DOI QR코드

DOI QR Code

Adhesion between Surfaces Treated with Aramid Fiber and Silicone/Fluorine Rubber

아라미드 표면처리에 의한 실리콘/불소 고무와의 접착성 연구

  • Received : 2018.08.29
  • Accepted : 2018.10.18
  • Published : 2018.10.31

Abstract

The interfacial adhesion property between aramid and rubber is a very important factor when aramid is applied as a reinforcing material for automotive heat-resistant hoses. This study examined the improvement of interfacial adhesion between aramid and rubber by applying plasma and a coupling agent to m-aramid. The SEM, AFM, and XPS characteristics were examined based on the plasma treatment conditions. The plasmatreated aramid was then treated with the coupling agent to analyze the interfacial adhesion with silicon, fluorine, and hybrid rubber. The plasma treatment resulted in an increase in the surface roughness of the aramid, and the mechanical properties of the aramid fabric decreased because the surface of the aramid was fibrillated. Moreover, the interfacial adhesion between aramid and rubber increased by 16.2% with the use of the coupling agent and plasma treatment.

Keywords

References

  1. S. M. Park, I. J. Kwon, M. S. Kim, S. S. Kim, J. Y. Choi, and J. H. Yeum, “Surface Modification Effect and Mechanical Property of para-Aramid Fiber by Low-temperature Plasma Treatment”, Textile Coloration and Finishing, 2012, 24, 131-137. https://doi.org/10.5764/TCF.2012.24.2.131
  2. J. H. Sim, J. Y. Kim, T. K. Kim, and J. S. Bae, “Surface Modification Effect and Mechanical Property of Para-aramid Fiber by Low-temperature Plasma Treatment(2)”, Textile Coloration and Finishing, 2015, 27, 18-26. https://doi.org/10.5764/TCF.2015.27.1.18
  3. B. Park and K. Koo, “Properties of Silicone-coated Fabric for Membrane Treated by Oxygen Low Temperature Plasma”, Textile Coloration and Finishing, 2011, 23, 195-200. https://doi.org/10.5764/TCF.2011.23.3.195
  4. T. S. Lee, B. S. Kim, H. N. Choi, K. Y. Lee, and S. G. Lee, "Interfacial Adhesion Properties of Plasma Treated Aramid Fiber with Chloroprene Rubber", Text. Sci. Eng., 2010, 47, 205-211.
  5. Y. S. Lee, K. S. Hwang, J. C. Lee, T. G. Kim, and K. R. Ha, "Effect of TESPT Silane Coupling Agent on Mechanical Properties of Precipitated Silica Filled NBR Compound for Oil Seal", Elastomer. Compos., 2011, 46, 45-53.
  6. K. J. Kim and J. L. White, "TESPT and Different Aliphatic Silane Treated Silica Compounds Effects on Silica Agglomerate Dispersion and on Processability During Mixing in EPDM", J. Ind. Eng. Chem., 2001, 7, 50-57.
  7. L. A. E. M. Reuvekamp, J. W. ten Brinke, P. J. van Swaaij, and J. W. M. Noordermeer, "Effects of Time and Temperature on the Reaction of TESPT Silane Coupling Agent During Mixing with Silica Filler and Tire Rubber", Rubber Chem. Technol., 2002, 75, 178-198.
  8. H. Ismail, A. Rusli, and A. A. Rashid, "Maleated Natural Rubber as a Coupling Agent for Paper Sludge Filled Natural Rubber Composites", Polymer Testing, 24, 2005, 856-862. https://doi.org/10.1016/j.polymertesting.2005.06.011
  9. C. Jia, P. Chen, W. Liu, B. Li, and Q. Wang, "Surface Treatment of Aramid Fiber by Air Dielectric Barrier Discharge Plasma at Atmospheric Pressure", Appl. Surface Sci., 2011, 257, 4165-4170. https://doi.org/10.1016/j.apsusc.2010.11.190
  10. E. P. Plueddemann, "Chemistry of Silane Coupling Agents", Springer, Boston, MA, 1991.
  11. J. P. Matinlinna, C. Y. K. Lung, and J. K. H. Tsoi, “Silane Adhesion Mechanism in Dental Applications and Surface Treatments: A Review”, Dental Materials, 2018, 34, 13-28. https://doi.org/10.1016/j.dental.2017.09.002
  12. Z. Peng, Y. Yang, J. Luo, C. Nie, L. Ma, C. Cheng, and C. Zhao, "Nanofibrous Polymeric Beads from Aramid Fibers for Efficient Bilirubin Removal", Biomater. Sci., 2016, 4, 1392-1401. https://doi.org/10.1039/C6BM00328A
  13. J. R. Brown and Z. Mathys, "Plasma Surface Modification of Advanced Organic Fibres: Part V. Effects on the Mechanical Properties of Aramid/phenolic Composites", J. Mater. Sci., 1997, 32, 2599-2604. https://doi.org/10.1023/A:1018654501851
  14. M. V. de Souza, S. N. Monteiro, and J. R. M. d'Almeida, "Effect of the Shear and Coupling Elements of the Aij and Dij Matrices on the Impact Behavior of Glass, Aramid and Hybrid Fabric Composites", Compos. Struct., 2006, 76, 345-351. https://doi.org/10.1016/j.compstruct.2005.05.006
  15. R. J. M. Borggreve and R. J. Gaymans, "Impact Behaviour of Nylon-rubber Blends: 4. Effect of the Coupling Agent, Maleic Anhydride", Polymer, 1989, 30, 63-77. https://doi.org/10.1016/0032-3861(89)90384-4