Membrane and Water Treatment

  • 제9권3호
  • /
  • Pages.189-194
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  • 2018
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  • 2005-8624(pISSN)
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  • 2092-7037(eISSN)
테크노프레스 (Techno-Press)
권호 표지
DOI QR코드

DOI QR Code

Electrochemical nitrate reduction using a cell divided by ion-exchange membrane

  • Lee, Jongkeun (Department of Civil and Environmental Plant Engineering, Konkuk University) ;
  • Cha, Ho Young (Department of Civil and Environmental Plant Engineering, Konkuk University) ;
  • Min, Kyung Jin (AinChem Tech Co., Ltd) ;
  • Cho, Jinwoo (Department of Environmental and Energy, Sejong University) ;
  • Park, Ki Young (Department of Civil and Environmental Plant Engineering, Konkuk University)
  • 투고 : 2017.12.29
  • 심사 : 2018.05.03
  • 발행 : 2018.05.25
⟨ 이전 논문 다음 논문 ⟩

초록

Electrochemical reduction of nitrate was studied using Zn, Cu and (Ir+Ru)-Ti cathodes and Pt/Ti anode in a cell divided by an ion exchange membrane. During electrolysis, effects of the different cathode types on operating parameters (i.e., voltage, temperature and pH), nitrate removal efficiency and by-products (i.e., nitrite and ammonia) formation were investigated. Ammonia oxidation rate in the presence of NaCl was also determined using the different ratios of hypochlorous acid to ammonia. The operating parameter values were similar for all types of cathode materials and were maintained relatively constant. Nitrate was well reduced and converted mostly to ammonia using Zn and Cu cathodes. Ammonia, produced as a by-product of nitrate reduction, was oxidized in the presence of NaCl in the electrochemical process and the oxidation performance was enhanced upon increasing the hypochlorous acid-to-ammonia ratio to 1.09:1. Zn and Cu cathodes promoted the nitrate reduction to ammonia and the produced ammonia was finally removed from solution by reacting with hypochlorite ions. Using Zn or Cu cathodes, instead of noble metal cathodes, in the electrochemical process can be an alternative technology for nitrate-containing wastewater treatment.

키워드

과제정보

연구 과제번호 : Technologies for the Risk Assessment & Management Program

연구 과제 주관 기관 : Ministry of Environment (MOE)

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피인용 문헌

  1. Separation of metals from electroplating wastewater using electrodialysis pp.1556-7230, 2019, https://doi.org/10.1080/15567036.2019.1568629
  2. Electrochemical reduction of nitrate using divided electrolytic cell by proton exchange membrane vol.12, pp.4, 2018, https://doi.org/10.12989/mwt.2021.12.4.157