Elastomers and Composites

The Rubber Society of Korea (한국고무학회)
권호 표지
DOI QR코드

DOI QR Code

Synthesis of ZnS:Mn-Gly-C60 Nanocomposites and Their Photocatalytic Activity of Brilliant Green

  • Li, Jiulong (Department of Environmental Horticulture, Environmental Chemistry Major, Graduate School) ;
  • Ko, Weon Bae (Department of Environmental Horticulture, Environmental Chemistry Major, Graduate School)
  • Received : 2018.06.07
  • Accepted : 2018.06.20
  • Published : 2018.06.30
Download PDF
⟨ Previous Next ⟩

Abstract

ZnS:Mn-glycine (ZnS:Mn-Gly) nanocomposites were synthesized by capping ZnS:Mn nanocomposites with glycine. Zinc sulfate heptahydrate ($ZnSO_4{\cdot}7H_2O$), glycine ($C_2H_5NO_2$), manganese sulfate monohydrate ($MnSO_4{\cdot}H_2O$), and sodium sulfide ($Na_2S$) were used as the source reagents. $ZnS:Mn-Gly-C_{60}$ nanocomposites were obtained by heating the ZnS:Mn-Gly nanocomposites and fullerene ($C_{60}$) at a 2:1 mass ratio in an electric furnace at $700^{\circ}C$ for 2 h. X-ray diffraction (XRD) was used to characterize the crystal structure of the synthesized nanocomposites. The photocatalytic activity of the $ZnS:Mn-Gly-C_{60}$ nanocomposites was evaluated, via the degradation of brilliant green (BG) dye under 254 nm irradiation, with a UV-vis spectrophotometer.

Keywords

References

  1. H. R. Pouretedal, A. Norozi, M. H. Keshavarz, and A. Semnani, "Nanoparticles of zinc sulfide doped with manganese, nickel and copper as nanophotocatalyst in the degradation of organic dyes", J. Hazard. Mater., 162, 674 (2009). https://doi.org/10.1016/j.jhazmat.2008.05.128
  2. M. Sharma, T. Jain, S. Singh, and O. P. Pandey, "Photocatalytic degradation of organic dyes under UV-visible light using capped ZnS nanoparticles", Sol. Energy, 86, 626 (2012). https://doi.org/10.1016/j.solener.2011.11.006
  3. Y. J. He, "Synthesis of ZnO nanoparticles with narrow size distribution under pulsed microwave heating", Chin. Particuol., 2, 168 (2004). https://doi.org/10.1016/S1672-2515(07)60050-5
  4. J. P. Li, Y. Xu, Y. Liu, D. Wu, and Y. H. Sun, "Synthesis of hydrophilic ZnS nanocrystals and their application in photocatalytic degradation of dye pollutants", Chin. Particuol., 2, 266 (2004). https://doi.org/10.1016/S1672-2515(07)60072-4
  5. A. Eyasu, O. P. Yadav, and R. K. Bachheti, "Photocatalytic degradation of methyl orange dye using Cr-doped ZnS nanoparticles under visible radiation", Int. J. Chemtech. Res., 5, 1452 (2013).
  6. T. Robinson, G. McMullan, R. Marchant, and P. Nigam, "Remediation of dyes in textile effluent: a critical review on current treatment technologies with a proposed alternative", Bio. Tech., 77, 247 (2001). https://doi.org/10.1016/S0960-8524(00)00080-8
  7. I. Arslan, I. A. Balcioglu, T. Tuhkanen, and D. Bahnemann, "$H_2O_2$/UV-C and $Fe ^{2+}$/$H_2O_2$/UV-C versus $TiO_2$/UV-A treatment for reactive dye wastewater", J. Environ. Eng., 126, 877 (2000). https://doi.org/10.1061/(ASCE)0733-9372(2000)126:9(875)
  8. K. Parida and D. P. Das, "Photo-oxidation of 4-nitrophenol in aqueous suspensions, catalysed by titania intercalated zirconium phosphate (ZrP) and titanium phosphate (TiP)", J. Photochem. Photobiol. A: Chem., 163, 561 (2004). https://doi.org/10.1016/j.jphotochem.2004.02.016
  9. S. Kato, Y. Hirano, M. Iwata, T. Sano, K. Takeuchi, and S. Matsuzawa, "Photocatalytic degradation of gaseous sulfur compounds by silver-deposited titanium dioxide", J. Appl. Catal. B: Environ. Biol., 57, 109 (2005). https://doi.org/10.1016/j.apcatb.2004.10.015
  10. M. Qamar, M. Saquib, and M. Muneer, "Photocatalytic deg- radation of two selected dye derivatives, chromotrope 2B and amido black 10B, in aqueous suspensions of titanium dioxide", Dyes Pigm., 6, 1 (2005).
  11. N. Soltani, E. Saion, W. M. M. Yunus, M. Navasery, G. Bah- manrokh, M. Erfani, M. R. Zare, and E. Gharibshahi, "Photocatalytic degradation of methylene blue under visible light using PVP-capped ZnS and CdS nanoparticles", Sol. Energy, 97, 147 (2013). https://doi.org/10.1016/j.solener.2013.08.023
  12. T. Aarthi, P. Narahari, and G. Madras, "Photocatalytic degradation of azure and sudan dyes using nano $TiO_2$", J. Hazard. Mater., 149, 725 (2007). https://doi.org/10.1016/j.jhazmat.2007.04.038
  13. N. Karar, F. Singh, and B. R. Mehta, "Structure and photoluminescence studies on ZnS:Mn nanoparticles", J. Appl. Phys., 95, 656 (2004). https://doi.org/10.1063/1.1633347
  14. S. K. Pardeshi and A. B. Patil, "A simple route for photocatalytic degradation of phenol in aqueous zinc oxide suspension using solar energy", Sol. Energy, 82, 700 (2008). https://doi.org/10.1016/j.solener.2008.02.007
  15. K. M. Parida and S. Parija, "Photocatalytic degradation of phenol under solar radiation using microwave irradiated zinc oxide", Sol. Energy, 80, 1048 (2006). https://doi.org/10.1016/j.solener.2005.04.025
  16. W. Q. Peng, S. C. Qu, G. W. Cong, X. Q. Zhang, and Z. G. Wang, "Optical and magnetic properties of ZnS nanoparticles doped with $Mn^{2+}$", J. Cryst. Growth, 282, 179 (2005). https://doi.org/10.1016/j.jcrysgro.2005.05.005
  17. Y. L. Soo, Z. H. Ming, S. W. Huang, and Y. H. Kao, "Local structures around Mn luminescent centers in Mn-doped nanocrystals of ZnS", Phys. Rev. B, 50, 7602 (1994). https://doi.org/10.1103/PhysRevB.50.7602
  18. A. A. Bol, R. V. Beek, and A. Meijerink, "On the incorporation of trivalent rare earth ions in II-VI semiconductor nanocrystals", Chem. Mater., 14, 1121 (2002). https://doi.org/10.1021/cm011195s
  19. J. M. Huang, Y. Yang, S. H. Xue, B. Yang, S. Y. Liu, and J. C. Shen, "Photoluminescence and electroluminescence of ZnS:Cu nanocrystals in polymeric networks", Appl. Phys. Lett., 70, 2335 (1997). https://doi.org/10.1063/1.118866
  20. M. W. Porambo, H. R. Howard, and A. L. Marsh, "Dopant effects on the photocatalytic activity of colloidal zinc sulfide semiconductor nanocrystals for the oxidation of 2-chlorophenol", J. Phys. Chem. C, 114, 1580 (2010). https://doi.org/10.1021/jp907061d
  21. H. Althues, R. Palkovits, A. Rumplecker, P. Simon, W. Sigle, M. Bredol, U. Kynast, and S. Kaskel, "Synthesis and characterization of transparent luminescent ZnS:Mn/PMMA nanocomposites", Chem. Mater., 18, 1068 (2006). https://doi.org/10.1021/cm0477422
  22. L. X. Cao, J. H. Zhang, S. L. Ren, and S. H. Huang, "Luminescence enhancement of core-shell ZnS:Mn/ZnS nanoparticles", Appl. Phys. Lett., 80, 4300 (2002). https://doi.org/10.1063/1.1483113
  23. R. D. Yang, S. Tripathy, F. E. H. Tay, L. M. Gan, and S. J. Chua, "Photoluminescence and micro-Raman scattering in Mn-doped ZnS nanocrystalline semiconductors", J. Vac. Sci. Technol. B, 21, 984 (2003). https://doi.org/10.1116/1.1568350
  24. G. Murugadossn, B. Rajamannan, and V. Ramasamy, "Synthesis, characterization and optical properties of water-soluble ZnS:$Mn^{2+}$ nanoparticles", J. Lumin., 130, 2032 (2010). https://doi.org/10.1016/j.jlumin.2010.05.022
  25. P. Balaz, E. Boldizarova, E. Godocikova, and J. Briancin, "Mechanochemical route for sulphide nanoparticles preparation", Mater. Lett., 57, 1585 (2003). https://doi.org/10.1016/S0167-577X(02)01037-6
  26. A. H. Souici, N. Keghouche, J. A. Delaire, H. Remita, and M. Mostafavi, "Radiolytic synthesis and optical properties of ultra-small stabilized ZnS nanoparticles", Chem. Phys. Lett., 422, 25 (2006). https://doi.org/10.1016/j.cplett.2006.02.013
  27. N. Karan, S. Raj, and F. Singh, "Properties of nanocrystalline ZnS:Mn", J. Cryst. Growth, 268, 585 (2004). https://doi.org/10.1016/j.jcrysgro.2004.04.096
  28. M. Konishi, T. Isobe, and M. Senna, "Enhancement of photo- luminescence of ZnS:Mn nanocrystals by hybridizing with polymerized acrylic acid", J. Lumin., 93, 1 (2001). https://doi.org/10.1016/S0022-2313(01)00174-0
  29. B. Bhattacharjee, D. Ganguli, K. Iakoubovskii, A. Stesmans, and S. Chaudhuri, "Synthesis and characterization of sol-gel derived ZnS:$Mn^{2+}$ nanocrystallites embedded in a silica matrix", Bull. Mater. Sci., 25, 175 (2002). https://doi.org/10.1007/BF02711150
  30. J. Q. Zhuang, X. D. Zhang, G. Wang, D. M. Li, W. S. Yang, and T. J. Li, "Synthesis of water-soluble ZnS:$Mn^{2+}$ nanocrystals by using mercaptopropionic acid as stabilizer", J. Mater. Chem., 13, 1853 (2003). https://doi.org/10.1039/b303287f
  31. Y. He, H. F. Wang, and X. P. Yan, "Exploring Mn-doped ZnS quantum dots for the room-temperature phosphorescence detection of enoxacin in biological fluids", Anal. Chem., 80, 3832 (2008). https://doi.org/10.1021/ac800100y
  32. M. Ishikawa, S. Kamiya, S. Yoshimoto, M. Suzuki, D. Kuwa- hara, N. Sasaki, and K. Miura, "Nanocomposite materials of alternately stacked $C_{60}$ monolayer and graphene", J. Nanomater., 2010, 891514 (2010).