Journal of the Korea Academia-Industrial cooperation Society (한국산학기술학회논문지)

The Korea Academia-Industrial cooperation Society (한국산학기술학회)
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Evaluation of the Antioxidant Effects of Extracted Seed Oils by Pressure Method using Domestic Seeds and Nuts

국내 종실류를 이용한 압착 오일의 화장품 소재로서 항산화 활성 평가

  • Ku, Hee-Yeon (Interdisciplinary Program of Perfume and Cosmetics, Graduate School of Chonnam National University) ;
  • Lee, Ki-Young (Interdisciplinary Program of Perfume and Cosmetics, Graduate School of Chonnam National University)
  • 구희연 (전남대학교 대학원 향장품학협동과정) ;
  • 이기영 (전남대학교 대학원 향장품학협동과정)
  • Received : 2017.11.28
  • Accepted : 2018.03.09
  • Published : 2018.03.31
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Abstract

This study was performed to evaluate the antioxidant activity capacity of extracted seed oils by pressure method using domestic plant resources as a cosmetics material. Four type of oil were extracted from pumpkin seed, camellia seed, red pepper seed, peanut. The extracted seed oils were analyzed for fatty acid composition by GCMS, The antioxidant activity evaluated by DPPH radical scavenging activity, ABTS radical cation decolorization activity. Pumpkin seed oil(PSO), camellia seed oil(CSO), peanut oil(PO) showed higher ratio of unsaturated fatty acid than saturated fatty acid. After heat treatment, the content of unsaturated fatty acids was higher than that of saturated fatty acids except for red pepper seed oil(RSO). In the result of DPPH, ABTS antioxidant activity, RSO were the highest 87.84%, 76.72% at the $200{\mu}{\ell}/m{\ell}$, PSO, PO and CSO were the highest antioxidant activities at the $1000{\mu}{\ell}/m{\ell}$. Compared with the positive control olive oil, DPPH radical scavenging activity of RSO, PSO and PO showed higher than the control. ABTS radical cation decolorization activity of RSO and PSO is stronger than the control. After heat treatment, the antioxidant activity capacity showed a slight difference, four type of oils is expected as having potential to be useful as a cosmetic material.

본 연구는 국내 식물자원을 이용한 압착 오일의 화장품소재로서 항산화 활성 평가를 실시하였다. 4종류의 종실에서 기름을 착유하여 gas chromatography mass spectrometry(GCMS)로 지방산 성분 분석을 비교하고 항산화 활성을 확인하기 위해 DPPH radical scavenging과 ABTS radical cation decolorization 활성을 측정하였다. 호박씨 오일, 동백씨 오일, 땅콩 오일은 불포화지방산이 포화지방산 보다 높은 비율을 보였으며, 열처리 후에도 고추씨 오일을 제외하고는 불포화지방산이 포화지방산보다 높은 비율을 차지했다. DPPH에서 고추씨 오일은 농도 $200{\mu}{\ell}/m{\ell}$에서 87.84%의 가장 높은 항산화 활성을 보였고, 호박씨 오일, 땅콩오일 그리고 동백씨 오일은 $1000{\mu}{\ell}/m{\ell}$에서 각각 75.20%, 74.16%, 43.18%의 가장 높은 활성을 나타냈다. ABTS에서는 고추씨 오일은 농도 $200{\mu}{\ell}/m{\ell}$에서 76.72%의 가장 높은 항산화 활성을 보였고, 호박씨 오일, 땅콩 오일 그리고 동백씨 오일은 $1000{\mu}{\ell}/m{\ell}$에서 각각 76.25%, 73.34%, 41.26%로 가장 높은 활성을 나타냈다. 양성대조군인 올리브 오일과 비교하여 DPPH에서는 고추씨 오일, 호박씨 오일 그리고 땅콩 오일이 대조군 보다 높은 항산화 활성을 보였고, ABTS에서는 고추씨 오일, 호박씨 오일이 높은 항산화 활성을 보였다. 열처리 후 항산화 활성능력은 근소한 차이를 보여, 본 연구를 통해 4종의 오일은 화장품 용 소재로서 유용하게 활용 될 수 있는 가능성을 가진 것으로 평가되었다.

Keywords

References

  1. Aleksandra ZIELINSKA, Izabela NOWAK, Fatty acids in vegetable oils and their importance incosmetic industry, Chemik, vol. 68, no. 2, pp. 103-110, 2014.
  2. J. H. Park, [Market Analysis]Current status and characteristics of cosmetic raw materials market, futurekorea, www.futurekorea.co.kr/news/articleView.hml?idxno=34136, 2016, 2017.
  3. Y. S. Oh, The study on the adoption of the nagoya protocol on access and benefit sharing and analysis on prospection of the Protocol, The journal of intellectual property, vol. 6, no. 3, pp. 205-237, 2011.
  4. Hanbit Flavor & Fragrance Co. LTD, Development of alternative import-dependent vegetable oil substitute material, 9-21, Ministry of agriculture, food and rural affairs, 2015.
  5. D. M. Jung, The contents of beneficiary components and oxidative stability of perilla seed oil obtained from roasted perilla seed with supercritical $CO_2$, press, and solvent extraction, Ph.D. dissertation, Woosuk university, 15, 2012.
  6. E. S. Kwon, The effect of clove essential oil on antioxidation and antiinflammation, Ph.D. dissertation, Daejeon university, 16, 2016.
  7. Rubalya Valantina, S., Neelamegam, P., Selective abts and dpph-radical scavenging activity of peroxide from vegetable oils, International food research journal, vol. 22, no. 1, pp. 289-294, 2015.
  8. D. Y. Park, K. Y. Lee, Evaluation of the cosmeceutical activity of ethanol extracts from perilla frutescens var. acuta, Journal of the korea Academia-Industrial cooperation society, vol .18, no. 3, pp. 513-517, 2017. DOI: http://doi.org/10.5762/KAIS.2017.18.3.513
  9. McArther, J.A., Marsho, T.V. and Newman, D.W. Transformations in plastids of bean leaves and pepper fruit, Plant physiology, vol. 39, no. 4, pp. 551-554. 1964. DOI: https://doi.org/10.1104/pp.39.4.551
  10. S. M. Mo, Research on the fatty acids of various seed oil of Korea, The korean nutrition society, vol. 7, no. 2, pp. 19-28, 1975.
  11. Procida G, Stancher, Cateni F, Zacchigna M, Chemical composition and functional characterization of commercial pumpkin seed oil, Journal of the science of food and agriculture, 93, pp. 1035-1041, 2012. DOI: https://doi.org/10.1002/jsfa.5843
  12. S. S. Park, The oxidation stability and antioxidant activity of camellia oil, Master's thesis, Kyungsung university, pp. 12-16, 2006.
  13. Y. J. Choi, Y. S. Ko, Studies on the lipid components of red pepper seed oil, Family and environment research, vol. 28, no. 2, pp. 31-36, 1990.
  14. J. H. Choi, Physicochemical characteristics of peanut, walnut and perilla seed oils roasted at different temperatures, Master's thesis, Chung-ang university, 23, 2015.
  15. M. J. Kim, S. P. Lee, J. H. Choi, S. H. Kwon, H. D. Kim, M. H. Bang, S. A. Yang, Characteristics of fermented dropwort extract and vinegar using fermented dropwort extract and its protective effects on oxidative damage in rat glioma C6 cell, Korean journal of food science and technology, 45, pp. 350-355, 2013. DOI: https://doi.org/10.9721/KJFST.2013.45.3.350
  16. Bonde V, Brand-Williams W and Berset C., Kinetics and mechanisms of antioxidant activity using the DPPH free radical method, Food science and technology, 30, pp. 609-615, 1997.
  17. Publio Viola, Marzia Viola, Virgin olive oil as a fundamental nutritional component and skin protector, Clinic in dermatology, vol. 27, no. 2, pp. 159-165, 2009. DOI: https://doi.org/10.1016/j.clindermatol.2008.01.008
  18. C. Samaniego Sanchez, A.M. Troncoso Gonzalez, M.C. García-Parrilla, J.J. Quesada Granados, H. Lopez García de la Serrana, M.C. Lopez Martinez, Different radical scavenging tests in virgin olive oil and their relation to the total phenol content, Analytica chimica acta, 593, 103-107, 2007. DOI: https://doi.org/10.1016/j.aca.2007.04.037
  19. Y. J. Kim, S. H. Lee, Cosmetology, 67-69, Chungku publishing co. lTd, 2014.
  20. Rita Stiens, The truth about cosmetics, 463, Firforest publishing co.,seoul, 2009.
  21. Wan Heo, S. Y. Lee, S. Y. Lim, J. H. Pan, H. M. Kim, Y. J. Kim, The functionalities and active constituents of olive oil, Korean society of food science and technology, vol. 44, no. 5, pp. 526-531, 2012. https://doi.org/10.9721/KJFST.2012.44.5.526
  22. B. G. Lee, J. H. Kim, S. G. Ham, C. E. Lee, Study on biological activities of extracts for cosmeceutical development from lagerstroemia indica L. Branch, Korean journal of plant resources, vol. 7, no. 1, pp. 029-034, 2014. DOI: http://dx.doi.org/10.7732/kjpr.2014.27.1.029
  23. J. C. Yang, The evaluation on the effectiveness as a cosmetic material of oil extracted from schizandra chinensis seed, Journal of korea oil Chemists Society, vol. 29, no. 2, pp. 231-237, 2012.