Korean Chemical Engineering Research

The Korean Institute of Chemical Engineers (한국화학공학회)
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Phase Equilibrium of Binary Mixture for the (Carbon Dioxide + 1-Phenyl-2-Pyrrolidone) System at High Pressure

  • Lee, Ho (Department of Chemical and Biomolecular Engineering, Chonnam National University) ;
  • Jeong, Jong-Dae (Department of Chemical and Biomolecular Engineering, Chonnam National University) ;
  • Byun, Hun-Soo (Department of Chemical and Biomolecular Engineering, Chonnam National University)
  • Received : 2018.08.13
  • Accepted : 2018.09.07
  • Published : 2018.10.01
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Abstract

Experimental data of phase equilibria are reported for the binary mixture of 1-phenyl-2-pyrrolidone in supercritical carbon dioxide. Phase behavior data was measured in a synthetic method at a temperature ranging from 333.2 to 393.2 K and at pressures up to 97.14 MPa. The solubility of 1-phenyl-2-pyrrolidone in the carbon dioxide + 1-phenyl-2-pyrrolidone system increased as temperature increased at a constant pressure and it exhibited the type-I phase behavior. The experimental data for the binary mixture were correlated with the Peng-Robinson equation of state using mixing rule and the critical properties of 1-phenyl-2-pyrrolidone were predicted with the Joback and Lyderson method.

Keywords

References

  1. Parshikov, A., Terent'ev, P. B., Piskunkova, N. F., Gracheva, R. A. and Bulakhov, G. A., "Microbiological Transformation of Deriv-atives of 4-Phenyl-2-Pyrrolidone by Mycelial Fungi," Chem. Heterocycl. Compd, 33(5), 523-526(1997). https://doi.org/10.1007/BF02291932
  2. Kendall, J. L., Canelas, D. A., Young, J. L. and DeSimone, J. M., "Polymerizations in Supercritical Carbon Dioxide," Chem. Rev., 99(2), 543-563(1999). https://doi.org/10.1021/cr9700336
  3. Yeo, S. D. and Kiran, E., "Formation of Polymer Particles with Supercritical Fluids: A Review," J. Supercrit. Fluids, 34(3), 287-308(2005). https://doi.org/10.1016/j.supflu.2004.10.006
  4. McHugh, M. A. and Krukonis, V. J., Supercritical Fluid Extraction, 2nd ed., Butterworth-Heinemann, Stoneham, Boston, 1994.
  5. Lee, J. C., Kim, C. R. and Byun, H. S., "Synthesis and Adsorption Properties of Carbamazepine Imprinted Polymer by Dispersion Polymerization in Supercritical Carbon Dioxide," Korean J. Chem. Eng., 31(12), 2266-2273(2014). https://doi.org/10.1007/s11814-014-0178-0
  6. Jang, Y. S. and Byun, H. S., "Cloud-Point and Bubble-Point Measurement for the Poly(2-butoxyethyl acrylate) + Cosolvent Mixture and 2-Butoxyethyl Acrylate in Supercritical Fluid Solvents," J. Chem. Eng. Data, 59(5), 1391-1399(2014). https://doi.org/10.1021/je400896u
  7. Jang, Y. S., Kim, S. H., Yoo, K. P. and Byun, H. S., "Phase Behavior Measurement for the Binary Mixture of $CO_2+$ Neopentyl Glycol Diacrylate and $CO_2+$ Neopentyl Glycol Dimethacrylate Systems at High Pressure," Fluid Phase Equilib., 302, 234-240 (2011). https://doi.org/10.1016/j.fluid.2010.09.003
  8. Yoon, Y. D. and Byun, H. S., "Experimental Measurement and Correlation of Phase Behavior for the $CO_2+$ Heptafluorobutyl Acrylate and $CO_2+$ Heptafluorobutyl Methacrylate Systems at High Pressure," Korean J. Chem. Eng., 31(3), 522-527(2014) https://doi.org/10.1007/s11814-013-0256-8
  9. Byun, H. S., "High Pressure Phase Equilibria for the Binary mixture of $CO_2+$ 3-Phenyl Propionitirle and $CO_2+$ 2-Phenyl Butyronitrile Systems," J. Supercriti. Fluids, 120, 218-225(2017). https://doi.org/10.1016/j.supflu.2016.05.045
  10. Byun, H. S. and Rhee, S. Y., "Phase Equilibria Measurement of Binary Mixtures for Triethylene Glycol Dimethacrylate and Triethylene Glycol Diacrylate in Supercritical $CO_2$," Korean J. Chem. Eng., 34(4), 1170-1176(2017). https://doi.org/10.1007/s11814-016-0332-y
  11. Lee, B. S. and Byun, H. S., "Solubility on Tetrahydrofurfuryl Acrylate Effect for the Poly[tetrahydrofurfuryl acrylate] in Supercritical Carbon Dioxide and Dimethyl Ether," J. Supercriti. Fluids, 135, 211-217(2018). https://doi.org/10.1016/j.supflu.2018.01.026
  12. Lee, B. S., Lee, J.-K., Bong, J.-H. and Byun, H. S., "Phase Behavior for the 2-(trimethylsilyloxy)ethyl methacrylate and 3-(trimethoxysilyl)propyl Methacrylate in Supercritical Carbon Dioxide," Fluid Phase Equilib., 462, 1-5(2018). https://doi.org/10.1016/j.fluid.2018.01.013
  13. Kim, S.-H., Chun, D., Yoon, S.-D. and Byun, H. S., "Phase Behav- ior for the $CO_2+$ Methyl Methoxyacetate and $CO_2+$ Methyl trans-3- Methoxyacrylate Systems at Pressures from (5 to 20) MPa and Various Temperatures," J. Chem. Eng. Data, 61(3), 1101-1108(2016). https://doi.org/10.1021/acs.jced.5b00711
  14. Rebelatto, E. A., Polloni, A. E., Andrade, K. S., Bender, J. P., Cora- zza, M. L., Lanza, M. and Oliveira, J. V., "High-Pressure Phase Equilibrium Data for Systems Containing Carbon Dioxide, ${\omega}$-Penta-decalactone, Chloroform and Water," J. Chem. Thermodyn., 122, 125-132(2018). https://doi.org/10.1016/j.jct.2018.03.008
  15. Peng, D. Y. and Robinson, D. B., "A New Two-Constant Equation of State," Ind. Eng. Chem. Fundam., 15(1), 59-63(1976). https://doi.org/10.1021/i160057a011
  16. Poling, B. E., Prausnitz, J. M. and O'Connell, J. P., The Properties of Liquids and Gases, 5th ed., McGraw-Hill, New York, 2001.
  17. Lee, B. S. and Byun, H. S., "Phase Behavior of Binary and Ternary Mixture for the Poly(TBAEMA) and TBAEMA in Supercritical Solvents," Korean J. Chem. Eng., 34(7), 2056-2064(2017). https://doi.org/10.1007/s11814-017-0091-4
  18. Cho, D. W., Shin, J., Bae, W., Kim, H., Lee, J. H. and Shin, M. S., "High-pressure Phase Behavior of Tri-ethylene Glycol Dimethac-rylate and Tetra-ethylene Glycol Dimethacrylate in Supercritical Carbon Dioxide," Fluid Phase Equilib., 319, 37-41(2012). https://doi.org/10.1016/j.fluid.2011.12.011
  19. Chirico, R. D., Frenkel, M., Diky, V. V., Marsh, K. N. and Wil- hoit, R. C., "ThermoML-An XML-Based Approach for Storage and Exchange of Experimental and Critically Evaluated Ther-mophysical and Thermochemical Property Data. 2. Uncertainties," J. Chem. Eng. Data, 48(5), 1344-1359(2003). https://doi.org/10.1021/je034088i
  20. Yoon, S. D. and Byun, H. S., "Phase Behaviour for the (Carbon Dioxide + 1,3-Butanediol Diacrylate) and (Carbon Dioxide + 1,3-Butanediol Dimethacrylate) Systems at Elevated Pressures and Temperatures," J. Chem. Thermodyn., 71, 91-97(2014). https://doi.org/10.1016/j.jct.2013.11.030
  21. Scott, R. L. and van Konynenburg, P. B., "Static Properties of Solutions - van der Waals and Related Models for HydrocarbonMixtures," Discuss. Faraday Soc., 49, 87-97(1970). https://doi.org/10.1039/df9704900087
  22. Rowlinson, J. S. and Swinton, F. L., Liquid and Liquid Mixtures, 3rd ed., Butterworth, Boston, 1982.
  23. http://www.chemspider.com/Chemical-Structure.70744.html.

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