Corrosion Science and Technology

The Corrosion Science Society of Korea (한국부식방식학회)
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Anticorrosion Coatings Obtained by Plasma Electrolytic Oxidation on Implant Metals and Alloys

  • Sinebryukhov, S.L. (Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences) ;
  • Gnedenkov, S.V. (Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences) ;
  • Khrisanfova, O.A. (Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences) ;
  • Puz', A.V. (Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences) ;
  • Egorkin, V.S. (Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences) ;
  • Zavidnaya, A.G. (Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences)
  • Received : 2018.02.19
  • Accepted : 2018.04.30
  • Published : 2018.06.29
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Abstract

Development of biodegradable implants for treatment of complex bone fractures has recently become one of the priority areas in biomedical materials research. Multifunctional corrosion resistant and bioactive coatings containing hydroxyapatite $Ca_{10}(PO_4)_6(OH)_2$ and magnesium oxide MgO were obtained on Mg-Mn-Ce magnesium alloy by plasma electrolytic oxidation. The phase and elemental composition, morphology, and anticorrosion properties of the coatings were investigated by scanning electron microscopy, energy dispersive spectroscopy, potentiodynamic polarization, and electrochemical impedance spectroscopy. The PEO-layers were post-treated using superdispersed polytetrafluoroethylene powder. The duplex treatment considerably reduced the corrosion rate (>4 orders of magnitude) of the magnesium alloy. The use of composite coatings in inducing bioactivity and controlling the corrosion degradation of resorbable Mg implants are considered promising. We also applied the plasma electrolytic oxidation method for the formation of the composite bioinert coatings on the titanium nickelide surface in order to improve its electrochemical properties and to change the morphological structure. It was shown that formed coatings significantly reduced the quantity of nickel ions released into the organism.

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References

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