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Detection of electromagnetic interference shielding effect of Hanji mixed with carbon nanotubes using nuclear magnetic resonance techniques

  • Byun, Young Seok (Western Seoul Center, Korea Basic Science Institute) ;
  • Chae, Shin Ae (Western Seoul Center, Korea Basic Science Institute) ;
  • Park, Geun Yeong (Department of Carbon and Advanced Nanomaterials Engineering, Jeonju University) ;
  • Lee, Haeseong (Department of Carbon and Advanced Nanomaterials Engineering, Jeonju University) ;
  • Han, Oc Hee (Western Seoul Center, Korea Basic Science Institute)
  • Received : 2017.11.12
  • Accepted : 2017.12.30
  • Published : 2018.07.31

Abstract

Electromagnetic interference (EMI) shielding is an important issue in modern daily life due to the increasing prevalence of electronic devices and their compact design. This study estimated EMI-shielding effect (EMI-SE) of small ($8-14{\times}17mm$) Hanji (Korean traditional paper) doped with carbon nanotubes (CNTs) and compared to Hanji without CNT using $^2H$ (92.1 MHz) and $^{23}Na$ (158.7 MHz) nuclear magnetic resonance (NMR) peak area data obtained from 1 M NaCl in $D_2O$ samples in capillary tubes that were wrapped in the Hanji samples. The simpler method of using the variation of reflected power and tuning frequency by inserting the sample into an NMR coil was also tested at 242.9, 158.7, and 92.1 MHz. Overall, EMI shielding was relatively more effective at the higher frequencies. Our results validated that NMR methods to be useful to evaluate EMI-SE, particularly for small, flexible shielding materials, and demonstrated that EMI shielding by absorption is dominant in Hanji mixed with CNT.

Keywords

References

  1. Chung DDL. Materials for electromagnetic interference shielding. J Mater Eng Perform, 9, 350 (2000). https://doi.org/10.1361/105994900770346042.
  2. Chung DDL. Electromagnetic interference shielding effectiveness of carbon materials. Carbon, 39, 279 (2001). https://doi.org/10.1016/S0008-6223(00)00184-6.
  3. Al-Saleh MH, Sundararaj U. Electromagnetic interference shielding mechanisms of CNT/polymer composites. Carbon, 47, 1738 (2009). https://doi.org/10.1016/j.carbon.2009.02.030.
  4. Geetha S, Kumar KKS, Rao CRK, Vijayan M, Trivedi DC. EMI shielding: methods and materials-a review. J Appl Polym Sci, 112, 2073 (2009). https://doi.org/10.1002/app.29812.
  5. Im JS, Kim JG, Lee YS. Fluorination effects of carbon black additives for electrical properties and EMI shielding efficiency by improved dispersion and adhesion. Carbon, 47, 2640 (2009). https://doi.org/10.1016/j.carbon.2009.05.017.
  6. Cao J, Chung DDL. Colloidal graphite as an admixture in cement and as a coating on cement for electromagnetic interference shielding. Cem Concr Res, 33, 1737 (2003). https://doi.org/10.1016/S0008-8846(03)00152-2.
  7. Luo X, Chung DDL. Electromagnetic interference shielding reaching 130 dB using flexible graphite. Carbon, 34, 1293 (1996). https://doi.org/10.1016/0008-6223(96)82798-9.
  8. Seo YB, Kim YW, Lee MW, Jung SY. Improvements in the physical properties of Hanji by using red algae pulp. J Korea TAPPI, 41, 33 (2009).
  9. Yoo SI, Oh UM, Min YR, Choi TH. Improvement on dyeability of Hanji with natural dyes using a (3-chloro-2-hydroxypropyl) trimethyl ammonium chloride. J Korea TAPPI, 43, 88 (2011).
  10. Kim KJ, Lee MH, Eom TJ. Strengthening treatment of aged Hanji with solvent soluble polymers. J Korea TAPPI, 44, 1 (2012). https://doi.org/10.7584/ktappi.2012.44.1.001.
  11. Vavrda M, Hertl I. Automatic measurement of small boxes shielding effectiveness. Meas Sci Rev, 6, 22 (2006).
  12. Li Y, Chen C, Zhang S, Ni Y, Huang J. Electrical conductivity and electromagnetic interference shielding characteristics of multiwalled carbon nanotube filled polyacrylate composite films. App Surf Sci, 254, 5766 (2008). https://doi.org/10.1016/j.apsusc.2008.03.077.
  13. Drinovsky J, Kejik Z. Electromagnetic shielding efficiency measurement of composite materials. Meas Sci Rev, 9, 109 (2009). https://doi.org/10.2478/v10048-009-0020-8.
  14. Chase B, Citterio M, Lanni F, Makowiecki D, Radeka V, Rescia S, Takai H, Ban J, Parsons J, Sippach W. Characterization of the coherent noise, electromagnetic compatibility and electromagnetic interference of the ATLAS EM calorimeter front end board, in Proceedings of 5th Conference on Electronics for LHC Experiments (LEB 99), Snowmass, CO, 222 (1999).
  15. Maiti S, Shrivastava NK, Suin S, Khatua BB. Polystyrene/MWCNT/graphite nanoplate nanocomposites: efficient electromagnetic interference shielding material through graphite nanoplate-MWCNT-graphite nanoplate networking. ACS Appl Mater Interfaces, 5, 4712 (2013). https://doi.org/10.1021/am400658h.
  16. Lee CY, Song HG, Jang KS, Oh EJ, Epstein AJ, Joo J. Electromagnetic interference shielding efficiency of polyaniline mixtures and multilayer films. Synth Met, 102, 1346 (1999). https://doi.org/10.1016/S0379-6779(98)00234-3.
  17. Derome AE. Modern NMR Techniques for Chemistry Research, Pergamon Press, Oxford, 131 (1987).
  18. Tong XC. Advanced Materials and Design for Electromagnetic Interference Shielding, CRC Press, Florida, 14 (2008).
  19. Zhang W, Xiong H, Wang S, Li M, Gu Y. Electromagnetic characteristics of carbon nanotube film materials. Chin J Aeronaut, 28, 1245 (2015). https://doi.org/10.1016/j.cja.2015.05.002.