Advances in nano research

Techno-Press (테크노프레스)
권호 표지
DOI QR코드

DOI QR Code

Molecular interactions between pre-formed metal nanoparticles and graphene families

  • Low, Serena (Department of Chemistry and Biochemistry, California State University) ;
  • Shon, Young-Seok (Department of Chemistry and Biochemistry, California State University)
  • Received : 2017.12.16
  • Accepted : 2018.12.18
  • Published : 2018.12.25
⟨ Previous Next ⟩

Abstract

Two dimensional (2D) atomic layered nanomaterials exhibit some of the most striking phenomena in modern materials research and hold promise for a wide range of applications including energy and biomedical technologies. Graphene has received much attention for having extremely high surface area to mass ratio and excellent electric conductivity. Graphene has also been shown to maximize the activity of surface-assembled metal nanoparticle catalysts due to its unique characteristics of enhancing mass transport of reactants to catalysts. This paper specifically investigates the strategy of pre-formed nanoparticle self-assembly used for the formation of various metal nanoparticles supported on graphene families such as graphene, graphene oxide, and reduced graphene oxide and aims at understanding the interactions between ligand-capped metal nanoparticles and 2D nanomaterials. By varying the functional groups on the ligands between alkyl, aromatic, amine, and alcohol groups, different interactions such as van der Waals, ${\pi}-{\pi}$ stacking, dipole-dipole, and hydrogen bonding are formed as the 2D hybrids produced.

Keywords

Acknowledgement

Supported by : National Institute of General Medical Science

References

  1. Ahn, E., Lee, T., Gu, M., Park, M., Min, S.H. and Kim, B.-S. (2017), "Layer-by-layer assembly for graphene-based multilayer nanocomposites: the field manual", Chem. Mater., 29, 69-79. https://doi.org/10.1021/acs.chemmater.6b02688
  2. Al-Sherbini, E.-S.A.M. (2010), "UV-visible light reshaping of gold nanorods", Mater. Chem. Phys., 121, 349-353. https://doi.org/10.1016/j.matchemphys.2010.01.048
  3. Bae, H.S., Seo, E., Jang, S., Park, K.H. and Kim, B.-S. (2011), "Hybrid gold nanoparticle-reduced graphene oxide nanosheets as active catalysts for highly efficient reduction of nitroarenes", J. Mater. Chem., 21, 15431-15436. https://doi.org/10.1039/c1jm12477c
  4. Bhaskar, R., Joshi, H., Sharma, A.K. and Singh, A.K. (2017), "Reusable catalyst for transfer hydrogenation of aldehydes and ketones designed by anchoring palladium as nanoparticles on graphene oxide functionalized with selenated amine", ACS Appl. Mater. Interf., 9, 2223-2231. https://doi.org/10.1021/acsami.6b10457
  5. Bhimanapati, G.R. et al. (2015), "Recent advances in two-dimensional materials beyond graphene", ACS Nano, 9, 11509-11539. https://doi.org/10.1021/acsnano.5b05556
  6. Chen, Z., Liu, S., Yang, M.-Q. and Xu, Y.-J. (2013), "Synthesis of uniform CdS nanospheres/graphene hybrid nanocomposites and their application as visible light photocatalyst for selective reduction of nitro organics in water", ACS Appl. Mater. Interf., 5, 4309-4319.
  7. Chen, Y., Tan, C., Zhang, H. and Wang, L. (2015), "Two-dimensional graphene analogues for biomedical applications", Chem. Soc. Rev., 44, 2681-2701. https://doi.org/10.1039/C4CS00300D
  8. Chmiola, J., Largeot, C., Taberna, P.-L., Simon, P. and Gogotsi, Y. (2010), "Monolithic carbide-derived carbon films for micro-supercapacitors", Science, 328, 480-483. https://doi.org/10.1126/science.1184126
  9. Choi, Y., Bae, H.S., Seo, E., Jang, S., Park, K.H. and Kim, B.-S. (2011), "Hybrid gold nanoparticle-reduced graphene oxide nanosheets as active catalysts for highly efficient reduction of nitroarenes", J. Mater. Chem., 21, 15431-15436. https://doi.org/10.1039/c1jm12477c
  10. Compton, O.C. and Nguyen, S.T. (2010), "Graphene oxide, highly reduced graphene oxide, and graphene: versatile building blocks for carbon-based materials", Small, 6, 711-723. https://doi.org/10.1002/smll.200901934
  11. Dalfovo, M.C., Lacconi, G.I., Moreno, M., Yappert, M.C., Sumanasekera, G.U., Salvarezza, R.C. and Ibanez, F.J. (2014), "Synergy between graphene and Au nanoparticles (heterojunction) towards quenching, improving Raman signal, and UV light sensing", ACS Appl. Mater. Interf., 6, 6384-6391. https://doi.org/10.1021/am405753t
  12. Dembereldorj, U., Choi, S.Y., Ganbold, E.-O., Song, N.W., Kim, D., Choo, J., Lee, S.Y., Kim, S. and Joo, S.-W. (2014), "Gold nanorod-assembled PEGylated graphene-oxide nanocomposites for photothermal cancer therapy", Photochem. Photobiol. Sci., 90, 659-666. https://doi.org/10.1111/php.12212
  13. Diyarbakir, S., Can, H. and Metin, O. (2015), "Reduced graphene 0xide-supported CuPd alloy nanoparticles as efficient catalysts for the Sonogashira cross-coupling reactions", ACS Appl. Mater. Interf., 7, 3199-3206.
  14. Du, Y., Su, J., Luo, W. and Cheng, G. (2015), "Graphene-supported nickel-platinum nanoparticles as efficient catalyst for hydrogen generation from hydrous hydrazine at room temperature", ACS Appl. Mater. Interf., 7, 1031-1034. https://doi.org/10.1021/am5068436
  15. Ferrari, A.C., et al. (2015), "Science and technology roadmap for graphene, related two-dimensional crystals, and hybrid systems", Nanoscale, 7, 4598-4810. https://doi.org/10.1039/C4NR01600A
  16. Gavia, D.J., Do, Y., Gu, J. and Shon, Y.-S. (2014), "Mechanistic insights into the formation of dodecanethiolate-stabilized magnetic iridium nanoparticles: thiosulfate vs thiol ligands", J. Phys. Chem. C, 118, 14548-14554. https://doi.org/10.1021/jp504239x
  17. Ghosh, A., Pradeep, T. and Chakrabarti, J. (2014), "Coalescence of atomically precise clusters on graphenic surfaces", J. Phys. Chem. C, 118, 13959-13964. https://doi.org/10.1021/jp503001s
  18. Goksu, H., Ho, S.F., Metin, O., Korkmz, K., Garcia, A.M., Gultekin, M.S. and Sun, S. (2014), "Tandem dehydrogenation of ammonia borane and hydrogenation of nitro/nitrile compounds catalyzed by graphene-supported NiPd alloy nanoparticles", ACS Catal., 4, 1777-1782. https://doi.org/10.1021/cs500167k
  19. Gordel, M., Olesiak-Banska, J., Matczyszyn, K., Nogues, C., Buckle, M. and Samoc, M. (2014), "Post-synthesis reshaping of gold nanorods using a femtosecond laser", Phys. Chem. Chem. Phys., 16, 71-78. https://doi.org/10.1039/C3CP53457J
  20. Granatier, J., Lazar, P., Prucek, R., Safarova, K., Zboril, R., Otyepka, M. and Hobza, P. (2012), "Interaction of graphene and arenes with noble metals", J. Phys. Chem. C, 116, 14151-14162.
  21. Gupta, S. and Subramanian, V. (2014), "Encapsulating $Bi_2Ti_2O_7$ (BTO) with reduced graphene oxide (RGO): an effective strategy to enhance photocatalytic and photoelectrocatalytic activity of BTO", ACS Appl. Mater. Interf., 6, 18597-18608. https://doi.org/10.1021/am503396r
  22. Horiguchi, Y., Honda, K., Kato, Y., Nakashima, N. and Niidome, Y. (2008), "Photothermal reshaping of gold nanorods depends on the passivating layers of the nanorod surfaces", Langmuir, 24, 12026-12031. https://doi.org/10.1021/la800811j
  23. Hrbek, J., Hoffmann, F.M., Park, J.B., Liu, P., Stacchiola, D., Hoo, Y.S., Ma, S., Nambu, A., Rodriguez, J.A. and White, M.G. (2008), "Adsorbate-driven morphological changes of a gold surface at low temperature", J. Am. Chem. Soc., 130, 17272-17273. https://doi.org/10.1021/ja8081268
  24. Hu, C., Rong, J., Cui, J., Yang, Y., Yang, L., Wang, Y. and Liu, Y. (2013), "Fabrication of a graphene oxide-gold nanorod hybrid material by electrostatic self-assembly for surface-enhanced Raman scattering", Carbon, 51, 255-264. https://doi.org/10.1016/j.carbon.2012.08.051
  25. Huang, J., Zhang. L., Chen, B., Ji, N., Chen, F., Zhang, Y. and Zhang, Z. (2010), "Nanocomposites of size-controlled gold nanoparticles and graphene oxide: formation and applications in SERS and catalysis", Nanoscale, 2, 2733-2738.
  26. Huang, Y.-X., Xie, J.-F., Zhang, X., Xiong, L. and Yu, H.-Q. (2014), "Reduced graphene oxide supported palladium nanoparticles via photoassisted citrate reduction for enhanced electrocatalytic activities", ACS Appl. Mater. Interf., 6, 15795-15801. https://doi.org/10.1021/am504664r
  27. Isaacs, S.R., Choo, H., Ko, W.-B. and Shon, Y.-S. (2006), "Chemical, thermal, and ultrasonic stability of hybrid nanoparticles and nanoparticle multilayer films", Chem. Mater., 18, 107-114. https://doi.org/10.1021/cm0518980
  28. Ismaili, H., Geng, D., Sun, A.X., Kantzas, T.T. and Workentin, M.S. (2011), "Light-activated covalent formation of gold nanoparticle-graphene and gold nanoparticle-glass composites", Langmuir, 27, 13261-13268.
  29. Liu, M., Zhang, R. and Chen, W. (2014), "Graphene-supported nanoelectrocatalysts for fuel cells: synthesis, properties, and applications", Chem. Rev., 114, 5117-5160.
  30. Mao, S., Lu, G., Yu, K., Bo, Z. and Chen, J. (2010), "Specific protein detection using thermally reduced graphene oxide sheet decorated with gold nanoparticle-antibody conjugates", Adv. Mater., 22, 3521-3526. https://doi.org/10.1002/adma.201000520
  31. Mondal, A. and Jana, N.R. (2014), "Surfactant-free, stable noble metal-graphene nanocomposite as high performance electrocatalyst", ACS Catal., 4, 593-599. https://doi.org/10.1021/cs401032p
  32. Muszynski, R., Seger, B. and Kamat, P.V. (2008), "Decorating graphene sheets with gold nanoparticles", J. Phys. Chem. C., 112, 5263-5266. https://doi.org/10.1021/jp800977b
  33. Nguyen, T.H.D., Zhang, Z., Mustapha, A., Li, H. and Lin, M. (2014), "Use of graphene and gold nanorods as substrates for the detection of pesticides by surface enhanced Raman spectroscopy", J. Agric. Food Chem., 62, 10445-10451.
  34. Pan, H., Low, S., Weerasuriya, N. and Shon, Y.-S. (2015), "Graphene Oxide-Promoted Reshaping and Coarsening of Gold Nanorods and Nanoparticles", ACS Appl. Mater. Interf., 7, 3406-3413. https://doi.org/10.1021/am508801e
  35. Robertson, A.W., Ford, C., He, K., Kirkland, A.I., Watt, A.A.R. and Warner, J.H. (2014), "PbTe nanocrystal arrays on graphene and the structural influence of capping ligands", Chem. Mater., 26, 1567-1575. https://doi.org/10.1021/cm403373q
  36. Salam, N., Sinha, A., Roy, A.S., Mondal, P., Jana, N.R. and Islam, S.M. (2014), "Synthesis of silver-graphene nanocomposite and its catalytic application for the one-pot three-component coupling reaction and one-pot synthesis of 1,4-disubstituted 1,2,3-triazoles in water", RSC Adv., 4, 10001-10012. https://doi.org/10.1039/c3ra47466f
  37. Shon, Y.-S. (2004), "Metal nanoparticles protected with monolayers: synthetic methods", Dekker Encyclopedia of Nanoscience and Nanotechnology; (Schwarz J.A. Ed.), Marcel Dekker, New York, NY, USA, pp. 1-11.
  38. Shon, Y.-S., Aquino, M., Pham, T.V., Rave, D., Ramirez, M., Lin, K., Vaccarello, P., Lopez, G., Gredig, T. and Kwon, C. (2011), "Stability and morphology of gold nanoisland arrays generated from layer-by-layer assembled nanoparticle multilayer films: effects of heating temperature and particle size", J. Phys. Chem. C, 115, 10597-10605. https://doi.org/10.1021/jp110531x
  39. Sugden, M.W., Richardson, T.H. and Leggett, G. (2010), "Sub-10 ${\Omega}$ resistance gold films prepared by removal of ligands from thiol-stabilized 6 nm gold nanoparticles", Langmuir, 26, 4331-4338.
  40. Tan, C., Huang, X. and Zhang, H. (2013), "Synthesis and applications of graphene-based noble metal nanostructures", Mater. Today, 16, 29-36.
  41. Tao, Y., Dandapat, A., Chen, L., Huang, Y., Sasson, Y., Lin, Z., Zhang, J., Guo, L. and Chen, T. (2016), "Pd-on-Au supra-nanostructures decorated graphene oxide: an advanced electrocatalyst for fuel cell application", Langmuir, 32, 8557-8564.
  42. Xiang, Q. and Yu, J. (2013), "Graphene-based photocatalysts for hydrogen generation", J. Phys. Chem. Lett., 4, 753-759. https://doi.org/10.1021/jz302048d
  43. Xu, C., Yang, D., Mei, L., Lu, B., Chen, L., Li, Q., Zhu, H. and Wang, T. (2013), "Encapsulating gold nanoparticles or nanorods in graphene oxide shells as a novel gene vector", ACS Appl. Mater. Interf., 5, 2715-2724. https://doi.org/10.1021/am400212j
  44. Yao, H., Jin, L., Sue, H-J., Sumi, Y. and Nishimura, R. (2013), "Facile decoration of Au nanoparticles on reduced graphene oxide surfaces via a one-step chemical functionalization approach", J. Mater. Chem. A, 1, 10783-10789. https://doi.org/10.1039/c3ta11901g
  45. Yin, P.T., Shah, S., Chhowalla, M. and Lee, K.-B. (2015), "Design, synthesis, and characterization of graphene-nanoparticle hybrid materials for bioapplications", Chem. Rev., 115, 2483-2531. https://doi.org/10.1021/cr500537t
  46. Zedan, A.F., Moussa, S., Terner, J., Atkinson, G. and El-Shall, M.S. (2013), "Ultrasmall gold nanoparticles anchored to graphene and enhanced photothermal effects by laser irradiation of gold nanostructures in graphene oxide solutions", ACS Nano, 7, 627-636. https://doi.org/10.1021/nn304775h
  47. Zhang, N., Yan, X., Huang, Y., Li, J., Ma, J. and Ng, D.H.L. (2017), "Electrostatically assembled magnetite nanoparticles/graphene foam as a binder-free anode for lithium ion battery", Langmuir, 33, 8899-8905.
  48. Zhao, P., Li, N. and Astruc, D. (2013), "State of the art in nanoparticle synthesis", Coord. Chem. Rev., 257, 638-665. https://doi.org/10.1016/j.ccr.2012.09.002
  49. Zhao, J., Yang, B., Zheng, Z., Yang, J., Yang, Z., Zhang, P., Ren, W. and Yan, X. (2014), "Facile preparation of one-dimensional wrapping structure: graphene nanoscroll-wrapped of $Fe_3O_4$ nanoparticles and its application for lithium-ion battery", ACS Appl. Mater. Interf., 6, 9890-9896. https://doi.org/10.1021/am502574j
  50. Zhou, J., Chen, M., Xie, J. and Diao, G. (2013), "Synergistically enhanced electrochemical response of host-guest recognition based on ternary nanocomposites: reduced graphene oxide-amphiphilic pillar[5]arene-gold nanoparticles", ACS Appl. Mater. Interf., 5, 11218-11224. https://doi.org/10.1021/am403463p
  51. Zhu, C., Guo, S., Zhai, Y. and Dong, S. (2009), "Layer-by-layer self-assembly for constructing a graphene/platinum nanoparticle three-dimensional hybrid nanostructure using ionic liquid as a linker", Langmuir, 26(10), 7614-7618. https://doi.org/10.1021/la904201j
  52. Zhuo, Q., Ma, Y., Gao, J., Zhang, P., Xia, Y., Tian, Y., Sun, X., Zhong, J. and Sun, X. (2013), "Facile synthesis of graphene/metal nanoparticle composites via self-catalysis reduction at room temperature", Inorg. Chem., 52, 3141-3147. https://doi.org/10.1021/ic302608g

Cited by

  1. Covalent anchoring of atomically precise glutathione-protected gold nanoclusters on graphene oxide nanosheets vol.1, pp.3, 2020, https://doi.org/10.1088/2632-959x/abbe31
  2. An insight into the binding behavior of graphene oxide and noble metal nanoparticles vol.129, pp.12, 2021, https://doi.org/10.1063/5.0041894