Advances in environmental research

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Isotherm, kinetic and thermodynamic studies of dye removal from wastewater solution using leach waste materials

  • DEN, Muhammed Kamil O (Department of Environmental Protect Technology, University of Selcuk) ;
  • ONGAR, Sezen KUC UKC (Department of Environmental Engineering, Engineering and Natural Sciences Faculty, Konya Technical University)
  • Received : 2019.01.14
  • Accepted : 2019.06.07
  • Published : 2019.09.25
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Abstract

In this study, Malachite Green (MG) dye removal from synthetic wastewaters by adsorption process using raw boron enrichment waste (BEW) and it's modifications (with acid and ultrasound) were aimed. 81% MG removal was obtained by BEW at optimum equilibrium conditions (time: 40 min., dosage: 500 mg/dm3, pH: 5-6, speed: 200 rpm, 298 K). MG removal from wastewaters using acid modified boron enrichment waste (HBEW) was determined as 82% at optimum conditions (time: 20 min., dosage: 200 mg/dm3, pH: 10, speed: 200 rpm, 298 K). For ultrasound modified BEW (UBEW), the highest MG removal percent was achieved as 84% at optimum conditions (time: 30 min, dosage: 375 mg/ dm3, pH: 8, speed: 200 rpm, 298 K). The equilibrium data of Malachite Green was evaluated for BEW, HBEW and UBEW adsorbents by using sorption isotherms such as Langmuir, Freundlich and Temkin models, out of which Langmuir model (R2 = 0.971, 0.987 and 0.984) gave better correlation and maximum adsorption capacity was found to be 147.05, 434.78 and 192.30 mg/g, respectively. The adsorption kinetics followed the pseudo-second-order kinetic equation for sorption of MG onto wastes. A look at thermodynamic data reveals that natural sorption is spontaneous and endothermic because of free negative energy exchange and positive change in enthalpy, respectively. The results indicated that boron enrichment waste, and HCl and ultrasound-modified boron enrichment waste served as good alternative adsorbents in dye removal from wastewater.

Keywords

Acknowledgement

Supported by : Selcuk University

This study was supported by Selcuk University, coordinatorship of scientific research projects (BAP) with the Project no 13101005. Some parts of this research study were presented in different conferences and were located in congress materials as abstract or full text. We also thank the late Assoc. Prof. Dr. Celalettin OZDEMİR for his contribution and support.

References

  1. Abdel-Khalek, M.A., Abdel Rahman, M.K. and Francis, A.A. (2017), "Exploring the adsorption behavior of cationic and anionic dyes on industrial waste shells of egg", J. Environ. Chem. Eng., 5(1), 319-327. https://doi.org/10.1016/j.jece.2016.11.043.
  2. Abussaud, B., Asmaly, H.A., Saleh, T.A., Gupta, V.K. and Atieh, M.A. (2016), "Sorption of phenol from waters on activated carbon impregnated with iron oxide, aluminum oxide and titanium oxide", J. Mol. Liq., 213, 351-359. https://doi.org/10.1016/j.molliq.2015.08.044.
  3. Adamson, A.W. and Gast, A.P. (1997), Physical Chemistry of Surfaces, Wiley, New York, U.S.A.
  4. Ahmad, A.L., Harris, W.A. and Ooi, B.S. (2002), "Removal of dye from wastewater of textile industry using membrane technology", Jurnal Teknologi, 36(1), 31-44. https://doi.org/10.11113/jt.v36.581.
  5. Ahmad, R. and Kumar, R. (2010), "Adsorption studies of hazardous malachite green onto treated ginger waste", J. Environ. Manage., 91(4), 1032-1038. https://doi.org/10.1016/j.jenvman.2009.12.016.
  6. Ahmad, R. and Mondal, P.K. (2010), "Adsorption studies of hazardous malachite green onto treated ginger waste", Sep. Sci. Technol., 45(3), 394-403. https://doi.org/10.1016/j.jenvman.2009.12.016.
  7. Ali Khan, M., Khan, M. and Zafar, S. (2017), "Removal of different anionic dyes from aqueous solution by anion exchange membrane", Membr. Water Treat., 8(3), 259-277. https://doi.org/10.12989/mwt.2017.8.3.259.
  8. Alizadeh, R. and Zeidi, A. (2017), "Adsorption of methylene blue from an aqueous dyeing solution by use of santa barbara amorphous-15 nanostructure: Kinetic and isotherm studies", Adv. Environ. Res., 6(2), 113-125. https://doi.org/10.12989/aer.2017.6.2.113.
  9. Amarasinghe, B.M.W.P.K., Jayasinghe, P.A. and Gunesekara, M.Y. (2007), "Adsorption of cibacron blue dye from aqueous solutions onto HCL treated waste biomass", Eng. J. Inst. Eng., 40(3), 7-15.
  10. Bhatti, H.N., Jabeen, A., Iqbal, M., Noreen, S. and Naseem, Z. (2017), "Adsorptive behavior of rice bran-based composites for malachite green dye: Isotherm, kinetic and thermodynamic studies", J. Mol. Liq., 237, 322-333. https://doi.org/10.1016/j.molliq.2017.04.033.
  11. Bouaziz, F., Koubaa, M., Kallel, F., Ghorbel, R.E. and Chaabouni, S.E. (2017), "Adsorptive removal of malachite green from aqueous solutions by almond gum: Kinetic study and equilibrium isotherms", Int. J. Biol. Macromol., 105, 56-65. https://doi.org/10.1016/j.ijbiomac.2017.06.106.
  12. Buthelezi, S., Olaniran, A. and Pillay, B. (2012), "Textile dye removal from wastewater effluents using bioflocculants produced by indigenous bacterial isolates", Molecules, 17(12),14260. https://doi.org/10.3390/molecules171214260.
  13. Chiou, M.S., Ho, P.Y. and Li, H.Y. (2004), "Adsorption of anionic dyes in acid solutions using chemically cross-linked chitosan beads", Dyes Pigm., 60(1), 69-84. https://doi.org/10.1016/S0143-7208(03)00140-2.
  14. Caglar, E., Donar, Y.O., Sinag, A., Birogul, I., Bilge, S., Aydincak, K. and Pliekhov, O. (2018), "Adsorption of anionic and cationic dyes on biochars, produced by hydrothermal carbonization of waste biomass: Effect of su", Turk. J. Chem., 42(1), 86-99. https://doi.org/10.3906/kim-1704-12
  15. Ciftci, D.I. (2016), "Enhancement of Methylene Blue dye adsorption by Fe-Hydroxyapatite composite", Adv. Environ. Res., 5(4), 225-235. https://doi.org/10.12989/aer.2016.5.4.225.
  16. Ciftci, D.I. and Meric, S. (2016), "Optimization of methylene blue adsorption by pumice powder", Adv. Environ. Res., 5(1), 37-50. https://doi.org/10.12989/aer.2016.5.1.037.
  17. Dubinin, M.M. (1965), "Modern state of the theory of volume filling of micropore adsorbents during adsorption of gases and steams on carbon adsorbents", Zh. Fiz. Khim., 39(6), 1305-1317.
  18. Elsharkawy, R.G. (2017), "Incorporation of copper/melamine complexes in silica surface and their sorption activity of organic dye", Iran J. Chemistry Chem. Eng., 36(5), 99-114.
  19. El-Zahhar, A.A. and Awwad, N.S. (2016), "Removal of malachite green dye from aqueous solutions using organically modified hydroxyapatite", J. Environ. Chem. Eng., 4(1), 633-638. https://doi.org/10.1016/j.jece.2015.12.014.
  20. Evliyaogullari, N.E., Oden, M.K. and Kucukcongar, S. (2017), "The removal of chromium from aqueous solutions using an industrial waste material", Int. J. Ecosyst. Ecol. Sci., 7(4), 671-676.
  21. Foo, K.Y. and Hameed, B.H. (2010), "Insights into the modeling of adsorption isotherm systems", Chem. Eng. J., 156(1), 2-10. https://doi.org/10.1016/j.cej.2009.09.013.
  22. Freundlich, H.M.F. (1906), "Over the adsorption in solution", J. Phys. Chem., 57, 385-471.
  23. Gadekar, M.R. and Ahammed, M.M. (2016), "Coagulation/flocculation process for dye removal using water treatment residuals: Modelling through artificial neural networks", Desalin. Water Treat., 57(55), 26392-26400. https://doi.org/10.1080/19443994.2016.1165150.
  24. Ghaedi, M., Hajjati, S., Mahmudi, Z., Tyagi, I., Agarwal, S., Maity, A. and Gupta, V.K. (2015), "Modeling of competitive ultrasonic assisted removal of the dyes-Methylene blue and Safranin-O using Fe3O4 nanoparticles", Chem. Eng. J., 268, 28-37. https://doi.org/10.1016/j.cej.2014.12.090.
  25. Ghaedi, M., Shojaeipour, E., Ghaedi, A.M. and Sahraei, R. (2015), "Isotherm and kinetics study of malachite green adsorption onto copper nanowires loaded on activated carbon: Artificial neural network modeling and genetic algorithm optimization", Spectrochim. Acta Part A, 142, 135-149. https://doi.org/10.1016/j.saa.2015.01.086.
  26. Gupta, V.K., Jain, R., Nayak, A., Agarwal, S. and Shrivastava, M. (2011), "Removal of the hazardous dye-Tartrazine by photodegradation on titanium dioxide surface", Mater. Sci. Eng. C, 31(5), 1062-1067. https://doi.org/10.1016/j.msec.2011.03.006.
  27. Gupta, V.K., Pathania, D., Agarwal, S. and Sharma, S. (2012), "De-coloration of hazardous dye from water system using chemically modified Ficus carica adsorbent", J. Mol. Liq., 174, 86-94. https://doi.org/10.1016/j.molliq.2012.07.017.
  28. Indu, M., Gupta, A. and Sahoo, C. (2014), "Electrochemical oxidation of methylene blue using lead acid battery anode", APCBEE Procedia, 9, 70-74. https://doi.org/10.1016/j.apcbee.2014.01.013.
  29. Jirankova, H., Mrazek, J., Dolecek, P. and Cakl, J. (2010), "Organic dye removal by combined adsorption-membrane separation process", Desalin. Water Treat., 20(1-3), 96-101. https://doi.org/10.5004/dwt.2010.1170.
  30. Khattri, S.D. and Singh, M.K. (2009), "Removal of malachite green from dye wastewater using neem sawdust by adsorption", J. Hazard. Mater., 167(1), 1089-1094. https://doi.org/10.1016/j.jhazmat.2009.01.101.
  31. Kushwaha, A.K., Gupta, N. and Chattopadhyaya, M.C. (2014), "Removal of cationic methylene blue and malachite green dyes from aqueous solution by waste materials of Daucus carota", J. Saudi Chem. Soc., 18(3), 200-207. https://doi.org/10.1016/j.jscs.2011.06.011.
  32. Lafi, R., Mabrouk, W. and Hafiane, A. (2019), "Removal of Methylene blue from saline solutions by adsorption and electrodialysis", Membr. Water Treat., 10(2), 139-148. https://doi.org/10.12989/mwt.2019.10.2.139.
  33. Liu, N., Wang, H., Weng, C.H. and Hwang, C.C. (2018), "Adsorption characteristics of Direct Red 23 azo dye onto powdered tourmaline", Arab. J. Chem., 11(8), 1281-1291. https://doi.org/10.1016/j.arabjc.2016.04.010.
  34. Malek, A. and Farooq, S. (1996), "Comparison of isotherm models for hydrocarbon adsorption on activated carbon", AIChE J., 42(11), 3191-3201. https://doi.org/10.1002/aic.690421120.
  35. Mittal, A., Mittal, J., Malviya, A. and Gupta, V.K. (2010), "Removal and recovery of Chrysoidine Y from aqueous solutions by waste materials", J. Colloid Interface Sci., 344(2), 497-507. https://doi.org/10.1016/j.jcis.2010.01.007.
  36. Mohammadi, N., Khani, H., Gupta, V.K., Amereh E. and Agarwal, S. (2011), "Adsorption process of methyl orange dye onto mesoporous carbon material-kinetic and thermodynamic studies", J. Colloid Interface Sci., 362(2), 457-462. https://doi.org/10.1016/j.jcis.2011.06.067.
  37. Oden, M.K. and Kucukcongar, S. (2018), "Acid and ultrasound assisted modification of boron enrichment process waste and using for methylene blue removal from aqueous solutions", Global Nest J., 20(2), 234-242. https://doi.org/10.30955/gnj.002500
  38. Oden, M.K. and Sari-Erkan, H. (2018), "Treatment of metal plating wastewater using iron electrode by electrocoagulation process: Optimization and process performance", Process Saf. Environ. Protect., 119, 207-217. https://doi.org/10.1016/j.psep.2018.08.001.
  39. Oei, B.C., Ibrahim, S., Wang, S. and Ang, H.M. (2009), "Surfactant modified barley straw for removal of acid and reactive dyes from aqueous solution", Bioresour. Technol., 100(18), 4292-4295. https://doi.org/10.1016/j.biortech.2009.03.063.
  40. Ozdemir, C., Oden, M.K., Sahinkaya S. and Kalipci, E. (2011), "Color removal from synthetic textile wastewater by sono-fenton process", Clean-Soil Air Water, 39(1), 60-67. https://doi.org/10.1002/clen.201000263.
  41. Pandian, A.M.K., Karthikeyan, C. and Rajasimman, M. (2016), "Isotherm and kinetic studies on nanosorption of malachite green onto Aspergillus flavus mediated synthesis of silver nano particles", Environ. Nanotechnol. Monit. Manage., 6, 139-151. https://doi.org/10.1016/j.enmm.2016.10.001.
  42. Radushkevich, L.V. (1949), "Potential theory of sorption and structure of carbons", Zh. Fiz. Khim., 23, 1410-1420.
  43. Rizzi, V., D'Agostino, F., Fini, P., Semeraro, P. and Cosma, P.(2017), "An interesting environmental friendly cleanup: The excellent potential of olive pomace for disperse blue adsorption/desorption from wastewater", Dyes Pigm., 140, 480-490. https://doi.org/10.1016/j.dyepig.2017.01.069.
  44. Sartape, A. S., Mandhare, A.M., Jadhav, V.V., Raut, P.D., Anuse, M.A. and Kolekar, S.S. (2017), "Removal of malachite green dye from aqueous solution with adsorption technique using Limonia acidissima (wood apple) shell as low cost adsorbent", Arab. J. Chem., 10, S3229-S3238. https://doi.org/10.1016/j.arabjc.2013.12.019.
  45. Sharma, A., Verma, M. and Haritash, A.K. (2016), "Degradation of toxic azo dye (AO7) using Fenton's process", Adv. Environ. Res., 5(3), 189-200. http://dx.doi.org/10.12989/aer.2016.5.3.189.
  46. Tempkin, M.I. and Pyzhev, V. (1940), "Kinetics of ammonia synthesis on promoted iron catalyst", Acta Phys. Chim., 12, 327-356.
  47. Weber, W.J. and Morris, J.C. (1963), "Kinetics of adsorption on carbon from solution", J. Sanit. Eng. Div. Am. Soc. Civ. Eng., 89, 31-60. https://doi.org/10.1061/JSEDAI.0000430
  48. Wijetunga, S. and Gunasekara, C.D.F.A. (2017), "Evaluation of refused tea waste activated carbon for color removal: Equilibrium and kinetic studies", Adv. Environ. Res., 6(1),1-14. https://doi.org/10.12989/aer.2017.6.1.001.