-cryst. Solids., 375, 25 (2013). https://doi.org/10.1016/j.jnoncrysol.2013.05.010
  16. Accuratus, "Aluminum Oxide, $Al_2O_3$ Ceramic Properties", (2013) from https://accuratus.com/alumox.html
  17. J. Garche, C. K. Dyer, P. T. Moseley, Z. Ogumi, D. A. J. Rand, and B. Scrosati, "Encyclopedia of Electrochemical Power Sources", Eds., pp.202, Newnes, Elsevier, Amsterdam (2013).