농업과학연구 (Korean Journal of Agricultural Science)

  • 제46권4호
  • /
  • Pages.941-953
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  • 2019
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  • 2466-2402(pISSN)
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  • 2466-2410(eISSN)
충남대학교 농업과학연구소 (Institute of Agricultural Science, CNU)
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Fuel properties of biodiesel produced from beef-tallow and corn oil blends based on the variation in the fatty acid methyl ester composition

  • Woo, Duk Gam (Research Faculty of Agriculture, Hokkaido University) ;
  • Kim, Tae Han (Dept. of Bio-industrial Machinery Engineering, Kyungpook National University)
  • 투고 : 2019.08.27
  • 심사 : 2019.11.01
  • 발행 : 2019.12.31
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초록

Biodiesels are being explored as a clean energy alternative to regular diesel, which causes pollution. In this study, the optimum conditions for producing biodiesel (BD) by combining beef tallow, an animal waste resource with a high saturated fatty acid content, and corn oil, a vegetable oil with a high unsaturated fatty acid content, were investigated, and the fuel properties were analyzed. Furthermore, Multivariate Analysis of Variance (MANOVA) was used to verify the optimum conditions for producing biodiesel. The influences of control factors, such as the oil blend ratio and methanol to oil molar ratio, on the fatty acid methyl ester and biodiesel production yield were investigated. As a result, the optimum condition for producing blended biodiesel was verified to be tallow to corn oil blend ratio of 7 : 3 (TACO7) and a methanol to oil molar ratio of 14 : 1. Moreover, the interaction between the oil blend ratio and the methanol to oil molar ratio has the most crucial effects on the production of oil blended biodiesel. In conclusion, the analysis results of the fuel properties of TACO7 BD satisfied the BD quality standard, and thus, the viability of BD blended with waste tallow as fuel was verified.

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참고문헌

  1. Adewale P, Dumont MJ, Ngadi M. 2015. Recent trends of biodiesel production from animal fat wastes and associated production techniques. Renewable and Sustainable Energy Reviews 45:574-588. https://doi.org/10.1016/j.rser.2015.02.039
  2. Akhihiero ET, Oghenejoboh KM, Umukoro PO. 2013. Effects of process variables on transesterification reaction of jatropha curcas seed oil for the production of biodiesel. International Journal of Emerging Technology and Advanced Engineering 2013:388-393.
  3. Albuquerque MCG, Machado YL, Torres AEB, Azevedo DCS, Cavalcante CL, Firmiano LR, Parente Jr. EJS. 2009. Properties of biodiesel oils formulated using different biomass sources and their blends. Renewable Energy 34:857-859. https://doi.org/10.1016/j.renene.2008.07.006
  4. Alcantara R, Amores J, Canoira L, Fidalgo E, Franco MJ, Navarro A. 2000. Catalytic production of biodiesel from soy-bean oil, used frying oil and tallow. Biomass and Bioenergy 18:515-527. https://doi.org/10.1016/S0961-9534(00)00014-3
  5. Al-Hamamre Z, Foerster S, Hartmann F, Kröger M, Kaltschmitt M. 2012. Oil extracted from spent coffee grounds as a renewable source for fatty acid methyl ester manufacturing. Fuel 96:70-76. https://doi.org/10.1016/j.fuel.2012.01.023
  6. Atabani AE, Silitonga AS, Ong HC, Mahlia TMI, Masjuki HH, Badruddin IA, Fayaz H. 2013. Non-edible vegetable oils: A critical evaluation of oil extraction, fatty acid compositions, biodiesel production, characteristics, engine performance and emissions production. Renewable and Sustainable Energy Reviews 18:211-245. https://doi.org/10.1016/j.rser.2012.10.013
  7. Aydin F, Kafadar AB, Erdogan S, Saydut A, Kaya C, Hamamci C. 2011. Basic properties of transesterified corn oil and biodiesel-diesel blends. Energy Source Part A 33:745-751. https://doi.org/10.1080/15567030903261824
  8. Bankovic-Ilic IB, Stojkovic IJ, Stamenkovic OS, Veljkovic VB, Hung YT. 2014. Waste animal fats as feedstocks for biodiesel production. Renewable and Sustainable Energy Reviews 32:238-254. https://doi.org/10.1016/j.rser.2014.01.038
  9. Bi Y, Ding D, Wang D. 2010. Low-melting-point biodiesel derived from corn oil via urea complexation. Bioresource Technology 101:1220-1226. https://doi.org/10.1016/j.biortech.2009.09.036
  10. Boshui C, Yuqiu S, Jianhua F, Jiu W, Jiang W. 2010. Effect of cold flow improvers on flow properties of soybean biodiesel. Biomass Bioenergy 34:1309-1313. https://doi.org/10.1016/j.biombioe.2010.04.001
  11. Cunha ME, Krause LC, Moraes MSA, Faccini CS, Jacques RA, Almeida SR, Rodrigues MRA, Caramao EB. 2009. Beef tallow biodiesel produced in a pilot scale. Fuel Processing Technology 90:570-575. https://doi.org/10.1016/j.fuproc.2009.01.001
  12. Demirbas A. 2005. Biodiesel production from vegetable oils via catalytic and non-catalytic supercritical methanol transesterification methods. Progress in Energy and Combustion Science 31:466-487. https://doi.org/10.1016/j.pecs.2005.09.001
  13. Demirbas A. 2008. New liquid biofuels from vegetable oils via catalytic pyrolysis. Energy, Education, Science and Technology 21:1-59.
  14. Demirbas A. 2009. Biodiesel from waste cooking oil via base-catalytic and supercritical methanol transesterification. Energy Conversion and Management 50:923-927. https://doi.org/10.1016/j.enconman.2008.12.023
  15. Dias JM, Alvim-Ferraz MCM, Almeida MF. 2008. Mixtures of vegetable oils and animal fat for biodiesel production: Influence on product composition and quality. Energy and Fuels 22:3889-3893. https://doi.org/10.1021/ef8005383
  16. Ding J, He B, Li J. 2011. Biodiesel production from acidified oils via supercritical methanol. Energies 4:2212-2223. https://doi.org/10.3390/en4122212
  17. Dorni C, Sharma P, Saikia G, Longvah T. 2018. Fatty acid profile of edible oils and fats consumed in India. Food Chemistry 238:9-15. https://doi.org/10.1016/j.foodchem.2017.05.072
  18. EIA (U.S. Energy Information Administration). 2019. Inputs to biodiesel production. Accessed in https://www.eia.gov/biofuels/biodiesel/production/ on 1 August 2019.
  19. Encinar JM, Gonzalez JF, Rodriguez JJ, Tajedor A. 2002. Biodiesels fuel from vegetable oils: Transesterification of Cynara cardunculus L. oils with ethanol. Energy and Fuels 16:443-450. https://doi.org/10.1021/ef010174h
  20. Fadhil AB. 2013. Biodiesel production from beef tallow using alkali-catalyzed transesterification. Arabian Journal for Science and Engineering 38:41-47. https://doi.org/10.1007/s13369-012-0418-8
  21. Freedman B, Pryde EH, Mounts TL. 1984.Variables affecting the yields of fatty esters from transesterified vegetable oils. Journal of the American Oil Chemists' Society 61:1638-1643. https://doi.org/10.1007/BF02541649
  22. Ghayal D, Pandit AB, Rathod VK. 2013. Optimization of biodiesel production in a hydrodynamic cavitation reactor using used frying oil. Ultrasonics Sonochemistry 20:322-328. https://doi.org/10.1016/j.ultsonch.2012.07.009
  23. Giakoumis EG, Sarakatsanis CK. 2018. Estimation of biodiesel cetane number, density, kinematic viscosity and heating values from its fatty acid weight composition. Fuel 222:574-585. https://doi.org/10.1016/j.fuel.2018.02.187
  24. Gryglewicz S. 1999. Rapeseed oil methyl esters preparation using heterogeneous catalysts. Bioresource Technology 70:249-253. https://doi.org/10.1016/S0960-8524(99)00042-5
  25. Guan G, Kusakabe K, Sakurai N, Moriyama K. 2009. Transesterification of vegetable oil to biodiesel fuel using acid catalysts in the presence of dimethyl ether. Fuel 88:81-86. https://doi.org/10.1016/j.fuel.2008.07.021
  26. Gui MM, Lee KT, Bhatia S. 2008. Feasibility of edible oil vs. non-edible oil vs. waste edible oil as biodiesel feedstock. Energy 33:1646-1653. https://doi.org/10.1016/j.energy.2008.06.002
  27. Hanna MA, Ali Y, Cuppett SL, Zheng D. 1996. Crystallization characteristics of methyl tallowate and its blends with ethanol and diesel fuel. Journal of the American Oil Chemists' Society 93:759-763.
  28. Hoekman SK, Broch A, Robbins C, Ceniceros E, Natarajan M. 2012. Review of biodiesel composition, properties, and specifications. Renewable and Sustainable Energy Reviews 16:143-169. https://doi.org/10.1016/j.rser.2011.07.143
  29. Jeong GT, Park JH, Park SH, Park DH. 2008. Estimating and improving cold filter plugging points by blending biodiesels with different fatty acid contents. Biotechnology and Bioprocess Engineering 13:505-510. https://doi.org/10.1007/s12257-008-0144-y
  30. KCorbitz W. 1999. Biodiesel production in Europe and North American, an encouraging prospect. Renewable Energy 16:1078-1083. https://doi.org/10.1016/S0960-1481(98)00406-6
  31. Knothe G, Matheaus AC, Ryan III TW. 2003. Cetane numbers of branched and straight-chain fatty esters determined in an ignition quality tester. Fuel 82:971-975. https://doi.org/10.1016/S0016-2361(02)00382-4
  32. Lam MK, Lee KT, Mohamed AR. 2010. Homogeneous, heterogeneous and enzymatic catalysis for transesterification of high free fatty acid oil (waste cooking oil) to biodiesel: A review. Biotechnology Advances 28:500-518. https://doi.org/10.1016/j.biotechadv.2010.03.002
  33. Lapuerta M, Fernandez JR, Oliva F, Canoira L. 2009. Biodiesel from low-grade animal fats: Diesel engine performance and emissions. Energy and Fuels 23:121-129. https://doi.org/10.1021/ef800481q
  34. Leung DYC, Wu X, Leung MKH. 2010. A review on biodiesel production using catalyzed transesterification. Applied Energy 87:1083-1095. https://doi.org/10.1016/j.apenergy.2009.10.006
  35. Lin R, Zhu Y, Tavlarides LL. 2014. Effect of thermal decomposition on biodiesel viscosity and cold flow property. Fuel 17:981-988.
  36. Maddikeri GL, Pandit AB, Gogate PR. 2012. Intensification approaches for biodiesel synthesis from waste cooking oil: A review. Industrial and Engineering Chemistry Research 51:14610-14628. https://doi.org/10.1021/ie301675j
  37. Ma F, Clements LD, Hanna MA. 1998. The effect of catalyst, free fatty acids, and water on transesterification of beef tallow. Transactions of the American Society of Agricultural and Biological Engineers 41:1261-1264. https://doi.org/10.13031/2013.17292
  38. Ma F, Hanna MA. 1999. Biodiesel production: A review. Bioresource Technology 70:1-15. https://doi.org/10.1016/S0960-8524(99)00025-5
  39. Mata TM, Cardoso N, Ornelas M, Neves S, Caetano NS. 2010. Sustainable production of biodiesel from tallow, lard and poultry fat and its quality evaluation. Chemical Engineering Transactions 19:13-18.
  40. Mata TM, Cardoso N, Ornelas M, Neves S, Caetano NS. 2011. Evaluation of two purification methods of biodiesel from beef tallow, pork lard, and chicken fat. Energy and Fuels 25:4756-4762. https://doi.org/10.1021/ef2010207
  41. Meher LC, Sagar DV, Naik SN. 2006. Technical aspects of biodiesel production by transesterification-a review. Renewable and Sustainable Energy Reviews 10:248-268. https://doi.org/10.1016/j.rser.2004.09.002
  42. Mudge SM, Pereira G. 1999. Stimulating the biodegradation of crude oil with biodiesel preliminary results. Spill Science & Technology Bulletin 5:353-355. https://doi.org/10.1016/S1353-2561(99)00075-4
  43. Muniyappa PR, Brammer SC, Noureddini H. 1996. Improved conversion of plant oils and animal fats into biodiesel and co-product. Bioresource Technology 56:19-24. https://doi.org/10.1016/0960-8524(95)00178-6
  44. Oner C, Altun S. 2009. Biodiesel production from inedible animal tallow and an experimental investigation of its use as alternative fuel in a direct injection diesel engine. Applied Energy 86:2114-2120. https://doi.org/10.1016/j.apenergy.2009.01.005
  45. Park JY, Kim DK, Lee JP, Park SC, Kim YJ, Lee JS. 2008. Blending effects of biodiesels on oxidation stability and low temperature flow properties. Bioresource Technology 99:1196-1203. https://doi.org/10.1016/j.biortech.2007.02.017
  46. Patil PD, Deng S. 2009. Optimization of biodiesel production from edible and non-edible vegetable oils. Fuel 88:1302-1306. https://doi.org/10.1016/j.fuel.2009.01.016
  47. Pereiral GG, Garcia RKA, Ferreira LL, Arellano DB. 2017. Soybean and soybean/beef-tallow Biodiesel: A comparative study on oxidative degradation during long‑term storage. Journal of the American Oil Chemists' Society 94:587-593. https://doi.org/10.1007/s11746-017-2962-6
  48. Ramos MJ, Fernandez CM, Casas A, Rodriguez L, Perez A. 2009. Influence of fatty acid composition of raw materials on biodiesel properties. Bioresource Technology 100:261-268. https://doi.org/10.1016/j.biortech.2008.06.039
  49. Ryu KH, Oh YT. 2004. Combustion characteristics of an agricultural diesel engine using biodiesel fuel. Journal of Mechanical Science and Technology 18:709-717.
  50. Serqueira DS, Fernandes DM, Cunha RR, Squissato AL, Santos DQ, Richter EM, Munoz RAA. 2014. Influence of blending soybean, sunflower, colza, corn, cottonseed, and residual cooking oil methyl biodiesels on the oxidation stability. Fuel 118:16-20. https://doi.org/10.1016/j.fuel.2013.10.028
  51. Singh D, Ganesh A, Mahajani S. 2015. Heterogeneous catalysis for biodiesel synthesis and valorization of glycerol. Clean Technologies and Environmental Policy 17:1103-1110. https://doi.org/10.1007/s10098-014-0858-9
  52. Sousa VM, Luz SM, Caldeira-Pires A, Machado FS, Silveira CM. 2017. Life cycle assessment of biodiesel production from beef tallow in Brazil. International Journal of Life Cycle Assessment 22:1837-1850. https://doi.org/10.1007/s11367-017-1396-6
  53. Speidel HK, Lightner RL, Ahmed I. 2000. Biodegradability of new engineered fuels compared to conventional petroleum fuels and alternative fuels in current use. Applied Biochemistry and Biotechnology 84-86:879-897.
  54. Taravus S, Temur H, Yartasi A. 2009. Alkali-catalyzed biodiesel production from mixtures of sunflower oil and beef tallow. Energy and Fuels 23:4112-4115. https://doi.org/10.1021/ef900211n
  55. Teixeira LSG, Assis JCR, Mendonca DR. 2009. Comparison between conventional and ultrasonic preparation of beef tallow biodiesel. Fuel Processing Technology 90:1164-1166. https://doi.org/10.1016/j.fuproc.2009.05.008
  56. Teixeira LSG, Couto MB, Souza GS, Filho MA, Assis JCR, Guimaraes PRB, Pontes LAM, Almeida SQ, Teixeira JSR. 2010. Characterization of beef tallow biodiesel and their mixtures with soybean biodiesel and mineral diesel fuel. Biomass and Bioenergy 34:438-441. https://doi.org/10.1016/j.biombioe.2009.12.007
  57. Tomasevic AV, Marinkovic SS. 2003. Methanolysis of used frying oil. Fuel Processing Technology 81:1-6. https://doi.org/10.1016/S0378-3820(02)00096-6
  58. Tubino M, Junior JGR, Bauerfeldt GF. 2014. Biodiesel synthesis with alkaline catalysts: A new refractometric monitoring and kinetic study. Fuel 125:164-172. https://doi.org/10.1016/j.fuel.2014.01.096
  59. Wu X, Leung DYC. 2011. Optimization of biodiesel production from camelina oil using orthogonal experiment. Applied Energy 88:3615-3624. https://doi.org/10.1016/j.apenergy.2011.04.041
  60. Wyatt VT, Hess MA, Dunn RO, Foglia TA, Hass MJ, Marmer WN. 2005. Fuel properties and nitrogen oxide emission levels of biodiesel produced from animal fats. Journal of the American Oil Chemists' Society 82:585-591. https://doi.org/10.1007/s11746-005-1113-2
  61. Yasar F, Altun S, Adin H. 2011. Fuel properties of biodiesels produced from blends of canola oil and animal tallow. Energy Education Science and Technology Part A: Energy Science and Research 27:199-208.
  62. Zhang D. 1994. Crystallization characteristics and fuel properties of tallow methyl esters. Ph. D. dissertation, University of Nebraska-Lincoln, Nebraska, USA.
  63. Zullaikah S, Lai CC, Vali SR, Ju YH. 2005. A two-step acid-catalyzed process for the production of biodiesel from rice bran oil. Bioresource Technology 96:1889-1896. https://doi.org/10.1016/j.biortech.2005.01.028

피인용 문헌

  1. Performance characteristics of a single-cylinder power tiller engine with biodiesel produced from mixed waste cooking oil vol.47, pp.1, 2019, https://doi.org/10.7744/kjoas.20190085