Journal of Industrial and Engineering Chemistry

  • Volume 67
  • /
  • Pages.316-325
  • /
  • 2018
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  • 1226-086X(pISSN)
  • /
  • 1876-794X(eISSN)
The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Green synthesis of aluminum-based metal organic framework for the removal of azo dye Acid Black 1 from aqueous media

  • Jung, Kyung-Won (Center for Water Resources Cycle Research, Korea Institute of Science and Technology) ;
  • Choi, Brian Hyun (Center for Water Resources Cycle Research, Korea Institute of Science and Technology) ;
  • Lee, Seon Yong (Department of Earth and Environmental Sciences, Korea University) ;
  • Ahn, Kyu-Hong (Center for Water Resources Cycle Research, Korea Institute of Science and Technology) ;
  • Lee, Young Jae (Department of Earth and Environmental Sciences, Korea University)
  • Received : 2018.02.08
  • Accepted : 2018.07.02
  • Published : 2018.11.25
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Abstract

Aluminum based metal-organic framework using a di-carboxylate linker succinic acid (Al-SA MOF), are synthesized in water with minimal generation of secondary pollutants. The physicochemical properties of Al-SA MOF were examined, followed by its utility for the adsorption of Acid Black 1 (AB1) in aqueous media. Influences of key parameters such as pH, contact time, initial AB1 concentration,temperature, and selectivity on the adsorption process were assessed. A series of adsorption mechanisms are proposed, which involve electrostatic, hydrogen bonding, and hydrophobic interactions. These findings suggest that Al-SA MOF is a potent candidate in removing complex azo dyes molecules from aqueous media.

Keywords

Acknowledgement

Supported by : National Research Foundation of Korea (NRF)

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