Journal of Industrial and Engineering Chemistry

  • Volume 67
  • /
  • Pages.140-147
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  • 2018
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  • 1226-086X(pISSN)
  • /
  • 1876-794X(eISSN)
The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Effects of a naturally derived surfactant on hydrate anti-agglomeration using micromechanical force measurement

  • Li, Mingzhong (College of Petroleum Engineering, China University of Petroleum (East China)) ;
  • Dong, Sanbao (College of Petroleum Engineering, China University of Petroleum (East China)) ;
  • Li, Bofeng (College of Petroleum Engineering, China University of Petroleum (East China)) ;
  • Liu, Chenwei (College of Petroleum Engineering, China University of Petroleum (East China))
  • Received : 2018.05.02
  • Accepted : 2018.06.24
  • Published : 2018.11.25
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Abstract

The performance of a hydrate anti-agglomerant (AA) on cyclopentane (CyC5) hydrate anti-agglomeration at various concentrations (0-1 wt%, based on the oil phase) using MMF apparatus has been investigated. At low AA concentrations up to 0.01 wt%, the AA reduces the cohesion force (capillary force) by reducing the CyC5-water interfacial tension. At concentrations higher than 0.1 wt%, hydrate hydrophobicity alternation and AA's thermodynamic inhibition effects are the main part of AA's mechanism. Additionally, a "temporary agglomeration" phenomenon caused by surface melting of the hydrate particles is also observed, which may indicate the AA's weak ability to produce stable water-CyC5 interface.

Keywords

Acknowledgement

Supported by : Central Universities, National Natural Science Foundation, Natural Science Foundation of Shandong Province

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