Journal of Industrial and Engineering Chemistry

  • Volume 68
  • /
  • Pages.48-56
  • /
  • 2018
  • /
  • 1226-086X(pISSN)
  • /
  • 1876-794X(eISSN)
The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Immobilization of potassium copper hexacyanoferrate in doubly crosslinked magnetic polymer bead for highly effective Cs+ removal and facile recovery

  • Kim, Yun Kon (Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST)) ;
  • Bae, Kyeonghui (Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST)) ;
  • Kim, Yonghwan (Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST)) ;
  • Harbottle, David (School of Chemical and Process Engineering, University of Leeds) ;
  • Lee, Jae W. (Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST))
  • Received : 2018.06.02
  • Accepted : 2018.07.23
  • Published : 2018.12.25
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Abstract

A potassium copper hexacyanoferrate (KCuHCF) embedded magnetic hydrogel bead (HCF-Mbead) was synthesized via a facile double crosslinking methods of $Fe^{3+}$ ionic binding and freeze-thaw for effective $Cs^+$ removal. The HCF-Mbead had a hierarchical porous structure facilitating fast access of $Cs^+$ ions to embedded active sites. The adsorbent showed enhanced $Cs^+$ removal properties in terms of capacity (69.2 mg/g), selectivity ($K_d=4{\times}10^4mL/g$, 1 ppm $Cs^+$ in seawater) and stability (>99.5% removal in pH 3~11) with rapid magnetic separation. This study further opens the possibility to develop an efficient material that links the integration of adsorption and recovery.

Keywords

Acknowledgement

Supported by : NRF, Engineering and Physical Sciences Research Council

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