한국섬유공학회지 (Textile Science and Engineering)

  • 제55권2호
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  • Pages.95-100
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  • 2018
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  • 1225-1089(pISSN)
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  • 2288-6419(eISSN)
한국섬유공학회 (The Korean Fiber Society)
권호 표지
DOI QR코드

DOI QR Code

알킬기로 연결된 실록산 말단기를 가지는 비대칭 아연-프탈로시아닌의 합성과 물성에 대한 연구

Synthesis and Properties of Asymmetrical Zinc-phthalocyanines Containing a Siloxane End-group Linked with Alkyl Spacers of Different Lengths

  • 홍선미 (부산대학교 유기소재시스템공학과) ;
  • 박종승 (부산대학교 유기소재시스템공학과)
  • Hong, Sun-Mi (Department of Organic Material Science and Engineering, Pusan National University) ;
  • Park, Jong S. (Department of Organic Material Science and Engineering, Pusan National University)
  • 투고 : 2018.02.19
  • 심사 : 2018.04.04
  • 발행 : 2018.04.30
⟨ 이전 논문 다음 논문 ⟩

초록

Phthalocyanine (Pc), which has an electron-rich, aromatic structure, exhibits excellent optical properties as well as thermal and chemical stability. Numerous Pc derivatives, based on highly conjugated ring systems, have been proposed to facilitate efficient energy or electron transfer. They have been frequently adopted for suitable applications such as sensors and photosensitizers. In this study, we present the synthesis and properties of various asymmetrical zinc-phthalocyanine (ZnPc) derivatives having a siloxane end-group linked with alkyl chain spacers of different lengths. A ZnPc-immobilized ITO electrode was prepared by the direct attachment of the siloxane anchoring group to the oxide surface. The synthesized Pcs and the immobilized Pc surfaces were fully characterized by various techniques. The effect of the alkyl spacer length on the optical and electrochemical properties of the Pc-functionalized electrode is briefly discussed.

키워드

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