DOI QR코드

DOI QR Code

Preparation and characterization of green adsorbent from waste glass and its application for the removal of heavy metals from well water

  • Rashed, M. Nageeb (Department of Chemistry, Faculty of Science, Aswan University) ;
  • Gad, A.A. (Department of Chemistry, Faculty of Science, Aswan University) ;
  • AbdEldaiem, A.M. (Drinking Water and Wastewater Company)
  • 투고 : 2017.11.19
  • 심사 : 2018.04.09
  • 발행 : 2018.03.25

초록

Waste glass disposal causes environmental problems in the cities. To find a suitable green environmental solution for this problem low cost adsorbent in this study was prepared from waste glass. An effective new green adsorbent was synthesized by hydrothermal treatment of waste glass (WG), followed by acidic activation of its surface by HCl (WGP). The prepared adsorbent was characterized by scanning electron microscopy (SEM), X-ray fluorescence (XRF), X-ray diffraction (XRD), and BET surface measurement. The developed adsorbent was used for the removal of heavy metals (Cd, Cu, Fe, Pb and Zn) from well water. Batch experiments were conducted to test the ability of the prepared adsorbent for the removal of Cd, Cu, Fe, Pb and Zn from well water. The experiments of the heavy metals adsorption by adsorbent (WGP) were performed at different metal ion concentrations, solution pH, adsorbent dosage and contact time. The Langmuir and Freundlich adsorption isotherms and kinetic models were used to verify the adsorption performance. The results indicated high removal efficiencies (99-100%) for all the studied heavy metals at pH 7 at constant contact time of 2 h. The data obtained from adsorption isotherms of metal ions at different time fitted well to linear form of the Langmuir sorption equation, and pseudo-second-order kinetic model. Application of the resulted conditions on well water demonstrated that the modified waste glass adsorbent successfully adsorbed heavy metals (Cd, Cu, Fe, Pb and Zn) from well water.

키워드

참고문헌

  1. Abdelhamid, B., Ourari, A. and Ouali, M.S. (2012), "Copper (II) ions removal from aqueous solution using bentonite treated with ammonium chloride", Am. J. Phys. Chem., 1(1), 1-10. https://doi.org/10.11648/j.ajpc.20120101.11
  2. Bhattacharya, A.K., Naiya, T.K., Mandal, S.N. and Das, S.K. (2008), "Adsorption, kinetics and equilibrium studies on removal of Cr(VI) from aqueous solutions using different low-cost adsorbents", Chem. Eng. J., 137(3), 529-541. https://doi.org/10.1016/j.cej.2007.05.021
  3. Budiman, H., Sri, H.K. and Setiawan, A. (2009), "Preparation of silica modified with 2-mercaptoimidazole and its sorption properties of Chromium (III)", J. Chem., 6(1), 141-150.
  4. Catalfamo, P., Primerano, P., Arrigo, I. and Corigliano, F. (2006), "The removal of heavy metals from wastewater by glass residue", Ann. Chim., 96(7-8), 487-492. https://doi.org/10.1002/adic.200690049
  5. Demirbas A. (2008), "Heavy metal adsorption onto agro-based waste materials: A review", J. Hazard. Mater., 157(2-3), 220-229. https://doi.org/10.1016/j.jhazmat.2008.01.024
  6. El-Ashtoukhy, E.S., Amin, N.K. and Abdelwahab, O. (2008), "Removal of lead(II) and copper(II) from aqueous solution using pomegranate peel as a new adsorbent", Desalination, 223(1-3), 162-173. https://doi.org/10.1016/j.desal.2007.01.206
  7. Garcia, A.M., Villora, J.M., Moreno, D.A., Ranninger, C., Callejas, P. and Barba, M.F. (2003), "Heavy metals bioremediation from polluted water by glass-ceramic materials", J. Am. Ceram. Soc., 86(12), 2200-2202. https://doi.org/10.1111/j.1151-2916.2003.tb03631.x
  8. Gardea-Torresdey, J.L., De La Rosa, G. and Peralta-Videa, J.R. (2004), "Use of phyto filtration technologies in the removal of heavy metals: A review", Pure Appl. Chem., 76(4), 801-813. https://doi.org/10.1351/pac200476040801
  9. Givianrad, M.H., Saber-Tehrani, M., Aberoomand-Azar, P. and Hosseini Sabzevari, M (2011), "Removal of cadmium using a novel nano composite silica aerogel, activated carbon", J. Phys. Theor. Chem., 8(2), 63-69.
  10. Gubbuk, I.H., Ozkan, S.C. and Yilmaz, A. (2013), "Sorption of heavy metal ions by glass beadsimmobilized calix [4] arenes derivative", Protect. Metal. Phys. Chem. Surf., 49(3), 266-273. https://doi.org/10.1134/S2070205113030180
  11. Gupta, S.S. and Bhattacharyya, K.G. (2006), "Removal of Cd (II) from aqueous solution by kaolinite, montmorillonite and their poly (oxo zirconium) and tetrabutylammonium derivatives", J. Hazard. Mater., 128(2-3), 247-257. https://doi.org/10.1016/j.jhazmat.2005.08.008
  12. Gupta, V.K. and Ali, I. (2004), "Removal of lead and chromium from wastewater using bagasse fly ash-a sugar industry waste", J. Colloid Interfac. Sci., 271(2), 321-328. https://doi.org/10.1016/j.jcis.2003.11.007
  13. Ibrahim, H.S., Ammar, N.S., Abdel Ghafar, H.H. and Farahat, M. (2012), "Adsorption of Cd (II), Cu (II) and Pb (II) using recycled waste glass: equilibrium and kinetic studies", Desalin. Water Treat., 48(1-3), 320-328. https://doi.org/10.1080/19443994.2012.698836
  14. Imamoglu, M. and Tekir, O. (2008), "Removal of copper (II) and lead (II) ions from aqueous solutions by adsorption on activated carbon from a new precursor hazelnut husks", Desalination, 228(1-3), 108-113. https://doi.org/10.1016/j.desal.2007.08.011
  15. Inglezakis, V.J., Stylianou, M.A., Gkantzou, D. and Loizidou, M.D. (2007), "Removal of Pb (II) from aqueous solutions by using clinoptilolite and bentonite as adsorbents", Desalination, 210(1-3), 248-256. https://doi.org/10.1016/j.desal.2006.05.049
  16. Karapinar, N. and Donat, R. (2009), "Adsorption behaviour of Cu2+ and Cd2+ onto natural bentonite", Desalination, 249(1), 123-129. https://doi.org/10.1016/j.desal.2008.12.046
  17. Karthikeyan, G. and Siva, I.S. (2008), "Equilibrium Sorption studies of Fe, Cu and Co ions in aqueous medium using activated Carbon prepared from Recinius Communis Linn", J. Appl. Sci. Environ. Manage., 12(2).
  18. Kumar, P.S., Ramalingam, S., Kirupha, S.D., Murugesan, A., Vidhyadevi, T. and Sivanesan, S. (2011), "Adsorption behavior of nickel (II) onto cashew nut shell: Equilibrium, thermodynamics, kinetics, mechanism and process design", Chem. Eng. J., 167(1), 122-131. https://doi.org/10.1016/j.cej.2010.12.010
  19. Li, L., Shi, H., Chen, L., Yuan, Q., Chen, X. and Lin, W. (2015), "Evaluation of La-doped mesoporous bioactive glass as adsorbent and photocatalyst for removal of methylene blue from aqueous solution", J. Photoenergy, 1-11.
  20. Liu, Q.S., Zheng, T., Wang, P., Jiang, J.P. and Li, N. (2010), "Adsorption isotherm, kinetic and mechanism studies of some substituted phenols on activated carbon fibers", Chem. Eng. J., 157(2-3), 348-356. https://doi.org/10.1016/j.cej.2009.11.013
  21. Meena, A.K., Rajagopal, C. and Mishra, G K. (2010), "Removal of heavy metal ions from aqueous solutions using chemically ($Na_2S$) treated granular activated carbon as an adsorbent", J. Sci. Ind. Res., 69(6), 449-453 .
  22. Mohan, S. and Gandhimathi, R. (2009), "Removal of heavy metal ions from municipal solid waste leachate using coal fly ash as an adsorbent", J. Hazard. Mater., 169(1-3), 351-359. https://doi.org/10.1016/j.jhazmat.2009.03.104
  23. Moyo, M., Chikazaza, L., Nyamunda, B.C. and Guyo, U. (2013), "Adsorption batch studies on the removal of Pb (II) using maize tassel based activated carbon", J. Chem.
  24. Nakazawa, R., Tomemori, H., Hirano, A., Mochizuki, H., An, P. and Inanaga, S. (2006), "Effects of the application of porous glass material treated with phosphate on the growth of tomato plants and the phytoavailable phosphate in soil", Soil Sci. Plant Nutr., 52(4), 540-544. https://doi.org/10.1111/j.1747-0765.2006.00057.x
  25. Orodu, V.E., Olisedeme, S. and Okpu, R.C. (2014), "Removal of heavy metals from aqueous solutions using snail shell powder as available adsorbent", J. Sci. Technol., 3(7), 422-428.
  26. Oshima, S., Perera, J.M., Northcott, K.A., Kokusen, H., Stevens, G.W. and Komatsu, Y. (2006), "Adsorption behavior of cadmium (II) and lead (II) on mesoporous silicate MCM-41", Sep. Sci. Technol., 41(8), 1635-1643. https://doi.org/10.1080/01496390600674786
  27. Pandey, P., Sambi, S.S., Sharma, S.K. and Singh, S. (2009), "Batch adsorption studies for the removal of Cu (II) ions by zeolite NaX from aqueous stream", Proceedings of the World Congress on Engineering and Computer Science 2009, San Francisco, California, U.S.A., October.
  28. Petrella, A., Petruzzelli, V., Basile, T., Petrella, M., Boghetich, G. and Petruzzelli, D. (2010), "Recycled porous glass from municipal/industrial solid wastes sorting operations as a lead ion sorbent from wastewaters", React. Funct. Polym., 70(4), 203-209. https://doi.org/10.1016/j.reactfunctpolym.2009.11.013
  29. Rashed, M.N. (2013), Adsorption Technique for the Removal of Organic Pollutants from Water and Wastewater, in Organic Pollutants-Monitoring, Risk and Treatment, InTech.
  30. Rashed, M.N., Soltan, M.E., Ahmed, M.M. and Abdou, A.N.E. (2017), "Removal of heavy metals from wastewater by new adsorbents from chemical activation of sewage sludge", Environ. Eng. Manage. J., 16(7), 1531-1542.
  31. Salim, M. and Munekage, Y. (2009), "Lead removal from aqueous solution using silica ceramic: Adsorption kinetics and equilibrium studies", J. Chem., 1(1), 23.
  32. Shen, C., Wang, Y., Xu, J. and Luo, G. (2013), "Chitosan supported on porous glass beads as a new green adsorbent for heavy metal recovery", Chem. Eng. J., 229, 217-224. https://doi.org/10.1016/j.cej.2013.06.003
  33. Shen, C., Wang, Y., Xu, J., Lu, Y. and Luo, G. (2012), "Preparation and ion exchange properties of eggshell glass beads with different surface morphologies", Particuology, 10(3), 317-326. https://doi.org/10.1016/j.partic.2011.11.002
  34. Shen, C., Wang, Y., Xu, J., Lu, Y. and Luo, G. (2012), "Preparation and ion exchange properties of eggshell glass beads with different surface morphologies", Particuology, 10(3), 317-326. https://doi.org/10.1016/j.partic.2011.11.002
  35. Sivakumar, P. and Palanisamy, P.N. (2009), "Adsorption studies of basic Red 29 by a non-conventional activated carbon prepared from Euphorbia antiquorum L", J. Chem. Tech. Res., 1(3), 502-510.
  36. Sun, Y.W., Wang, Y.J., Yang, L., Lu, Y.C. and Luo, G.S. (2008), "Heavy metal ion sorption pproperties of porous glass beads with a core-shell structure", Solvent Extr. Ion Exc., 26(5), 672-685. https://doi.org/10.1080/07366290802301481
  37. Tangjuank, S., Insuk, N., Tontrakoon, J. and Udeye, V. (2009), "Adsorption of lead (II) and cadmium (II) ions from aqueous solutions by adsorption on activated carbon prepared from cashew nut shells", World Acad. Sci. Eng. Technol., 52, 110-116.
  38. Temkin, M.I. (1940), "Kinetics of ammonia synthesis on promoted iron catalysts", Acta Physiochim. URSS, 12, 327-356.
  39. Wang, Y., Zhu, K., Wang, F. and Yanagisawa, K. (2009), "Novel Fe/glass composite adsorbent for As(V) removal", J. Environ. Sci., 21(4), 434-439. https://doi.org/10.1016/S1001-0742(08)62288-3
  40. Yanagisawa, K., Bao, N., Shen, L., Onda, A., Kajiyoshi, K., Matamoras-Veloza, Z. and Rendon-Angeles, J.C. (2006), "Development of a technique to prepare porous materials from glasses", J. Eur. Ceram. Soc., 26(4-5), 761-765. https://doi.org/10.1016/j.jeurceramsoc.2005.07.041
  41. Zaitoun, M., Momani, K., Jaradat, Q., Momani, I. and Qurashi, I. (2014), "Synthesis of an organic chelate doped sol gel filter to remove Cu (II) ions from aqueous solutions", Jordan J. Chem., 146(3335), 1-16.

피인용 문헌

  1. Low concentration cadmium removal using weathered sand of basalt vol.12, pp.2, 2018, https://doi.org/10.12989/mwt.2021.12.2.051