DOI QR코드

DOI QR Code

Fabrication and Transfer of Laser Induced Graphene (LIG) Electrode for Flexible Substrate-based Electrochemical Sensor Applicatins

유연 기판 기반 전기화학 센서 응용을 위한 레이저 유도 그래핀 전극 제작 및 전사 연구

  • Kim, Jeong Dae (Dept. of Electrical and Electronic Engineering, Korea University) ;
  • Kim, Taeheon (Dept. of Electrical and Electronic Engineering, Korea University) ;
  • Pak, Jungho (Dept. of Electrical and Electronic Engineering, Korea University)
  • Received : 2018.01.30
  • Accepted : 2018.02.27
  • Published : 2018.03.01

Abstract

This paper describes the fabrication process of laser induced graphene (LIG) and its transfer method on to a flexible and stretchable PDMS substrate. By irradiating CO2 laser on a polyimide(PI) film surface, a localized high temperature is created, resulting in a three-dimensional porous graphene network structure with good conductivity. This LIG electrode is relatively easy to fabricate and since it is very weak the LIG electrode was transferred to a flexible PDMS substrate to increase the sturdiness as well as possible use in flexible applications. Sheet resistance, thickness, and electrochemical activity of the fabricated in-situ LIG electrodes have been examined and compared with the LIG electrodes after transferring to PDMS elastomer. The properties of the LIG electrodes were also examined depending on the $CO_2$ laser power. As the irradiated laser power increased, the LIG electrode resistance decreases and the LIG electrode thickness increased. At 4.8 W of laser power, the average sheet resistance and thickness of the fabricated LIG electrodes were approximately $31.7{\Omega}/{\Box}$ and $62.67{\mu}m$, respectively. Moreover, the electrochemical activity of the fabricated LIG electrode at 4.8 W of laser power showed a high oxidation current of $28.2{\mu}A$ after transferring to PDMS.

Keywords

References

  1. Ding, Guoping, Jan Sandtner, and Hannes Bleuler. "A novel flexible PCB conductive structure for electro- dynamic bearings and measurement in its induced voltage." Journal of Electrical Engineering & Technology, vol. 10, no, 5, pp. 2001-2008, 2015. https://doi.org/10.5370/JEET.2015.10.5.2001
  2. Yang, Sang-Yeol, Jae-Hwan Kim, and Kyo-D. Song. "Flexible patch rectennas for wireless actuation of cellulose electro-active paper actuator." Journal of Electrical Engineering and Technology, vol. 7, no. 6 pp. 954-958, 2012. https://doi.org/10.5370/JEET.2012.7.6.954
  3. Geetha, G., et al. "Compact and Flexible Monopole Antenna for Ultra-Wideband Applications Deploying Fractal Geometry." Journal of Electrical Engineering & Technology, vol. 13, no. 1, pp. 400-405, 2018. https://doi.org/10.5370/JEET.2018.13.1.400
  4. Cho I. -J, H. -K Lee, S. -I Chang and E. Yoon, "Compliant ultrasound proximity sensor for the safe operation of human friendly robots integrated with tactile sensing capability", Journal of Electrical Engineering and Technology, vol. 12, no. 1, pp. 310-316, 2017. https://doi.org/10.5370/JEET.2017.12.1.310
  5. Madaria A. R., A. Kumar and C. Zhou, "Large scale, highly conductive and patterned transparent films of silver nanowires on arbitrary substrates and their application in touch screens", Nanotechnology, vol. 22, no. 24, pp. 1-7, 2017.
  6. Choi S., Lee H., Ghaffari R., Hyeon T. and Kim D. H., "Recent Advances in Flexible and Stretchable Bioelectronic Devices Integrated with Nanomaterials", Advanced Materials, vol. 28, no. 22, pp. 4203-4218, 2016. https://doi.org/10.1002/adma.201504150
  7. Meng Y., Zhao Y., Hu C., Cheng H., Hu Y. Zhang Z and Qu L, "All-graphene core-sheath microfibers for all-solidstate, stretchable fibriform supercapacitors and wearable electronic textiles", Advanced materials, vol. 25, no. 16, pp. 2326-2331, 2013. https://doi.org/10.1002/adma.201300132
  8. Gomez De Arco, L. Zhang, Y. Schlenker, C. W. Ryu, K. Thompson, M. E. and Zhou C, "Continuous, highly flexible, and transparent graphene films by chemical vapor deposition for organic photovoltaics", ACS nano, vol. 4, no. 5, pp. 2865-2873, 2010. https://doi.org/10.1021/nn901587x
  9. Lee H. Kim, I. Kim, M. and Lee H, "Moving beyond flexible to stretchable conductive electrodes using metal nanowires and graphenes", Nanoscale, vol. 8, no. 4, pp. 1789-1822, 2016. https://doi.org/10.1039/C5NR06851G
  10. Lotters J. C., Olthuis W., Veltink P. H. and Bergveld P, "The mechanical properties of the rubber elastic polymer polydimethylsiloxane for sensor applications", Journal of micromechanics and microengineering, vol. 7 no. 3, pp. 145-147, 1997. https://doi.org/10.1088/0960-1317/7/3/017
  11. Bhagat A. A. S., Jothimuthu P. and Papautsky I., "Photodefinable polydimethylsiloxane (PDMS) for rapid lab-on-a-chip prototypin", Lab on a Chip, vol. 7, no. 9, pp. 1192-1197, 2007. https://doi.org/10.1039/b704946c
  12. Kenry Joo Chuan, Y. and Chwee Teck L, "Emerging flexible and wearable physical sensing platforms for healthcare and biomedical applications", Microsystems & nanoenegineering, vol. 2, no. 16043, pp. 1-19, 2016.
  13. Saleem K., Leandro L., Ravinder S. D., "Technologies for Printing Sensors and Electronics Over Large Flexible Substrat: A Review", IEEE Sensors Journal, vol. 15, no. 6, pp. 3164-3185, 2015 https://doi.org/10.1109/JSEN.2014.2375203
  14. Kim N., Kee S., Lee S. H., Lee B. H., Kahng Y. H., Jo Y. R. and Lee K., "Highly Conductive PEDOT: PSS Nanofibrils Induced by Solution-Processed Crystallization", Advanced materials, vo. 26, no. 14, pp. 2268-2272, 2014. https://doi.org/10.1002/adma.201304611
  15. Kim K. S., Zhao Y., Kim J. M., Kim K. S. and Hong B. H. "Large-scale pattern growth of graphene films for stretchable transparent electrodes", nature, vol. 457, no. 7230, pp. 706-710, 2009.. https://doi.org/10.1038/nature07719
  16. Lee S., No I. J., Shin P. K., and Kim Y., "Capacitance and Output Current Control by CNT Concentration in the CNT/PVDF Composite Films for Electronic Devices", Transactions of the Korean Institute of Electrical Engineers, vol. 62, no. 8, pp. 1115-1119, 2013. https://doi.org/10.5370/KIEE.2013.62.8.1115
  17. Yang L., Zhang T., Zhou H., Price S. C., Wiley B. J. and You W., "Solution-processed flexible polymer solar cells with silver nanowire electrodes", ACS applied materials & interfaces, vol. 3, no. 10, pp. 4075-4084, 2011. https://doi.org/10.1021/am2009585
  18. Ferrari A. C., Bonaccorso F., Fal'Ko V., Novoselov K. S. Roche, S. Boggild P. and Garrido J. A., "Science and technology roadmap for graphene, related two-dimensional crystals, and hybrid systems", Nanoscale, vol. 7, no. 11, pp. 4598-4810, 2015. https://doi.org/10.1039/C4NR01600A
  19. Bonaccorso F., Sun Z., Hasan T. and Ferrari A. C., "Graphene photonics and optoelectronics", Nature photonics, vol. 4, no. 9, pp. 611-622, 2010. https://doi.org/10.1038/nphoton.2010.186
  20. Pinto A. M., Goncalves I. C. and Magalhaes F. D., "Graphene-based materials biocompatibility: a review", Colloids and Surfaces B: Biointerfaces, vol. 111, pp. 188-202, 2013. https://doi.org/10.1016/j.colsurfb.2013.05.022
  21. Han S., Wu D., Li S., Zhang F. and Feng X., "Graphene: a two-dimensional platform for lithium storage", Small, vol. 9, no. 8, pp. 1173-1187, 2013. https://doi.org/10.1002/smll.201203155
  22. Shi J. L., Peng H. J., Zhu L., Zhu W. and Zhang Q., "Template growth of porous graphene microspheres on layered double oxide catalysts and their applications in lithium-sulfur batteries", Carbon, vol. 92, pp. 96-105, 2015. https://doi.org/10.1016/j.carbon.2015.03.031
  23. Zheng C., Zhou X., Cao H., Wang G. and Liu Z., "Synthesis of porous graphene/activated carbon composite with high packing density and large specific surface area for supercapacitor electrode material", Journal of power sources, vol. 258, pp. 290-296, 2014 https://doi.org/10.1016/j.jpowsour.2014.01.056
  24. Lin J., Peng Z., Liu Y., Ruiz-Zepeda F., Ye R., Samuel E. L. and Tour J. M., "Laser-induced porous graphene films from commercial polymers", Nature communications, vol. 5, no. 5714, pp. 1-8, 2014.
  25. K. Rouzbeh, and W. S. Kim. "Flexible temperature sensor with laser scribed graphene oxide", Nanotechnology (IEEE-NANO), 2014 IEEE 14th International Conference on. IEEE, pp. 420-423, 2014.
  26. Tehrani F. and Bavarian B., "Facile and scalable disposable sensor based on laser engraved graphene for electrochemical detection of glucose", Scientific reports, vol. 6, no. 27975, pp. 1-10, 2016. https://doi.org/10.1038/s41598-016-0001-8
  27. Clerici F., Fontana M., Bianco S., Serrapede M., Perrucci F., Ferrero S. and Lamberti A., "In situ MoS2 decoration of laser-induced graphene as flexible supercapacitor electrodes", ACS applied materials & interfaces, vol. 8, no. 16, pp. 10459-10465, 2016. https://doi.org/10.1021/acsami.6b00808
  28. Dreyfus R. W., "CN temperatures above laser ablated polyimide", Applied Physics A: Materials Science & Processing, vol. 55, no. 4, pp. 335-339, 1992 https://doi.org/10.1007/BF00324081
  29. Mansour Ahmed., "Structural Analysis of Planar $sp^3$ and $sp^2$ Films: Diamond-Like Carbon and Graphene Overlayers", Diss, 2011.
  30. Bott A. W. and Jackson B. P., "Study of ferricyanide by cyclic voltammetry using the CV-50W", Current Separations, vol. 15, pp. 25-30, 1996.