Current Applied Physics

Korean Physical Society (한국물리학회)
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Carbon-silica composites supported Pt as catalyst for asymmetric hydrogenation of ethyl 2-oxo-4-phenylbutyrate

  • Mao, Cong (College of Chemical Engineering, Huaqiao University) ;
  • Zhang, Jie (College of Chemical Engineering, Huaqiao University) ;
  • Xiao, Meitian (College of Chemical Engineering, Huaqiao University) ;
  • Liu, Yongjun (College of Chemical Engineering, Huaqiao University) ;
  • Zhang, Xueqin (College of Chemical Engineering, Huaqiao University)
  • Received : 2018.04.23
  • Accepted : 2018.09.02
  • Published : 2018.12.31
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Abstract

Mesoporous carbon-silica composites supported Pt nanoparticle catalysts (Pt/MCS) were firstly applied to the heterogeneous asymmetric hydrogenation of ethyl 2-oxo-4-phenylbutyrate (EOPB). A series of different silica contents were investigated in the fabrication of this mesoporous material. When the volume of added tetraethyl orthosilicate (TEOS) during the preparation of composites is 8 mL, Pt/MCS-8 holds carbon and silica as the main components and possesses relatively strong acidity, mesoporous structures with micropores, appropriate Pt nanoparticle size and high dispersibility showing by XRD, XPS, TPD, $N_2$ sorption and TEM. These properties cause its good catalytic performance in the heterogeneous asymmetric hydrogenation of EOPB with the enantiomeric excess value and conversion up to 85.6% and 97.8%, respectively.

Keywords

Acknowledgement

Supported by : National Natural Science Foundation of China, Fujian Province, Huaqiao University

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